Utilization of polyvinylidene difluoride, PVDF, as the disperse phase and thermal plastic polyurethane, PU, as the continuous phase, the PU/PVDF blend hollow fiber membranes with the property of pressure-responsibilit...Utilization of polyvinylidene difluoride, PVDF, as the disperse phase and thermal plastic polyurethane, PU, as the continuous phase, the PU/PVDF blend hollow fiber membranes with the property of pressure-responsibility, PR, was prepared by melt.spinning. For these hollow fibers, the formation of the interracial micro-voids, IFM, and the spinablllty of the blend were analyzed. The pressm-e-responslblllty was studied by measuring the changing of pure water flux, PWF, with the pressure, and the influence of drawing and heat-setting on the structure and pressure-responsibility of the membranes were also discussed.展开更多
A group of grafted PET fibers with different graft yield are formed by grafting acrylamide onto the PET main chains. The structure of grafted fibers are studied by scanning electronic microscope ( SEM ), infra-red spe...A group of grafted PET fibers with different graft yield are formed by grafting acrylamide onto the PET main chains. The structure of grafted fibers are studied by scanning electronic microscope ( SEM ), infra-red spectrophotometer ( IR ), and differential scanning calorimetry(DSC). At the same time, the moisture regain, dyeability, strength, and elongation at break of the samples are measured and their relations with structural changes are discussed. Compared with ungrafted fiber, shape of the fiber cross-section, IR characteristic absorption peaks, and melting behavior of the grafted fibers have been changed, causing the fiber dyeability and moisture regain to be increased, and mechanical properties to be changed.展开更多
基金Supported by the Fund of Ministry of Education (No.20040058002) and the Fund of Science Council of Tianjin (No.043102711)
文摘Utilization of polyvinylidene difluoride, PVDF, as the disperse phase and thermal plastic polyurethane, PU, as the continuous phase, the PU/PVDF blend hollow fiber membranes with the property of pressure-responsibility, PR, was prepared by melt.spinning. For these hollow fibers, the formation of the interracial micro-voids, IFM, and the spinablllty of the blend were analyzed. The pressm-e-responslblllty was studied by measuring the changing of pure water flux, PWF, with the pressure, and the influence of drawing and heat-setting on the structure and pressure-responsibility of the membranes were also discussed.
文摘A group of grafted PET fibers with different graft yield are formed by grafting acrylamide onto the PET main chains. The structure of grafted fibers are studied by scanning electronic microscope ( SEM ), infra-red spectrophotometer ( IR ), and differential scanning calorimetry(DSC). At the same time, the moisture regain, dyeability, strength, and elongation at break of the samples are measured and their relations with structural changes are discussed. Compared with ungrafted fiber, shape of the fiber cross-section, IR characteristic absorption peaks, and melting behavior of the grafted fibers have been changed, causing the fiber dyeability and moisture regain to be increased, and mechanical properties to be changed.
