在市政污泥和半焦粉成型过程中,为了研究各因素对成型效果的影响,以达到在较少黏结剂添加量的条件下,制备出强度和热值都较高的型煤,开展了市政污泥掺混半焦粉成型因素影响的实验研究。在实验室条件下,以褐煤半焦粉为基本原料,通过添加...在市政污泥和半焦粉成型过程中,为了研究各因素对成型效果的影响,以达到在较少黏结剂添加量的条件下,制备出强度和热值都较高的型煤,开展了市政污泥掺混半焦粉成型因素影响的实验研究。在实验室条件下,以褐煤半焦粉为基本原料,通过添加不同比例的市政污泥和黏结剂,同时调节成型压力,利用压力试验机进行压球并测其强度。在实验过程中,通过对各因素进行优化,得出了污泥半焦粉成型的最佳工艺。结果表明:在黏结剂添加量为2.0%,污泥添加量为20%,成型压力为35 k N的条件下,制得了发热量在22 MJ/kg以上的污泥半焦型煤,为市政污泥的高效清洁利用提供了新途径。展开更多
A dye-sensitized photocatalyst combining Pt-loaded TiO_(2) and Ru(Ⅱ)tris-diimine sensitizer(RuP)was constructed and its activity for photochemical hydrogen evolution was compared with that of Pt-intercalated HCa_(2)N...A dye-sensitized photocatalyst combining Pt-loaded TiO_(2) and Ru(Ⅱ)tris-diimine sensitizer(RuP)was constructed and its activity for photochemical hydrogen evolution was compared with that of Pt-intercalated HCa_(2)Nb_(3)O_(10) nanosheets.When the sacrificial donor ethylenediaminetetraacetic acid(EDTA)disodium salt dihydrate was used,RuP/Pt/TiO_(2) showed higher activity than RuP/Pt/HCa_(2)Nb_(3)O_(10).In contrast,when NaI(a reversible electron donor)was used,RuP/Pt/TiO_(2) showed little activity due to back electron transfer to the electron acceptor(I_(3)-),which was gener-ated as the oxidation product of I-.By modification with anionic polymers(sodium poly(styrenesulfonate)or sodium polymethacrylate)that could inhibit the scavenging of conduction band electrons by I_(3)-,the H_(2) production activity from aqueous NaI was improved,but it did not exceed that of RuP/Pt/HCa_(2)Nb_(3)O_(10).Transient absorption measurements showed that the rate of semiconductor-to-dye back electron transfer was slower in the case of TiO_(2) than HCa_(2)Nb_(3)O_(10),but the electron transfer reaction to I3-was much faster.These results indicate that Pt/TiO_(2) is useful for reactions with sacrificial reductants(e.g.,EDTA),where the back electron transfer reaction to the more reducible product can be neglected.However,more careful design of the catalyst will be nec-essary when a reversible electron donor is employed.展开更多
文摘在市政污泥和半焦粉成型过程中,为了研究各因素对成型效果的影响,以达到在较少黏结剂添加量的条件下,制备出强度和热值都较高的型煤,开展了市政污泥掺混半焦粉成型因素影响的实验研究。在实验室条件下,以褐煤半焦粉为基本原料,通过添加不同比例的市政污泥和黏结剂,同时调节成型压力,利用压力试验机进行压球并测其强度。在实验过程中,通过对各因素进行优化,得出了污泥半焦粉成型的最佳工艺。结果表明:在黏结剂添加量为2.0%,污泥添加量为20%,成型压力为35 k N的条件下,制得了发热量在22 MJ/kg以上的污泥半焦型煤,为市政污泥的高效清洁利用提供了新途径。
文摘A dye-sensitized photocatalyst combining Pt-loaded TiO_(2) and Ru(Ⅱ)tris-diimine sensitizer(RuP)was constructed and its activity for photochemical hydrogen evolution was compared with that of Pt-intercalated HCa_(2)Nb_(3)O_(10) nanosheets.When the sacrificial donor ethylenediaminetetraacetic acid(EDTA)disodium salt dihydrate was used,RuP/Pt/TiO_(2) showed higher activity than RuP/Pt/HCa_(2)Nb_(3)O_(10).In contrast,when NaI(a reversible electron donor)was used,RuP/Pt/TiO_(2) showed little activity due to back electron transfer to the electron acceptor(I_(3)-),which was gener-ated as the oxidation product of I-.By modification with anionic polymers(sodium poly(styrenesulfonate)or sodium polymethacrylate)that could inhibit the scavenging of conduction band electrons by I_(3)-,the H_(2) production activity from aqueous NaI was improved,but it did not exceed that of RuP/Pt/HCa_(2)Nb_(3)O_(10).Transient absorption measurements showed that the rate of semiconductor-to-dye back electron transfer was slower in the case of TiO_(2) than HCa_(2)Nb_(3)O_(10),but the electron transfer reaction to I3-was much faster.These results indicate that Pt/TiO_(2) is useful for reactions with sacrificial reductants(e.g.,EDTA),where the back electron transfer reaction to the more reducible product can be neglected.However,more careful design of the catalyst will be nec-essary when a reversible electron donor is employed.
