成岩相的形成、分类与定量评价方法

根据成岩作用和成岩相对储集层发育的控制作用及与储集层分布的关系,探讨成岩相的形成机理、划分方案与评价方法及其在油气勘探中的应用和意义。针对碎屑岩、碳酸盐岩和火山岩等扩容性成岩相,提出了有机酸性水溶解作用、白云石化等8种主要成岩作用机理。划分出9类扩容性成岩相和7类致密化成岩相,提出了反映岩性、成岩作用和孔渗性3个层次内容的"孔渗级别+岩石类型+成岩作用类型"的成岩相命名方案。在成岩相勘探评价中,强调根据沉积相、测井相、地震相和岩心薄片等综合定量预测,提出了"四个步骤"、"三图叠合"的评价方法和成图方式,根据不同成岩相类型的分布预测有利储集体、"甜点"、成岩圈闭及油气成藏。指出了成岩相的发展方向及成岩学的设想和思考。

火山岩储层特征与油气成藏模式研究

火山岩油气藏的勘探历史已经有一百二十多年,经历了偶然发现、初步勘探和深入研究三个发展阶段,火山岩从油气勘探的禁区转变为重要领域.目前火山岩油气藏在油气总量中占的比例并不大,但是已展现出良好的油气前景,成为新的油气增长点,越来越受到油气勘探界的重视.本文分析了火山岩岩性、岩相的研究现状,将火山岩的储集空间分为原生孔隙、原生裂缝、次生孔隙、次生裂缝4个大类,13个小类.火山岩的成藏模式有岩性成藏模式、构造成藏模式、构造-岩性成藏模式、风化壳成藏模式等.针对火山岩储层的复杂性,亟需以火山岩储层地质理论为指导,结合岩心、重磁力、测井、地震资料,建立一套有针对性的研究方法,全面评价火山岩储层特征和空间展布.

Chemical Constituents of Hedysarum gmelinii

To study the chemical constituents of Hedysarum gmelinii. Methods Theconstituents were separated and purified by different methods of chromatography, and theirstructures were elucidated by DR, MS and NMR. Results Eight compounds were isolated from Hedysarumgmelinii, including three triteipenoids, two flavonoids and two other compounds. Their structureswere identified as squasapogenol (1), soyasapogenol (2), lupeol (3), 3, 9-dihydroxy coumestan (4),3-hydroxy-9-me-thoxy pterocarpan (5), β-sitosterol (6), palmatic acid (7), and hexadecanoic acid 2,3-dihydroxypropyl ester (8). Conclusion All the compounds have been isolated from this plant forthe first time. Compounds 1 — 4 and 8 were obtained from this genus for the first time. The NMRdata of 1 are reported for the first time.

Rock-forming mechanism of Qingshanjiao intrusion in Dongguashan copper(gold) deposit, Tongling area, Anhui province, China

Dongguashan deposit is a large porphyry-skarn copper（gold） deposit in Tongling ore district. The Qingshanjiao intermediate acid intrusion of Yanshanian had a direct genetic relationship with mineralization. The magma origin, rock-forming dynamic background and rock-forming process were studied, and the rock-forming mechanism of Qingshanjiao intrusion was discussed, based on geological characteristics, detailed observation of petrography and systematic investigation of petrochemistry, trace elements and REE geochemistry characteristics of Qingshanjiao intrusion. The results show that Qingshanjiao rock body belongs to high-K calc-alkaline series with higher LREE elements, Th, Rb and Sr abundance, but depleted in HREE elements, Ba, Nb and Ta. The primary magma originated from the mantle-crust mixtures which were caused by basaltic magma of mantle mixing with syenite magma of partial melting of the lower crust, and the formation environment of Qingshanjiao intrusion was emplaced in the transitional environment from compression to extension. The Harker diagram and hybrid structures of plagioclase and potassium feldspar indicate that the fractional crystallization occurred in the process of magmatic evolution. The petrochemistry, trace elements and REE geochemistry characteristics indicate that the magma was contaminated by crustal material during the rock-forming. These results suggested that the Qingshanjiao intrusion was formed by fractional crystallization and assimilation and hybridization of mantle-crust magma in the transitional environment from compression to extensional.

Geochemistry of intrusive rock in Dachang tin-polymetallic ore field, Guangxi, China: Implications for petrogenesis and geodynamics

The major element, trace element and rare earth element（REE） of the intrusion rock from the Dachang ore field in Guangxi, China, were analyzed. The results show that the phenocryst（about 15%） and matrix（about 85%） mainly consist of quartz, K-feldspar and plagioclase. The rock is composed of low content of Si and high content of Al2O3, low contents of Ca, Fe2O3, Na, TiO2, etc. The intrusion rock has the medium alkali content, attributing to K-rich type rock; and contains medium to low REE contents, of which light rare earth elements（LREEs） and heavy rare earth elements（HREEs） are highly fractionated, showing a weak negative Ce anomaly and a negative Eu anomaly. These rocks are enriched in LREE, and the large ion lithophytes elements（LILE） are rich in Rb, Sr, and U; the high-field-strength elements（Nb, Th, etc） are relatively depleted. The REE chondrite-normalized patterns are consistent with the overall, roughly indicating their similar characteristics, sources and evolution. The intrusion rock mainly formed during the collisional and within-plate periods.

Petrogenesis of skarn in Shizhuyuan W-polymetallic deposit, southern Hunan,China:Constraints from petrology,mineralogy and geochemistry

Skarn is the main altered rock type and is of great importance to mineralization and ore-prospecting in the Shizhuyuan area of Hunan province, China. Its features of petrography, mineralogy and geochemistry were studied systematically. The results show that the skarn mainly consists of garnet skarn, secondary wollastonite-garnet skarn, tremolite-clinozoisite skarn, and few wolframine garnet skarn, idocrase-garnet skarn and wollastonite skarn with granoblastic texture, granular sheet crystalloblastic texture, and massive structure, disseminated structure, mesh-vein structure, comb structure, and banded structure. And, it is mainly composed of garnet, fluorite, chlorite, hornblende, epidote, tremolite, plagioclase, biotite, muscovite, plagioclase, quartz, idocrase, and calcite and so on. The chemical components mainly include SiO2, Al2O3, Fe2O3, MgO and CaO, and the trace elements and REEs consist of Li, Be, V, Co, Zn, Ga, Rb, Sr, Y, Ce, Nd, Pb and Bi, etc. And, the obvious fractionation exists between LREE and HREE, and it shows typical features of Nanling ore-forming granite for W？Sn polymetallic deposit. Skarn is derived from the sedimentary rock, such as limestone, mudstone, argillaceous rock, and few pelitic strips. It is affected by both Shetianqiao formation strata and Qianlishan granite during the diagenesis, indicating a strong reduction environment. The occurrence of skarn, whose mutation site is favorable to the mineralization enrichment, is closely related to the mineralization and prospecting.

三种典型火山岩储层的特征和综合预测研究

火山岩油气藏已经成为油气勘探的重要靶区,但火山岩储层的发育特点和成藏理论并不完善,针对火山岩储层的勘探尚未形成一套完善的预测思路。通过对国内外火山岩油气藏的特征分析,总结了原生孔隙型、风化壳型和构造裂缝型3种典型火山岩油气藏的成藏特点,结合这3种油气藏的特点和准噶尔盆地4个工区的勘探实践,提出了一套综合预测思路,主要包括岩性岩相预测、物性预测和流体预测3个方面。

Geochemistry and petrology of rift-related mafic sills and arc-related Gabbro–Diorite bodies, Northern Bafq District,Central Iran

Two types of mafic intrusions have been recognized in the north of the Bafq district, Central Iran. A number of olivine-gabbroic to gabbroic sills intruded the Rizu Formation, comprised of alternating carbonate and volcanic rocks. Mineralogical data show that olivine + pyroxene +brown amphibole(kaersutite) + calcic plagioclase +opaque comprise the olivine-gabbroic rocks, and intermediate(or sodic) plagioclase + altered pyroxene and altered amphibole to biotite + opaque minerals the gabbroic rocks.Both rock types have shown within-plate and alkaline characters and have been presumed to be related to rift formation. The mafic-alkaline magma source of the sills is proposed to have been derived from enriched mantle.Regionally, two Gabbro–Diorite intrusions have been identified in the metamorphic complexes. Mineralogical data suggest that the pyroxene + amphibole(hornblende) +plagioclase + biotite + opaque minerals formed the gabbro to diorite intrusions. These rocks have shown characteristics of calc-alkaline and volcanic arc magmatism.

Zircon geochemistry of different intrusive phases of Weiya pluton: implications for magma genesis

The characteristics of hosted magmas and their petrogenesis based on electron microprobe determination of trace element contents in zircons were discussed. Trace element geochemistry of zircons indicates that zircons in both gabbro and quartz syenite have two-generations. Zircons of the first generations are crystallized in the magma chamber, whereas those of the second generations are formed in supercooling environment. The former is richer in Zr, but poorer in U, Th, Hf and Y. Quartz diorite porphyrite contains zircons that can be distinguished into the early and late generations. Compared to the late generation, the early generation is richer in Zr but poorer in U, Th, Hf and Y. No conspicuous disruption of zircon evolution has been found in both biotite monzogranite and fine-grained granite. However, the content of zircon in fine-grained granite is higher in U, Th and Y and lower in Zr relative to biotite monzogranite without significant contrast in mass fraction ratio of ZrO2 to HfO2 ratio. Such differences in zircon geochemistry of various intrusive phases and the occurrence of the two zircon generations within a single intrusive phase suggest that these phases of magmas are generated from diverse sources during post-collisional continental extension. These magmas ascend rapidly and cool quickly in a short interval.

Research on inspection of stability of subsiding area in composite rock-mass roadway

The research concentrates mainly on the development of failure process in composite rock-mass through acoustic emission, convergence inspection, stress measurement, subside area measurement, level measurement in the process of stability and safety monitoring as well as inspecting of subside area in composite hard rock. In terms of the modern signal analysis technology, various aspects are discussed. The monitoring result and the stability of rock mass can be synthetically evaluated and inferred, and the location of acoustic origin according to the acoustic emission regularity can be successfully detected. Finally the key factors of the deformation can be inferred from in subside area.

Log evaluation of fractured igneous reservoirs in Songliao Basin

The petrophysical parameters are bad in most igneous reservoirs of Songliao Basin because of the very low porosity and permeability.The evaluation of igneous reservoirs has not been fully studied so far.The current technique of formation evaluation and interpretation used in sedimentary formations face a series of problems and difficulties.In this study,The PCA was used to identify lithology,a multi-mineral model "QAPM" was proposed."Surface effect" must be considered when evaluating saturation.A software "SIMPLE" was developed and was used to deal with the logging data in over 70 wells with good results were achieved.

Zircon U-Pb geochronology and geochemistry of Early Cretaceous granodiorite porphyries in Hutouya,western Shandong and their implications for petrogenesis

Zircon LA-ICP-MS U-Pb age and whole-rock geochemistry data are presented for the Hutouya grano-diorite porphyries in Mengyin, western Shandong, to restrict its petrogenesis. The analyzed zircons exhibit os-cillatory growth zoning and core-rim textures in the cathodoluminescence images and have high Th/U ratios （0.04-1.66）,indicating its magmatic origin. The youngest group of magmatic zircon yields weighted mean 206Pb/238U age of 132 ±2 Ma, which represents the forming age of the granodiorite porphyries, i. e., the Early Cretaceous. The oldest group of magmatic zircon 207Pb/206Pb ages ranges from 2 398 Ma to 2 370 Ma, yielding a weighted mean age of 2 389 ±23 Ma,suggesting that the basement of the North China Craton should exist in the research area. Geochemically, the samples are characterized by high Si02（70. 38% and 64. 87% ） , low MgO （0.60% and 1. 53% ） and Mg# values （42. 92 and 50. 42）. Moreover, they show enrichment of light rare earth elements and large ion lithophile elements （e. g. Rb, Ba and K） , depletion of heavy rare earth ele-ments and high field strength elements （e. g. Nb and Ta） , positive anomaly of Pb, and negative anomaly of Ti. These results, together with previously published data, indicate that the Hutouya granodiorite porphyries were derived from partial melting of a delaminated lower continental crust and subsequent interaction with the mantle peridotites. They are consistent with the period of lithospheric thinning beneath the eastern North China Craton and may be formed in an extensional tectonic environment.

Sediment recycling and indication of weathering proxies

As a result of recycling, the mineralogical and chemical compositions of riverine sediments may reflect the combined effects of the present-day weathering regime as well as previous weathering and diagenetic alteration history. River sediments can be interpreted as a mixture of non-weathered bedrock—of igneous, metamorphic, or sedimentary origin—and solids formed by the modern weathering system. The correlation between the weathering proxies chemical index of alteration and weathering index of Parker offers an approach to distinguish fine suspended particles, coarse bedload sediments, and recycled sediments under the influence of quartz dilution. Recycling of cation-depleted source rocks formed during past geological weathering episodes may have great impacts on the weathering indices of sediments from the Changjiang(Yangzte) and Zhuoshui Rivers. Special caution is required when using chemical weathering indices to investigate the intensity of chemical weathering registered in fluvial sediments. To minimize the effect of hydrodynamic sorting or sediment recycling, we suggest that the fine sediments(e.g.suspended particles and ﹤2 lm fractions of bedload sediments) in rivers better reflect the average of weatheredcrust in catchments and the terrigenous end-member in marginal seas.

PALAEOZOIC TECTONIC PALAEOGEOGRAPHY OF THE CATHAYSIA IN EASTERN ZHE JIANG AND NORTHERNFUJIAN, CHINA

Based on the data about sedimentary facies and palaeogeography, this paper proves the existence of the Cathaysia (the part in eastern Zhejiang and northern Fujian, the same hereinafter) and makes a survey about its palaeogeography since Sinian Period. It also discusses the evolution of the tectonic environment of this region during Phanerozoic Eon, according to the features such as the composition of sandstones derived from the old land and alkalinity of volcanic rocks and so on. Continuous uplifting was maintained in Cathaysia during Sinian Period and Paleozoic Era, typically with no significant tectono-magmatic activity being observed. Its northwestern margin belongs to the type of passive continental margin during the middle and late phase of Caledonian Cycle. It showed the characteristics of a steady continent in late Paleozoic era, but was turned quickly into an active continental margin after the middle Jurassic period.

Cu and Zn Speciation in an Acid Soil Amended withAlhalline Biosolids

Fractionation of metals in acid sandy loam soil amended withalkaline-stabilised sewage sludge biosolids was conducted in order toassess metal bioavailability and environmental mobility. Soilsolution was extracted by a centrifugation and filtration technique.Meal speciation in the soil solution was determined by a cationexchange resin method. Acetic acid and EDTA extracting solutions wereused for extraction of metals in soil solid surfaces. Metaldistribution in different fractions of soil solid phase wasdetermined using a three-step sequential extraction scheme.

Origin of Early Creceouscalc-alkaline granite, Taxkorgan: Implications for evolution of Tethys evolution in central Pamir

The Pamir plateau may have been a westward continuation of Tibet plateau.Meanwhile,the Rushan-Pshart suture is correlative to the Bangong-Nujiang suture of Tibet,and the Central Pamir is the lateral equivalent of the Qiangtang Block.We present the first detailed LA-ICPMS zircon U-Pb chronology,major and trace element,and Lu-Hf isotope geochemistry of Taxkorgan two-mica monzogranite to illuminate the Tethys evolution in central Pamir.LA-ICPMS zircon U-Pb dating shows that two-mica monzogranite is emplaced in the Cretaceous(118 Ma).Its geochemical features are similar to S-type granite,with enrichment in LREEs and negative Ba,Sr,Zr and Ti anomalies.All the samples show negative zirconεHf(t)values ranging from 17.0 to 12.5(mean 14.5),corresponding to crustal Hf model(TDM2)ages of 1906 to 2169 Ma.It is inferred that these granitoids are derived from partial melting of peliticmetasedimentary rocks analogous to the Paleoproterozoic Bulunkuole Group,predominantly with muscovite schists component.Based on the petrological and geochemical data presented above,together with the regional geology,this work provides new insights that Bangong Nujiang Ocean closed in Early Cretaceous(120114 Ma).

Petrological characteristics,geochemical feature and metallogenetic relation of alkaline-rich rocks in northwest of Yunan Province,China

The alkali-rich rocks, spreading along the suture zone of Jingsha River, refer to the alkali-rich porphyry rocks, which emplace during the Himalaya epoch in northwest of Yunnan Province, and consist of syenit, syenit porphyry, monzonite porphyry and granite porphyry. Petrological chemical analysis results suggest that silica is poor and aluminum is rich, and high potassium large ion lithophile elements （LILE）, light rare earth element （LREE） and Sr are obviously detracted in these rocks. High field strength elements （HFSE） and heavy rare earth element （HREE） are depleted, especially Nb, Ta, P and Ti. 8Eu： 0.09--1.64 shows that plagioclase does not appear fractional crystallization during the formation of alkali-rich rocks, t^348, H and O isotopes and Pb isotopes suggest that ore-forming fluid is derived from the mantle, and Pb is possibly mixed by mantle, wall rock and crust. The age of Pb in alkali-rich rocks is about 250-220 Ma. The age of alkali porphyry rock （dykes） varies from 30 Ma to 50 Ma. Alkali rocks have strong metallogenetic relation. Au mineralization is associated to the alkali magrnatic activities with a relatively high temperature, low pressure and high oxygen fugacity. However, copper mineralization is mainly associated with alkali-sub-alkali magmatic activities in a process of relatively low temperature, high pressure and lower oxygen fugacity.

Study of the engineering geologic feature of weathering zone of bedrock in 810 producing area of Luling Mine

For a safe extracting of the mine resource of the razor thin capping rock, a study of waterproof, sand prevention, roof fall prevention must be made. As a result, it’s necessary to master the engineering feature of weathering zone of bedrock. According to the lithology appraisal and X diffract analyses, the mineral feature of weathering zone of bedrock in 810 producing area has been studied in this article. By testing the physical mechanics index of weathering zone, we have found out some features of physical mechanic quality. Utilizing the determined result of viscosity index and slaking test, we reach a conclusion of the water stability of weathering zone, that is the weathering zone rock belongs to the type that is easily slaked when encountered water and the water stability is weak.

Petrographic characterization and evolution of the Karharbari coals, Talcher Coalfield, Orissa, India

In the present study an attempt has been made to carry out the detailed petrographic characterization of the Karharbari coals of Talcher coalfield and to reconstruct the paleoenvironment conditions of coal formation using macerals and microlithtotypes as a tool. For these purposes a large number of samples were collected following the pillar sampling method and were subjected to detailed petrographic study. The petrographic observation shows that these coals are vitrinite rich followed by the liptinite and inertinite group of macerals. On microlithotype scale, these coals shows the dominance of the vitrite followed by clarite, vitrinertite and inertite. The concentration of liptite, clarodurite, duroclarite and vitriner- toliptite are insignificant. The vitrinite reflectance ranks the Karharbari coal as high volatile bituminous ＇C＇ to high volatile ＇B＇ bituminous. Coal petrography based depositional models suggest peat accumulation in forested telmatic swamp. Moreover, during the time of their evolution, there were alternate phases of oxic and anoxic moor conditions with good tissue preservation.

Fracture evolution and localization effect of damage in rock based on wave velocity imaging technology

By utilizing wave velocity imaging technology,the uniaxial multi-stage loading test was conducted on siltstone to attain wave velocity imagings during rock fracture.Based on the time series parameters of acoustic emissions(AE),joint response characteristics of the velocity field and AE during rock fracture were analyzed.Moreover,the localization effect of damage during rock fracture was explored by applying wave velocity imagings.The experimental result showed that the wave velocity imagings enable three-dimensional(3-D)visualization of the extent and spatial position of damage to the rock.A damaged zone has a low wave velocity and a zone where the low wave velocity is concentrated tends to correspond to a severely damaged zone.AE parameters and wave velocity imagings depict the changes in activity of cracks during rock fracture from temporal and spatial perspectives,respectively:the activity of cracks is strengthened,and the rate of AE events increases during rock fracture;correspondingly,the low-velocity zones are gradually aggregated and their area gradually increases.From the wave velocity imagings,the damaged zones in rock were divided into an initially damaged zone,a progressively damaged zone,and a fractured zone.During rock fracture,the progressively damaged zone and the fractured zone both develop around the initially damaged zone,showing a typical localization effect of the damage.By capturing the spatial development trends of the progressively damaged zone and fractured zone in wave velocity imagings,the development of microfractures can be predicted,exerting practical significance for determining the position of the main fracture.