In this article, 12-acryloyloxystearic acid was synthesized, which was then used to prepare the magnesium 12-acryloyloxy stearate detergent. Reaction conditions for synthesizing 12-acryloyloxystearic acid, including t...In this article, 12-acryloyloxystearic acid was synthesized, which was then used to prepare the magnesium 12-acryloyloxy stearate detergent. Reaction conditions for synthesizing 12-acryloyloxystearic acid, including the molar ratio of 12-hydroxystearic acid to acrylic acid, the catalyst amount, the esterification temperature, and the esterification time, were optimized. Under the optimized conditions, the 12-acryloyloxystearic acid with an acid value of 159 mg KOH/g and a melting range of between 70.4 ℃ and 71.4 ℃ was obtained. The structure of 12-acryloyloxystearic acid was confirmed by FTIR spectroscopy. Results of preparing magnesium 12-acryloyloxy stearate detergent showed the existence of acryloyloxy radical in 12-hydroxystearic acid could improve the quality of lubricant detergent greatly.展开更多
Artificial photosynthesis is a new approach to generate sustainable energy. In order to constrain reaction solution in a solid state structure and increase the reaction efficiency in artificial photosynthesis reaction...Artificial photosynthesis is a new approach to generate sustainable energy. In order to constrain reaction solution in a solid state structure and increase the reaction efficiency in artificial photosynthesis reactions, we presented two methods to fabricate the chitosan scaffold with interconnected micro channels as construction structure of a novel artificial photosynthesis device. We built 3D chitosan structure with a home-made heterogeneous 3D rapid prototyping machine, and we used lyophilization method to generate the micron-scale pores inside the chitosan scaffold. Chitosan in acetic acid could achieve different viscosities. We found a proper chitosan recipe to construct 3D scaffold by our own rapid prototyping machine. Optional support material sodium bicarbonate was used in printing 3D scaffold for holding the printed structures, and the results images indicate that this method can make the scaffold stronger and more stable.展开更多
In this paper, different particle sizes of coal fly ash FA-R(D50= 15.75 μm), FA-A(D50= 3.61 μm) and FA-B(D50= 1.73 μm) were treated with Na OH solution to prepare the forming adsorbents FFA-R, FFA-A and FFA-B.The s...In this paper, different particle sizes of coal fly ash FA-R(D50= 15.75 μm), FA-A(D50= 3.61 μm) and FA-B(D50= 1.73 μm) were treated with Na OH solution to prepare the forming adsorbents FFA-R, FFA-A and FFA-B.The structure and adsorption properties of the forming adsorbents for methylene blue(MB) from aqueous solution were examined. The results showed that the specific surface areas and adsorption capacities of the forming adsorbent for MB increased with decreasing particle size of raw coal fly ashes. The adsorption kinetic data of MB on FFA-R, FFA-A and FFA-B fitted the second-order kinetic model very well with the rate constants(k2) of3.15 × 10-2, 3.84 × 10-2and 6.27 × 10-2g·mg-1·min-1, respectively. The adsorption process was not only controlled by intra-particle diffusion. The isotherms of MB on FFA-R, FFA-A and FFA-B can be described by the Langmuir isotherm and the Freundlich isotherm, and the adsorption processes were spontaneous and exothermic.展开更多
基金This work was supported by the National Undergraduate Innovative Training Program(201410375004)the Scientific Research Foundation for Introduced Scholars,Huangshan University(2015xkjq002)the Scientific Research Foundation of Huangshan University(2014xkj012)
文摘In this article, 12-acryloyloxystearic acid was synthesized, which was then used to prepare the magnesium 12-acryloyloxy stearate detergent. Reaction conditions for synthesizing 12-acryloyloxystearic acid, including the molar ratio of 12-hydroxystearic acid to acrylic acid, the catalyst amount, the esterification temperature, and the esterification time, were optimized. Under the optimized conditions, the 12-acryloyloxystearic acid with an acid value of 159 mg KOH/g and a melting range of between 70.4 ℃ and 71.4 ℃ was obtained. The structure of 12-acryloyloxystearic acid was confirmed by FTIR spectroscopy. Results of preparing magnesium 12-acryloyloxy stearate detergent showed the existence of acryloyloxy radical in 12-hydroxystearic acid could improve the quality of lubricant detergent greatly.
文摘Artificial photosynthesis is a new approach to generate sustainable energy. In order to constrain reaction solution in a solid state structure and increase the reaction efficiency in artificial photosynthesis reactions, we presented two methods to fabricate the chitosan scaffold with interconnected micro channels as construction structure of a novel artificial photosynthesis device. We built 3D chitosan structure with a home-made heterogeneous 3D rapid prototyping machine, and we used lyophilization method to generate the micron-scale pores inside the chitosan scaffold. Chitosan in acetic acid could achieve different viscosities. We found a proper chitosan recipe to construct 3D scaffold by our own rapid prototyping machine. Optional support material sodium bicarbonate was used in printing 3D scaffold for holding the printed structures, and the results images indicate that this method can make the scaffold stronger and more stable.
基金Supported by the National Natural Science Foundation of China(51278418)the Natural Science Basic Research Plan in Shaanxi Province of China(2013K11-10)
文摘In this paper, different particle sizes of coal fly ash FA-R(D50= 15.75 μm), FA-A(D50= 3.61 μm) and FA-B(D50= 1.73 μm) were treated with Na OH solution to prepare the forming adsorbents FFA-R, FFA-A and FFA-B.The structure and adsorption properties of the forming adsorbents for methylene blue(MB) from aqueous solution were examined. The results showed that the specific surface areas and adsorption capacities of the forming adsorbent for MB increased with decreasing particle size of raw coal fly ashes. The adsorption kinetic data of MB on FFA-R, FFA-A and FFA-B fitted the second-order kinetic model very well with the rate constants(k2) of3.15 × 10-2, 3.84 × 10-2and 6.27 × 10-2g·mg-1·min-1, respectively. The adsorption process was not only controlled by intra-particle diffusion. The isotherms of MB on FFA-R, FFA-A and FFA-B can be described by the Langmuir isotherm and the Freundlich isotherm, and the adsorption processes were spontaneous and exothermic.
