A tin (IV) complex with 4,5-benzo-1,2-dithiol-3-thione (C7H4S3) (A), [SnCI4 (C7H4S3)2] (B) was synthesized. The structure of the obtained complex (B) was characterized by Infrared Spectroscopy (IR), anal...A tin (IV) complex with 4,5-benzo-1,2-dithiol-3-thione (C7H4S3) (A), [SnCI4 (C7H4S3)2] (B) was synthesized. The structure of the obtained complex (B) was characterized by Infrared Spectroscopy (IR), analysis centesimal composition, and theoretical study. The complex (B) has an octahedral structure, where a tin in the center takes an octahedral geometry and is coordinated by four atoms of chlorine and two thiocarbonyl sulfur atom (C=S) of the ligand.展开更多
文摘A tin (IV) complex with 4,5-benzo-1,2-dithiol-3-thione (C7H4S3) (A), [SnCI4 (C7H4S3)2] (B) was synthesized. The structure of the obtained complex (B) was characterized by Infrared Spectroscopy (IR), analysis centesimal composition, and theoretical study. The complex (B) has an octahedral structure, where a tin in the center takes an octahedral geometry and is coordinated by four atoms of chlorine and two thiocarbonyl sulfur atom (C=S) of the ligand.