Electric product house of magnesium alloy sheet is usually obtained by warm stamping owing to its poor plasticity and formability at room temperature.The formability of AZ31B magnesium alloy sheet can be improved by r...Electric product house of magnesium alloy sheet is usually obtained by warm stamping owing to its poor plasticity and formability at room temperature.The formability of AZ31B magnesium alloy sheet can be improved by repeated unidirectional bending(RUB)process through control of(0002)basal texture.Compared with as-received sheet,the Erichsen value(IE)of the sheet underwent RUB process increases to 5.90 from 3.53 at room temperature.It is also confirmed that cell phone houses could be stamped successfully in crank press with AZ31B magnesium alloy sheets underwent RUB process.It provides an alternative to the electronics industry in the application of magnesium alloys.展开更多
The surface solar radiation(SSR) is of great importance to bio-chemical cycle and life activities.However,it is impossible to observe SSR directly over large areas especially for rugged surfaces such as the Qinghai-Ti...The surface solar radiation(SSR) is of great importance to bio-chemical cycle and life activities.However,it is impossible to observe SSR directly over large areas especially for rugged surfaces such as the Qinghai-Tibet Plateau.This paper presented an improved parameterized model for predicting all-sky global solar radiation on rugged surfaces using Moderate Resolution Imaging Spectroradiometer(MODIS) atmospheric products and Digital Elevation Model(DEM).The global solar radiation was validated using 11 observations within the plateau.The correlation coefficients of daily data vary between 0.67-0.86,while those of the averages of 10-day data are between 0.79-0.97.The model indicates that the attenuation of SSR is mainly caused by cloud under cloudy sky,and terrain is an important factor influencing SSR over rugged surfaces under clear sky.A positive relationship can also be inferred between the SSR and slope.Compared with horizontal surfaces,the south-facing slope receives more radiation,followed by the west-and east-facing slopes with less SSR,and the SSR of the north-facing slope is the least.展开更多
In wine production, the typical characteristics of variety, defined by its place of their origin, contribute to the development of distinctive and unique wines. In the current study, we analyzed the effect of the envi...In wine production, the typical characteristics of variety, defined by its place of their origin, contribute to the development of distinctive and unique wines. In the current study, we analyzed the effect of the environment using vine response and grape composition as indicators. Four cv. Tannat vineyards in three different climatic regions of Uruguay with similar soil conditions were studied in 2008 and 2009. Vines grafted onto SO4 （Vitis berlandieri × Vitis riparia） rootstock and were trained on a trellis system. Weather information was obtained from weather stations （MMO standards）. At each vineyard, we recorded： yield per plant, pruning weight, leaf area and pre-dawn leaf water potential. We analyzed sugars, total acidity and pH, polyphenolic potential, organic acids and berry weight. Analysis of variance, Pearson correlations and discriminant analysis were carried out. The climate factors with the highest discriminant weight were water balance, degree days （〉 10 ℃） of maturation and rainfall during the vegetative growth period. Plant response allowed us to discriminate between vineyards regardless of the year and was consistent with climate. Exposed leaf area and length of maturation period were the indexes with the highest values, followed by leaf water potential and grape yield. The total anthocyanin content, sugar contents and their daily accumulation, and acid composition statistically separate regions regardless of the year. We concluded that plant response and grape composition were strongly influenced by water supply and thermal conditions during ripening.展开更多
Syngas conversion to fuels and chemicals is one of the most challenging subjects in the field of C1 chemistry. It is considered as an attractive alternative non-petroleum-based production route. The direct synthesis o...Syngas conversion to fuels and chemicals is one of the most challenging subjects in the field of C1 chemistry. It is considered as an attractive alternative non-petroleum-based production route. The direct synthesis of olefins and alcohols as high value-added chemicals from syngas has drawn particular attention due to its process simplicity, low energy consumption and clean utilization of carbon resource, which conforms to the principles of green carbon science. This review describes the recent advances for the direct production of lower olefins and higher alcohols via syngas conversion. Recent progress in the development of new catalyst systems for enhanced catalytic performance is highlighted. We also give recommendations regarding major challenges for further research in syngas conversion to various chemicals.展开更多
In oil and gas exploration and transportation, low dosage hydrate inhibitors （LDHIs） are more favorably utilized to inhibit the formation of hydrates than thermodynamic inhibitors （THs） as a trend. However, there ...In oil and gas exploration and transportation, low dosage hydrate inhibitors （LDHIs） are more favorably utilized to inhibit the formation of hydrates than thermodynamic inhibitors （THs） as a trend. However, there are no industrial products of LDHIs available domestically, and the corresponding application experience is in urgent need. In this paper, a combined hydrate inhibitor （HY-1） was synthesized after a series of reaction condition optimization, and its performance on THF hydrate inhibition was investigated using kinetic hydrate inhibitor evaluation apparatus with 6 cells bathing in air. The results show that when the reaction temperature is 60℃, the reaction time is 6 h, and the monomer： solvent ratio is 1：2, the product has the best kinetic hydrate inhibitor performance on THF hydrate. On these bases, the scale-up production of this combined hydrate inhibitor was carried out. Although the scale-up product （HY-10） performs less effectively on the THF hydrate inhibition than HY-1, it functions better than a commercial product （Inhibex501） during in-house tests. HY-10 was successfully applied to the gas production process. Field trials in northem Shaanxi PetroChina Changqing Oilfield Company （PCOC） show that 2 wt% of HY-10 is effective on natural gas hydrate inhibition. It is found through economic analysis that the use of HY-10 has obvious economi- cal advantage over methanol and Inhibex501.展开更多
CO2 is a major greenhouse gas,and it can also be used as a chemical feedstock for synthesis of chemicals and fuels by passing the petrochemical source.Herein,we present the recent progress of our research work in the ...CO2 is a major greenhouse gas,and it can also be used as a chemical feedstock for synthesis of chemicals and fuels by passing the petrochemical source.Herein,we present the recent progress of our research work in the catalytic conversion of CO2 to chemicals,with particular attention paid to catalytic reactivity and reaction mechanism.We also give the recommendations regarding the challenges and potential directions of the future research in this field.展开更多
基金Project(50504019)supported by the National Natural Science Foundation of ChinaProject(2008BB4040)supported by the Science Foundation of Chongqing,ChinaProject(2008AA4028)supported by Scientific and Technological Project of Chongqing Science and Technology Commission,China
文摘Electric product house of magnesium alloy sheet is usually obtained by warm stamping owing to its poor plasticity and formability at room temperature.The formability of AZ31B magnesium alloy sheet can be improved by repeated unidirectional bending(RUB)process through control of(0002)basal texture.Compared with as-received sheet,the Erichsen value(IE)of the sheet underwent RUB process increases to 5.90 from 3.53 at room temperature.It is also confirmed that cell phone houses could be stamped successfully in crank press with AZ31B magnesium alloy sheets underwent RUB process.It provides an alternative to the electronics industry in the application of magnesium alloys.
基金Under the auspices of Knowledge Innovation Programs of the Chinese Academy of Sciences (No KZCX2-YW-308)National Natural Science Foundation of China (No 40771172, 40901223)
文摘The surface solar radiation(SSR) is of great importance to bio-chemical cycle and life activities.However,it is impossible to observe SSR directly over large areas especially for rugged surfaces such as the Qinghai-Tibet Plateau.This paper presented an improved parameterized model for predicting all-sky global solar radiation on rugged surfaces using Moderate Resolution Imaging Spectroradiometer(MODIS) atmospheric products and Digital Elevation Model(DEM).The global solar radiation was validated using 11 observations within the plateau.The correlation coefficients of daily data vary between 0.67-0.86,while those of the averages of 10-day data are between 0.79-0.97.The model indicates that the attenuation of SSR is mainly caused by cloud under cloudy sky,and terrain is an important factor influencing SSR over rugged surfaces under clear sky.A positive relationship can also be inferred between the SSR and slope.Compared with horizontal surfaces,the south-facing slope receives more radiation,followed by the west-and east-facing slopes with less SSR,and the SSR of the north-facing slope is the least.
文摘In wine production, the typical characteristics of variety, defined by its place of their origin, contribute to the development of distinctive and unique wines. In the current study, we analyzed the effect of the environment using vine response and grape composition as indicators. Four cv. Tannat vineyards in three different climatic regions of Uruguay with similar soil conditions were studied in 2008 and 2009. Vines grafted onto SO4 （Vitis berlandieri × Vitis riparia） rootstock and were trained on a trellis system. Weather information was obtained from weather stations （MMO standards）. At each vineyard, we recorded： yield per plant, pruning weight, leaf area and pre-dawn leaf water potential. We analyzed sugars, total acidity and pH, polyphenolic potential, organic acids and berry weight. Analysis of variance, Pearson correlations and discriminant analysis were carried out. The climate factors with the highest discriminant weight were water balance, degree days （〉 10 ℃） of maturation and rainfall during the vegetative growth period. Plant response allowed us to discriminate between vineyards regardless of the year and was consistent with climate. Exposed leaf area and length of maturation period were the indexes with the highest values, followed by leaf water potential and grape yield. The total anthocyanin content, sugar contents and their daily accumulation, and acid composition statistically separate regions regardless of the year. We concluded that plant response and grape composition were strongly influenced by water supply and thermal conditions during ripening.
基金supported by the National Natural Science Foundation of China(91545112,21573271,21403278)Shanghai Municipal Science and Technology Commission,China(15DZ1170500)the Chinese Academy of Sciences(QYZDB-SSW-SLH035)
文摘Syngas conversion to fuels and chemicals is one of the most challenging subjects in the field of C1 chemistry. It is considered as an attractive alternative non-petroleum-based production route. The direct synthesis of olefins and alcohols as high value-added chemicals from syngas has drawn particular attention due to its process simplicity, low energy consumption and clean utilization of carbon resource, which conforms to the principles of green carbon science. This review describes the recent advances for the direct production of lower olefins and higher alcohols via syngas conversion. Recent progress in the development of new catalyst systems for enhanced catalytic performance is highlighted. We also give recommendations regarding major challenges for further research in syngas conversion to various chemicals.
基金supported by the National Basic Research Program of China ("973" Program) (Grant No.G2009CB219504)the National Sci-ence and Technology Major Project of China (Grant No.2008ZX05026-004-06)the Fundamental Research Funds for the Central Universities (Grant No.2009ZM0185)
文摘In oil and gas exploration and transportation, low dosage hydrate inhibitors （LDHIs） are more favorably utilized to inhibit the formation of hydrates than thermodynamic inhibitors （THs） as a trend. However, there are no industrial products of LDHIs available domestically, and the corresponding application experience is in urgent need. In this paper, a combined hydrate inhibitor （HY-1） was synthesized after a series of reaction condition optimization, and its performance on THF hydrate inhibition was investigated using kinetic hydrate inhibitor evaluation apparatus with 6 cells bathing in air. The results show that when the reaction temperature is 60℃, the reaction time is 6 h, and the monomer： solvent ratio is 1：2, the product has the best kinetic hydrate inhibitor performance on THF hydrate. On these bases, the scale-up production of this combined hydrate inhibitor was carried out. Although the scale-up product （HY-10） performs less effectively on the THF hydrate inhibition than HY-1, it functions better than a commercial product （Inhibex501） during in-house tests. HY-10 was successfully applied to the gas production process. Field trials in northem Shaanxi PetroChina Changqing Oilfield Company （PCOC） show that 2 wt% of HY-10 is effective on natural gas hydrate inhibition. It is found through economic analysis that the use of HY-10 has obvious economi- cal advantage over methanol and Inhibex501.
基金the financial support from the Strategic Priority Research Program of the Chinese Academy of Sciences(XDA02040602)the National Science&Technology Pillar Program(2013BAC11B02)
文摘CO2 is a major greenhouse gas,and it can also be used as a chemical feedstock for synthesis of chemicals and fuels by passing the petrochemical source.Herein,we present the recent progress of our research work in the catalytic conversion of CO2 to chemicals,with particular attention paid to catalytic reactivity and reaction mechanism.We also give the recommendations regarding the challenges and potential directions of the future research in this field.
