The feasibility of semi solid processing of hypereutectic A390 alloys using a novel rheoforming process was investigated. A combination of the swirl enthalpy equilibration device （SEED） process, isothermal holding u...The feasibility of semi solid processing of hypereutectic A390 alloys using a novel rheoforming process was investigated. A combination of the swirl enthalpy equilibration device （SEED） process, isothermal holding using insulation and addition of solid alloy during swirling was introduced as a novel method to improve the processability of semi solid slurry. The effects of isothermal holding and the addition of solid alloy on the temperature gradient between the centre and the wall and on the formation of a（Al） particles were examined. In additional tests, phosphorus and strontium were added to the molten metal to refine the primary and eutectic silicon structure to facilitate semi solid processing. The results show that the combination of the SEED process with two additional processing steps can produce semi-solid A390 alloys that can be rheoprocessed. The microstructure reveals an adequate amount of non-dendritic a（Al） globules surrounded by liquid, which greatly improves the processability of semi-solid slurry.展开更多
The effect of thixoforming process on morphologies of silicon particles that affect fracture mode of A356 alloy was investigated.Microstructure and fracture surfaces of thixoformed samples were investigated by image a...The effect of thixoforming process on morphologies of silicon particles that affect fracture mode of A356 alloy was investigated.Microstructure and fracture surfaces of thixoformed samples were investigated by image analyzing technique and scanning electron microscopy.A new combination parameter, called silicon density ratio (SDR) index, was introduced.SDR index approximates the collective effects of morphological characteristics of silicon particles on microstructure transparency of alloy in crossing the dislocation.It is suggested that samples with lower SDR index have superior mechanical properties, especially elongation, and consequently intergranular fracture mode.On the contrary, samples with higher SDR index have inferior mechanical properties and fracture path tends to propagate along the cell boundaries leading to transgranular fracture.展开更多
The micro gear mold for powder injection molding was made by electroforming process of Fe-Ni and Fe-Ni-W alloys using UV-lithography process. Kinetics and activation energies in electroplating of both alloys were inve...The micro gear mold for powder injection molding was made by electroforming process of Fe-Ni and Fe-Ni-W alloys using UV-lithography process. Kinetics and activation energies in electroplating of both alloys were investigated to determine the best process conditions. Fe content within electrodeposited Fe-Ni alloys increased with the increase of rotating disk speed and the decrease of temperature and it is considered from the calculated activation energy of iron content that the rate determining step is controlled by mass transfer. Iron content in Fe-Ni electrodeposit varied from 58.33% to 70.45% by increasing current density from 2 to 6 A/drn2. Also, iron content in Fe-Ni-W electrodeposit increased from 59.32% to 70.15%, nickel content decreased from 27.86% to 17.07% and the content of tungsten was almost consistent in the range of 12.78%-12.82% although the current density increases from 1.5 to 5 A/dm^2. For the electroforming of micro gear mold, SU-8 mandrel with 550 μm in diameter and 400 μm in height was prepared by UV-lithography processing. Subsequently, Fe-36Ni and Fe-20Ni-13W alloys micro gear molds were electroformed successfully. Surface hardness values of the electroformed micro molds were measured to be HV490 and HV645, respectively.展开更多
A new Mg-14Al-0.5Mn alloy that exhibits a wide solidification range and sufficient fluidity for semi-solid forming was designed. And the rnicrostructure evolution of semi-solid Mg-14Al-0.5Mn alloy during isothermal he...A new Mg-14Al-0.5Mn alloy that exhibits a wide solidification range and sufficient fluidity for semi-solid forming was designed. And the rnicrostructure evolution of semi-solid Mg-14Al-0.5Mn alloy during isothermal heat treatment was investigated. The mechanism of the microstructure evolution and the processing conditions for isothermal heat treatment were also discussed. The results show that the microstructures of cast alloys consist of α-Mg,β-Mg17Al12 and a small amount of Al-Mn compounds. After holding at 520 ℃ for 3 min, the phases of β-Mg17Al12 and eutectic mixtures in the Mg-14Al-0.5Mn alloy melt and the microstructures of α-Mg change from developed dendrites to irregular solid particles. With increasing the isothermal time, the amount of liquid increases, and the solid particles grow large and become spherical. When the holding time lasts for 20 min or even longer, the solid and liquid phases achieve a state of dynamic equilibrium.展开更多
New sustainable syntheses based on solid-state strategies have sparked enormous attention and provided novel routes for the synthesis of supported metallic alloy nanocatalysts(SMACs).Despite considerable recent progre...New sustainable syntheses based on solid-state strategies have sparked enormous attention and provided novel routes for the synthesis of supported metallic alloy nanocatalysts(SMACs).Despite considerable recent progress in this field,most of the developed methods suffer from either complex operations or poorly controlled morphology,which seriously limits their practical applications.Here,we have developed a sustainable strategy for the synthesis of PdAg alloy nanoparticles(NPs)with an ultrafine size and good dispersion on various carbon matrices by directly grinding the precursors in an agate mortar at room temperature.Interestingly,no solvents or organic reagents are used in the synthesis procedure.This simple and green synthesis procedure provides alloy NPs with clean surfaces and thus an abundance of accessible active sites.Based on the combination of this property and the synergistic and alloy effects between Pd and Ag atoms,which endow the NPs with high intrinsic activity,the PdAg/C samples exhibit excellent activities as electrocatalysts for both the hydrogen oxidation and evolution reactions(HOR and HER)in a basic medium.Pd9Ag1/C showed the highest activity in the HOR with the largest j0,m value of 26.5 A g Pd^–1 and j0,s value of 0.033 mA cmPd^–2,as well as in the HER,with the lowest overpotential of 68 mV at 10 mA cm^–2.As this synthetic method can be easily adapted to other systems,the present scalable solid-state strategy may open opportunity for the general synthesis of a wide range of well-defined SMACs for diverse applications.展开更多
A new process of hydroforming with controllable radial pressure was proposed to overcome difficulties in the forming of low plastic materials and large height-to-diameter ratio workpieces. A typical 5A06 aluminum allo...A new process of hydroforming with controllable radial pressure was proposed to overcome difficulties in the forming of low plastic materials and large height-to-diameter ratio workpieces. A typical 5A06 aluminum alloy dome was numerically and experimentally investigated. The reasons for typical defects were analyzed under different radial pressures. Effects of radial pressure on the thickness distribution were discussed and optimal radial pressure was determined. It is shown by numerical simulations and experiment that a cup with a drawing ratio of 2.4 is formed by the new process of hydroforming with controllable radial pressure. It is significantly effective for the forming of low plastic materials and large height-to-diameter ratio workpieees. Two typical thinning points exit along the dome wall. With the radial pressure, thinning is decreased effectively at the two points, the dome forming is achieved and thickness distribution is more uniform.展开更多
基金the financial support provided by the Natural Sciences and Engineering Research Council of Canada (NSERC) and Rio Tinto Alcan through the NSERC Industrial Research Chair in Metallurgy of Aluminum Transformation at Université du Québec à Chicoutimi
文摘The feasibility of semi solid processing of hypereutectic A390 alloys using a novel rheoforming process was investigated. A combination of the swirl enthalpy equilibration device （SEED） process, isothermal holding using insulation and addition of solid alloy during swirling was introduced as a novel method to improve the processability of semi solid slurry. The effects of isothermal holding and the addition of solid alloy on the temperature gradient between the centre and the wall and on the formation of a（Al） particles were examined. In additional tests, phosphorus and strontium were added to the molten metal to refine the primary and eutectic silicon structure to facilitate semi solid processing. The results show that the combination of the SEED process with two additional processing steps can produce semi-solid A390 alloys that can be rheoprocessed. The microstructure reveals an adequate amount of non-dendritic a（Al） globules surrounded by liquid, which greatly improves the processability of semi-solid slurry.
文摘The effect of thixoforming process on morphologies of silicon particles that affect fracture mode of A356 alloy was investigated.Microstructure and fracture surfaces of thixoformed samples were investigated by image analyzing technique and scanning electron microscopy.A new combination parameter, called silicon density ratio (SDR) index, was introduced.SDR index approximates the collective effects of morphological characteristics of silicon particles on microstructure transparency of alloy in crossing the dislocation.It is suggested that samples with lower SDR index have superior mechanical properties, especially elongation, and consequently intergranular fracture mode.On the contrary, samples with higher SDR index have inferior mechanical properties and fracture path tends to propagate along the cell boundaries leading to transgranular fracture.
文摘The micro gear mold for powder injection molding was made by electroforming process of Fe-Ni and Fe-Ni-W alloys using UV-lithography process. Kinetics and activation energies in electroplating of both alloys were investigated to determine the best process conditions. Fe content within electrodeposited Fe-Ni alloys increased with the increase of rotating disk speed and the decrease of temperature and it is considered from the calculated activation energy of iron content that the rate determining step is controlled by mass transfer. Iron content in Fe-Ni electrodeposit varied from 58.33% to 70.45% by increasing current density from 2 to 6 A/drn2. Also, iron content in Fe-Ni-W electrodeposit increased from 59.32% to 70.15%, nickel content decreased from 27.86% to 17.07% and the content of tungsten was almost consistent in the range of 12.78%-12.82% although the current density increases from 1.5 to 5 A/dm^2. For the electroforming of micro gear mold, SU-8 mandrel with 550 μm in diameter and 400 μm in height was prepared by UV-lithography processing. Subsequently, Fe-36Ni and Fe-20Ni-13W alloys micro gear molds were electroformed successfully. Surface hardness values of the electroformed micro molds were measured to be HV490 and HV645, respectively.
基金Projects(2006BA104B04-1,2006BAE04B07-3)supported by the National Science and Technology Supporting Program of ChinaProject(2007KZ05)supported by the Science and Technology Supporting Project of Changchun City,China+1 种基金Project(2008)supported by the Open Subject of State Key Laboratory of Rare Earth Resource Utilization,ChinaProject supported by the"985 Project"of Jilin University,China
文摘A new Mg-14Al-0.5Mn alloy that exhibits a wide solidification range and sufficient fluidity for semi-solid forming was designed. And the rnicrostructure evolution of semi-solid Mg-14Al-0.5Mn alloy during isothermal heat treatment was investigated. The mechanism of the microstructure evolution and the processing conditions for isothermal heat treatment were also discussed. The results show that the microstructures of cast alloys consist of α-Mg,β-Mg17Al12 and a small amount of Al-Mn compounds. After holding at 520 ℃ for 3 min, the phases of β-Mg17Al12 and eutectic mixtures in the Mg-14Al-0.5Mn alloy melt and the microstructures of α-Mg change from developed dendrites to irregular solid particles. With increasing the isothermal time, the amount of liquid increases, and the solid particles grow large and become spherical. When the holding time lasts for 20 min or even longer, the solid and liquid phases achieve a state of dynamic equilibrium.
文摘New sustainable syntheses based on solid-state strategies have sparked enormous attention and provided novel routes for the synthesis of supported metallic alloy nanocatalysts(SMACs).Despite considerable recent progress in this field,most of the developed methods suffer from either complex operations or poorly controlled morphology,which seriously limits their practical applications.Here,we have developed a sustainable strategy for the synthesis of PdAg alloy nanoparticles(NPs)with an ultrafine size and good dispersion on various carbon matrices by directly grinding the precursors in an agate mortar at room temperature.Interestingly,no solvents or organic reagents are used in the synthesis procedure.This simple and green synthesis procedure provides alloy NPs with clean surfaces and thus an abundance of accessible active sites.Based on the combination of this property and the synergistic and alloy effects between Pd and Ag atoms,which endow the NPs with high intrinsic activity,the PdAg/C samples exhibit excellent activities as electrocatalysts for both the hydrogen oxidation and evolution reactions(HOR and HER)in a basic medium.Pd9Ag1/C showed the highest activity in the HOR with the largest j0,m value of 26.5 A g Pd^–1 and j0,s value of 0.033 mA cmPd^–2,as well as in the HER,with the lowest overpotential of 68 mV at 10 mA cm^–2.As this synthetic method can be easily adapted to other systems,the present scalable solid-state strategy may open opportunity for the general synthesis of a wide range of well-defined SMACs for diverse applications.
基金Projects(50525516, 50875062 ) supported by the National Natural Science Foundation of China
文摘A new process of hydroforming with controllable radial pressure was proposed to overcome difficulties in the forming of low plastic materials and large height-to-diameter ratio workpieces. A typical 5A06 aluminum alloy dome was numerically and experimentally investigated. The reasons for typical defects were analyzed under different radial pressures. Effects of radial pressure on the thickness distribution were discussed and optimal radial pressure was determined. It is shown by numerical simulations and experiment that a cup with a drawing ratio of 2.4 is formed by the new process of hydroforming with controllable radial pressure. It is significantly effective for the forming of low plastic materials and large height-to-diameter ratio workpieees. Two typical thinning points exit along the dome wall. With the radial pressure, thinning is decreased effectively at the two points, the dome forming is achieved and thickness distribution is more uniform.
