As a key technology of rapid prototyping and manufacturing (RP&M), rapid manufacturing of metal parts is a target of RP&M. Introducing selective laser sintering (SLS), an important branch of RP&M, this pap...As a key technology of rapid prototyping and manufacturing (RP&M), rapid manufacturing of metal parts is a target of RP&M. Introducing selective laser sintering (SLS), an important branch of RP&M, this paper gives a new method oriented on low power SLS system to fabricate metal parts. With this kind of technology, the mixture of metal and polymer powder is sintered first to get green part, then, after debinding and metal infiltration, dense parts are gotten. In the end, influencing factors of this technology are analyzed. At the same time, some applications are given.展开更多
Igneous rocks in the South China Sea have broad prospects for oil and gas exploration.Integrated geophysical methods are important approaches to study the distribution of igneous rocks and to determine and identify ig...Igneous rocks in the South China Sea have broad prospects for oil and gas exploration.Integrated geophysical methods are important approaches to study the distribution of igneous rocks and to determine and identify igneous rock bodies.Aimed at the characteristics of gravity and magnetic fields in the South China Sea,several potential field processing methods are preferentially selected.Reduction to the pole by variable inclinations in the area of low magnetic latitudes is used to perform reduction processing on magnetic anomalies.The preferential continuation method is used to separate gravity and magnetic anomalies and extract the gravity and magnetic anomaly information of igneous rocks in the shallow part of the South China Sea.The 3D spatial equivalent distribution of igneous rocks in South China Sea is illustrated by the 3 D correlation imaging of magnetic anomalies.Since the local anomaly boundaries are highlighted gravity and magnetic gradients,the distribution characters of different igneous rocks are roughly outlined by gravity and magnetic correlation analysis weighted by gradient.The results show the distribution of igneous rocks is controlled and influenced by deep crustal structure and faulting.展开更多
ZSM-5 zeolites were directly synthesized on the surface of honeycomb cordierite substrates by hydrothermal method and certified by XRD and SEM techniques; the adhesion of ZSM-5 coatings was evaluated by ultrasonic vib...ZSM-5 zeolites were directly synthesized on the surface of honeycomb cordierite substrates by hydrothermal method and certified by XRD and SEM techniques; the adhesion of ZSM-5 coatings was evaluated by ultrasonic vibration. Cu-ZSM-5/cordierite monolithic catalyst was prepared by ion-exchange and impregnation method and applied for the selective catalytic reduction (SCR) of NO by NH3 using a simulated diesel exhaust. The results show that the cordierite surface is almost completely covered by ZSM-5 crystals and the crystallization time greatly impacts the loadings and adhesion of ZSM-5 coatings on substrate, the NOx removal rate over Cu-ZSM-5/cordierite is above 90% in a temperature range of 240-480℃. Moreover, Cu-ZSM-5/cordierite prepared by different methods shows a wide temperature window (240-540 ℃) with high NO removal activities.展开更多
The absorbing process in isolating and coating process of α-olefin drag reducing polymer was studied by molecular dynamic simulation method, on basis of coating theory of α-olefin drag reducing polymer particles wit...The absorbing process in isolating and coating process of α-olefin drag reducing polymer was studied by molecular dynamic simulation method, on basis of coating theory of α-olefin drag reducing polymer particles with polyurethane as coating material. The distributions of sodium laurate, sodium dodeeyl sulfate, and sodium dodeeyl benzene sulfonate on the surface of α-olefin drag reducing polymer particles were almost the same, but the bending degrees of them were obviously different. The bending degree of SLA molecules was greater than those of the other two surfactant molecules. Simulation results of absorbing and accumulating structure showed that, though hydrophobie properties of surfactant molecules were almost the same, water density around long chain sulfonate sodium was bigger than that around alkyl sulfate sodium. This property goes against useful absorbing and accumulating on the surface of α-olefin drag reducing polymer particles; simulation results of interactions of different surfactant and multiple hydroxyl compounds on surface of particles showed that, interactions of different surfaetant and one kind of multiple hydroxyl compound were similar to those of one kind of surfaetant and different multiple hydroxyl compounds. These two contrast types of interactions also exhibited the differences of absorbing distribution and closing degrees to surface of particles. The sequence of closing degrees was derived from simulation; control step of addition polymerization interaction in coating process was absorbing mass transfer process, so the more closed to surface of particle the multiple hydroxyl compounds were, the easier interactions With isoeyanate were. Simulation results represented the compatibility relationship between surfactant and multiple hydroxyl compounds. The isolating and coating processes of α-olefin drag reducing polymer were further understood on molecule and atom level through above simulation research, and based on the simulation, a referenced theoretical basis was provided for practical optimal selection and experimental preparation of α-olefin drag reducing polymer particles suspension isolation agent.展开更多
The mechanism of antithrombotic of Dahuangzhechong Fang separated and purified by Ti-Al intermetallic compound porous material (TAICPM) was researched. Dahuangzhechong Fang, which was isolated and screened by TAICPM, ...The mechanism of antithrombotic of Dahuangzhechong Fang separated and purified by Ti-Al intermetallic compound porous material (TAICPM) was researched. Dahuangzhechong Fang, which was isolated and screened by TAICPM, was used to oral rats. At the end of study, their blood and thrombus were collected. The results show that TAICPM with the pore size of 1-5 μm can screen Dahuangzhechong Fang well. Dahuangzhechong Fang can increase 6-keto-PGF1α, lower content of TXD2 and platelet. Dahuangzhechong Fang has good effect to resist arterial thrombosis.展开更多
Cu-SAPO-34/cordierite catalysts were prepared via one-step hydrothermal synthesis method and their performances to remove NO x from the diesel vehicle exhaust were evaluated. The morphology, structure, Cu content and ...Cu-SAPO-34/cordierite catalysts were prepared via one-step hydrothermal synthesis method and their performances to remove NO x from the diesel vehicle exhaust were evaluated. The morphology, structure, Cu content and valence state were characterized by SEM, XRD, ICP and XPS, respectively. The experimental results show the active component Cu of the catalysts via in situ synthesis could significantly improve the selective catalytic reduction (SCR) activities of NOx and the optimal Cu content is in the range of 0.30%-0.40%(mass fraction). No N 2 O is detected by gas chromatograph (GC) during the evaluation process, which implies that NOx is almost entirely converted to N2 over Cu-SAPO-34/cordierite catalyst. The conversion rate of NOx to N2 by NH3 over catalyst could almost be up to 100%in the temperature range of 300-670 ℃with a space velocity of 12000 h-1 and it is still more than 60% at 300-620 ℃ under 36000 h-1. The catalysts also show the good hydrothermal and chemical stability at the atmosphere with H 2 O.展开更多
We provide a new way to prepare ZnO nanorods pattern from the solution composed of hexamethylenetetramine (HMT) and Zn(NO3)2. The substrate is ITO substrate covered by well ordered Au islands. Since Au and the und...We provide a new way to prepare ZnO nanorods pattern from the solution composed of hexamethylenetetramine (HMT) and Zn(NO3)2. The substrate is ITO substrate covered by well ordered Au islands. Since Au and the underneath ITO substrate have two different nucleation rates in the initial stage of heterogeneous nucleation process, the subsequent ZnO growth on the quick nucleating area takes place under diffusion control and is able to confine the synthesis of ZnO nanorods to specific locations. The concentrations of zinc nitrate and HMT are well adjusted to show the possibility of the new route for the patterning of the ZnO nanorods. Furthermore, the nanorods pattern was characterized by X-ray diffraction and photoluminescence and the performance of field emission property from ZnO nanorod patterns was investigated. The ZnO nanorods pattern with a good alignment also shows a good field enhancement behavior with a high value of the field enhancement factor.展开更多
Objective To screen and identify genetic loci affecting the active zone formation in C. elegans. Methods A SYD-2::GFP reporter was constructed and used as an active zone marker for forward genetic screen to identify...Objective To screen and identify genetic loci affecting the active zone formation in C. elegans. Methods A SYD-2::GFP reporter was constructed and used as an active zone marker for forward genetic screen to identify genetic loci affecting the active zone formation. Results Eight isolated mutant alleles were characterized from 15,000 haploid genomes. The SYD-2::GFP phenotypes of these mutants are mainly reflected as the changes of number, morphology, distribution of puncta and the gaps appearance. Some mutants also exhibit visible behavioral or physical phenotypes, and aldicarb resistant or sensitive phenotypes. Conclusion These mutants provide the opportunity for further systematic research on the active zone formation and the neurotransmission.展开更多
Based on the deficiency of time convergence and variability of Web services selection for services composition supporting cross-enterprises collaboration,an algorithm QCDSS(QoS constraints of dynamic Web services sele...Based on the deficiency of time convergence and variability of Web services selection for services composition supporting cross-enterprises collaboration,an algorithm QCDSS(QoS constraints of dynamic Web services selection)to resolve dynamic Web services selection with QoS global optimal path,was proposed.The essence of the algorithm was that the problem of dynamic Web services selection with QoS global optimal path was transformed into a multi-objective services composition optimization problem with QoS constraints.The operations of the cross and mutation in genetic algorithm were brought into PSOA(particle swarm optimization algorithm),forming an improved algorithm(IPSOA)to solve the QoS global optimal problem.Theoretical analysis and experimental results indicate that the algorithm can better satisfy the time convergence requirement for Web services composition supporting cross-enterprises collaboration than the traditional algorithms.展开更多
Silicon carbide(SiC)was used as a support for SSZ‐13zeolite in an attempt to improve the high‐temperature stability and activity of Cu/SSZ‐13in the selective catalytic reduction(SCR)of NO with NH3.SSZ‐13was grown ...Silicon carbide(SiC)was used as a support for SSZ‐13zeolite in an attempt to improve the high‐temperature stability and activity of Cu/SSZ‐13in the selective catalytic reduction(SCR)of NO with NH3.SSZ‐13was grown via a hydrothermal method using the silicon and silica contained in SiC as the source of silicon,which led to the formation of a chemically bonded SSZ‐13layer on SiC.Characterization using X‐ray diffraction,scanning electron microscopy,and N2adsorption‐desorption isotherms revealed that the alkali content strongly affected the purity of zeolite and the crystallization time affected the coverage and crystallinity of the zeolite layer.Upon ion exchange,the resulting Cu/SSZ‐13@SiC catalyst exhibited enhanced activity in NH3‐SCR in the high‐temperature region compared with the unsupported Cu/SSZ‐13.Thus,the application temperature was extended with the use of SiC as the support.?2018,Dalian Institute of Chemical Physics,Chinese Academy of Sciences.Published by Elsevier B.V.All rights reserved.展开更多
A series of meso‐microporous copper‐supporting chabazite molecular sieve(CuSAPO‐34) catalysts with excellent performance in low‐temperature ammonia selective catalytic reduction(NH3‐SCR)have been synthesized ...A series of meso‐microporous copper‐supporting chabazite molecular sieve(CuSAPO‐34) catalysts with excellent performance in low‐temperature ammonia selective catalytic reduction(NH3‐SCR)have been synthesized via a one‐pot hydrothermal crystallization method. The physicochemical properties of the catalysts were characterized by scanning electron microscopy, transmission electron microscopy, N2 adsorption‐desorption measurements, X‐ray diffraction, 27 Al magic angle spinning nuclear magnetic resonance, diffuse reflectance ultraviolet‐visible spectroscopy, inductively coupled plasma‐atomic emission spectroscopy, X‐ray photoelectron spectroscopy, temperature‐programmed reduction measurements, and electron paramagnetic resonance analysis. The formation of micro‐mesopores in the Cu‐SAPO‐34 catalysts decreases diffusion resistance and greatly improves the accessibility of reactants to catalytic active sites. The main active sites for NH3‐SCR reaction are the isolated Cu^2+ species displaced into the ellipsoidal cavity of the Cu‐SAPO‐34 catalysts.展开更多
An efficient new method has been developed to synthesize N2‐alkyl 1,2,3‐triazole products by tol‐uenesulfonic acid (TsOH) catalyzed addition of N1‐Ts substituted 1,2,3‐triazoles to olefins. The reac‐tions of m...An efficient new method has been developed to synthesize N2‐alkyl 1,2,3‐triazole products by tol‐uenesulfonic acid (TsOH) catalyzed addition of N1‐Ts substituted 1,2,3‐triazoles to olefins. The reac‐tions of monosubstituted and unsubstituted triazole substrates with various olefins, including vinyl esters, are explored.展开更多
A catalyst consisting of platinum nanoparticles on a ZIF-8 support(Pt@ZIF-8) was synthesized in a straightforward one-step procedure,by adding a nanostructured platinum sol during the formation of ZIF-8 at room temp...A catalyst consisting of platinum nanoparticles on a ZIF-8 support(Pt@ZIF-8) was synthesized in a straightforward one-step procedure,by adding a nanostructured platinum sol during the formation of ZIF-8 at room temperature.Pt@ZIF-8 was highly porous and well crystallized.The Pt nanoparticles were well dispersed within the ZIF-8 support.In the hydrogenation of 1,4-butynediol,Pt@ZIF-8 exhibited high activity,excellent selectivity for 1,4-butenediol of greater than 94%,and reusability.The Pt@ZIF-8 catalyst did not require further additives.The favorable catalytic performance was attributed primarily to the modification of the ZIF-8 support by the platinum nanoparticles.展开更多
Most of studies on Distributed Antenna System(DAS) focus on maximizing the sum capacity and perfect channel state information at transmitter(CSIT).However,CSI is inevitable imperfect in practical wireless networks.Bas...Most of studies on Distributed Antenna System(DAS) focus on maximizing the sum capacity and perfect channel state information at transmitter(CSIT).However,CSI is inevitable imperfect in practical wireless networks.Based on the sources of error,there are two models.One assumes error lies in a bounded region,the other assumes random error.Accordingly,we propose two joint antenna selection(AS) and robustbeamforming schemes aiming to minimize the total transmit power at antenna nodes subject to quality of service(QoS) guarantee for all the mobile users(MUs) in multicell DAS.This problem is mathematically intractable.For the bounded error model,we cast it into a semidefinite program(SDP) using semidefinite relaxation(SDR) and S-procedure.For the second,we first design outage constrained robust beamforming and then formulate it as an SDP based on the Bernstein-type inequality,which we generalize it to the multi-cell DAS.Simulation results verify the effectiveness of the proposed methods.展开更多
Promoter MgO on 10% CeO2/Al2O3 oxygen carrier was investigated for direct partial oxidation of methane to syngas in molten salt. The MgO content of 0.5%, 1%, 2%, 3% and 4% on the 10%CeO2/Al2O3 oxygen carriers in exper...Promoter MgO on 10% CeO2/Al2O3 oxygen carrier was investigated for direct partial oxidation of methane to syngas in molten salt. The MgO content of 0.5%, 1%, 2%, 3% and 4% on the 10%CeO2/Al2O3 oxygen carriers in experiments were prepared at the temperature of 750℃, respectively. The methane conversion, H2 and CO selectivity was measured on these prepared oxygen carriers at different reaction temperature. The results showed that the 3% MgO on 10%CeO2/Al2O3 had the best activity, and the CH4 conversion and CO selectivity reached 92.58% and 87.64% at 875℃, respectively. The effect of different calcination temperature on 3% MgO as promoter on 10% CeO2/Al2O3 oxygen carrier was investigated. The results of BET indicated that oxygen carrier had the largest surface area at 750℃. When the calcined temperature was too high there would be a negative effect on oxygen carrier activity.展开更多
HIV/AIDS is one of the most serious public health challenges globally. Despite the great efforts that are being devoted to prevent,treat and to better understand the disease,it is one of the main causes of morbidity a...HIV/AIDS is one of the most serious public health challenges globally. Despite the great efforts that are being devoted to prevent,treat and to better understand the disease,it is one of the main causes of morbidity and mortality worldwide. Currently,there are 30 drugs or combinations of drugs approved by FDA. Because of the side-effects,price and drug resistance,it is essential to discover new targets,to develop new technology and to find new anti-HIV drugs. This review summarizes the major targets and assays currently used in anti-HIV drug screening.展开更多
Recently, the product remanufacturing has been a hot topic in the field of operational management, and more manufacturers are beginning to recover the value in their end of life (EOI.) products hy remanufacturing. T...Recently, the product remanufacturing has been a hot topic in the field of operational management, and more manufacturers are beginning to recover the value in their end of life (EOI.) products hy remanufacturing. This paper focuses on the closed loop supply chain where the retailer takes charge of not only retail, but also col- lection. There are two possible types of the retailer's collection cost as an assumption, i.e. high cost or low cost, and the retailer knows his type, whereas the manufacturer only has a prior prohability over the two possible cost types. This paper deploys the contracts with which the manufacturer can screen the type of the retailer to improve her profit under incomplete information. As a result, the pooling contract can perfectly coordinate the decentral- ized system under incomplete information, but the manufacturer obtains the lower profit; nevertheless, with the separating contracts the manufacturer obtains the larger profits though the system profit is lower.展开更多
The V/O5-WO3-MoOy'TiO2 honeycomb catalyst was prepared with industrial grade chemicals. The structural and physico-chemical properties were analyzed with X-ray diffraction (XRD), scanning electron micrograph (SEM...The V/O5-WO3-MoOy'TiO2 honeycomb catalyst was prepared with industrial grade chemicals. The structural and physico-chemical properties were analyzed with X-ray diffraction (XRD), scanning electron micrograph (SEM) and mercury porosimetry. The NOx conversion and durability were investigated on a pilot plant test set under the actual operational conditions of a coal fired boiler. The catalyst monolith had good formability with mass per- centage of V : W : Mo : TiO2 : fiber glass = 1 : 4.5 : 4.5 : 72 : 18. Vanadium, tungsten and molybdenum species were highly dispersed on anatase TiO2 without causing the transformation of anatase TiO2 to ruffle by calcining under a current of air at 450℃ for 4.5 h, but there were some degrees of crystal distortion. The catalyst particle sizes were almost uniform with close pile-up and the pore structure was regular with complete macro-pore formation and large specific surface area. The NOx conversion was sensitive to temperature but nearly insensitive to NH3. The catalyst showed strong adaptability to NOx concentration with activity above 80% in the range of 615 1640 mg.m-3. Within the range of 720-8640 h continuous operation, the NOx conversion dropped at a rate of about 1% reduction per 600 h.展开更多
We compare the optimal operating cost of the two bicriterion policies, <p,T> and <p,N>, for an M/G/1 queueing system with second optional service, in which the length of the vacation period is randomly con...We compare the optimal operating cost of the two bicriterion policies, <p,T> and <p,N>, for an M/G/1 queueing system with second optional service, in which the length of the vacation period is randomly controlled either by the number of arrivals during the idle period or by a timer. After all the customers are served in the queue exhaustively, the server immediately takes a vacation and may operate <p,T> policy or <p,N> policy. For the two bicriterion policies, the total average cost function per unit time is developed to search the optimal stationary operating policies at a minimum cost. Based upon the optimal cost the explicit forms for joint optimum threshold values of (p,T) and (p,N) are obtained.展开更多
文摘As a key technology of rapid prototyping and manufacturing (RP&M), rapid manufacturing of metal parts is a target of RP&M. Introducing selective laser sintering (SLS), an important branch of RP&M, this paper gives a new method oriented on low power SLS system to fabricate metal parts. With this kind of technology, the mixture of metal and polymer powder is sintered first to get green part, then, after debinding and metal infiltration, dense parts are gotten. In the end, influencing factors of this technology are analyzed. At the same time, some applications are given.
基金the National 863 Projects(Nos.2006AA06Z111,2006AA06201-3,and 2006AA09A101-3)National Special Project(No.SinoProbe-01-05)Open Project of the National Key Laboratory for Geological Processes and Mineral Resources(No.GPMR0942).
文摘Igneous rocks in the South China Sea have broad prospects for oil and gas exploration.Integrated geophysical methods are important approaches to study the distribution of igneous rocks and to determine and identify igneous rock bodies.Aimed at the characteristics of gravity and magnetic fields in the South China Sea,several potential field processing methods are preferentially selected.Reduction to the pole by variable inclinations in the area of low magnetic latitudes is used to perform reduction processing on magnetic anomalies.The preferential continuation method is used to separate gravity and magnetic anomalies and extract the gravity and magnetic anomaly information of igneous rocks in the shallow part of the South China Sea.The 3D spatial equivalent distribution of igneous rocks in South China Sea is illustrated by the 3 D correlation imaging of magnetic anomalies.Since the local anomaly boundaries are highlighted gravity and magnetic gradients,the distribution characters of different igneous rocks are roughly outlined by gravity and magnetic correlation analysis weighted by gradient.The results show the distribution of igneous rocks is controlled and influenced by deep crustal structure and faulting.
基金Project (20906067) supported by the National Natural Science Foundation of China
文摘ZSM-5 zeolites were directly synthesized on the surface of honeycomb cordierite substrates by hydrothermal method and certified by XRD and SEM techniques; the adhesion of ZSM-5 coatings was evaluated by ultrasonic vibration. Cu-ZSM-5/cordierite monolithic catalyst was prepared by ion-exchange and impregnation method and applied for the selective catalytic reduction (SCR) of NO by NH3 using a simulated diesel exhaust. The results show that the cordierite surface is almost completely covered by ZSM-5 crystals and the crystallization time greatly impacts the loadings and adhesion of ZSM-5 coatings on substrate, the NOx removal rate over Cu-ZSM-5/cordierite is above 90% in a temperature range of 240-480℃. Moreover, Cu-ZSM-5/cordierite prepared by different methods shows a wide temperature window (240-540 ℃) with high NO removal activities.
文摘The absorbing process in isolating and coating process of α-olefin drag reducing polymer was studied by molecular dynamic simulation method, on basis of coating theory of α-olefin drag reducing polymer particles with polyurethane as coating material. The distributions of sodium laurate, sodium dodeeyl sulfate, and sodium dodeeyl benzene sulfonate on the surface of α-olefin drag reducing polymer particles were almost the same, but the bending degrees of them were obviously different. The bending degree of SLA molecules was greater than those of the other two surfactant molecules. Simulation results of absorbing and accumulating structure showed that, though hydrophobie properties of surfactant molecules were almost the same, water density around long chain sulfonate sodium was bigger than that around alkyl sulfate sodium. This property goes against useful absorbing and accumulating on the surface of α-olefin drag reducing polymer particles; simulation results of interactions of different surfactant and multiple hydroxyl compounds on surface of particles showed that, interactions of different surfaetant and one kind of multiple hydroxyl compound were similar to those of one kind of surfaetant and different multiple hydroxyl compounds. These two contrast types of interactions also exhibited the differences of absorbing distribution and closing degrees to surface of particles. The sequence of closing degrees was derived from simulation; control step of addition polymerization interaction in coating process was absorbing mass transfer process, so the more closed to surface of particle the multiple hydroxyl compounds were, the easier interactions With isoeyanate were. Simulation results represented the compatibility relationship between surfactant and multiple hydroxyl compounds. The isolating and coating processes of α-olefin drag reducing polymer were further understood on molecule and atom level through above simulation research, and based on the simulation, a referenced theoretical basis was provided for practical optimal selection and experimental preparation of α-olefin drag reducing polymer particles suspension isolation agent.
基金Project (2010FA32370) supported by The Ministry of Science and Technology of ChinaProject (2008WK3002) supported by Hunan Provincial Science and Technology DepartmentProject (20060390891) supported by the Postdoctoral Science Foundation of China
文摘The mechanism of antithrombotic of Dahuangzhechong Fang separated and purified by Ti-Al intermetallic compound porous material (TAICPM) was researched. Dahuangzhechong Fang, which was isolated and screened by TAICPM, was used to oral rats. At the end of study, their blood and thrombus were collected. The results show that TAICPM with the pore size of 1-5 μm can screen Dahuangzhechong Fang well. Dahuangzhechong Fang can increase 6-keto-PGF1α, lower content of TXD2 and platelet. Dahuangzhechong Fang has good effect to resist arterial thrombosis.
基金Project(20906067)supported by the National Natural Science Foundation of ChinaProject(2011M500543)supported by the Postdoctoral Science Foundation of ChinaProject supported by the Program for the Top Young Academic Leaders of Higher Learning Institutions of Shanxi
文摘Cu-SAPO-34/cordierite catalysts were prepared via one-step hydrothermal synthesis method and their performances to remove NO x from the diesel vehicle exhaust were evaluated. The morphology, structure, Cu content and valence state were characterized by SEM, XRD, ICP and XPS, respectively. The experimental results show the active component Cu of the catalysts via in situ synthesis could significantly improve the selective catalytic reduction (SCR) activities of NOx and the optimal Cu content is in the range of 0.30%-0.40%(mass fraction). No N 2 O is detected by gas chromatograph (GC) during the evaluation process, which implies that NOx is almost entirely converted to N2 over Cu-SAPO-34/cordierite catalyst. The conversion rate of NOx to N2 by NH3 over catalyst could almost be up to 100%in the temperature range of 300-670 ℃with a space velocity of 12000 h-1 and it is still more than 60% at 300-620 ℃ under 36000 h-1. The catalysts also show the good hydrothermal and chemical stability at the atmosphere with H 2 O.
文摘We provide a new way to prepare ZnO nanorods pattern from the solution composed of hexamethylenetetramine (HMT) and Zn(NO3)2. The substrate is ITO substrate covered by well ordered Au islands. Since Au and the underneath ITO substrate have two different nucleation rates in the initial stage of heterogeneous nucleation process, the subsequent ZnO growth on the quick nucleating area takes place under diffusion control and is able to confine the synthesis of ZnO nanorods to specific locations. The concentrations of zinc nitrate and HMT are well adjusted to show the possibility of the new route for the patterning of the ZnO nanorods. Furthermore, the nanorods pattern was characterized by X-ray diffraction and photoluminescence and the performance of field emission property from ZnO nanorod patterns was investigated. The ZnO nanorods pattern with a good alignment also shows a good field enhancement behavior with a high value of the field enhancement factor.
文摘Objective To screen and identify genetic loci affecting the active zone formation in C. elegans. Methods A SYD-2::GFP reporter was constructed and used as an active zone marker for forward genetic screen to identify genetic loci affecting the active zone formation. Results Eight isolated mutant alleles were characterized from 15,000 haploid genomes. The SYD-2::GFP phenotypes of these mutants are mainly reflected as the changes of number, morphology, distribution of puncta and the gaps appearance. Some mutants also exhibit visible behavioral or physical phenotypes, and aldicarb resistant or sensitive phenotypes. Conclusion These mutants provide the opportunity for further systematic research on the active zone formation and the neurotransmission.
基金Project(70631004)supported by the Key Project of the National Natural Science Foundation of ChinaProject(20080440988)supported by the Postdoctoral Science Foundation of China+1 种基金Project(09JJ4030)supported by the Natural Science Foundation of Hunan Province,ChinaProject supported by the Postdoctoral Science Foundation of Central South University,China
文摘Based on the deficiency of time convergence and variability of Web services selection for services composition supporting cross-enterprises collaboration,an algorithm QCDSS(QoS constraints of dynamic Web services selection)to resolve dynamic Web services selection with QoS global optimal path,was proposed.The essence of the algorithm was that the problem of dynamic Web services selection with QoS global optimal path was transformed into a multi-objective services composition optimization problem with QoS constraints.The operations of the cross and mutation in genetic algorithm were brought into PSOA(particle swarm optimization algorithm),forming an improved algorithm(IPSOA)to solve the QoS global optimal problem.Theoretical analysis and experimental results indicate that the algorithm can better satisfy the time convergence requirement for Web services composition supporting cross-enterprises collaboration than the traditional algorithms.
基金supported by the INCOEmission project coordinated by BASF SE,Germanythe support from the Fundamental Research Funds for the Central Universities(DC201502080409)~~
文摘Silicon carbide(SiC)was used as a support for SSZ‐13zeolite in an attempt to improve the high‐temperature stability and activity of Cu/SSZ‐13in the selective catalytic reduction(SCR)of NO with NH3.SSZ‐13was grown via a hydrothermal method using the silicon and silica contained in SiC as the source of silicon,which led to the formation of a chemically bonded SSZ‐13layer on SiC.Characterization using X‐ray diffraction,scanning electron microscopy,and N2adsorption‐desorption isotherms revealed that the alkali content strongly affected the purity of zeolite and the crystallization time affected the coverage and crystallinity of the zeolite layer.Upon ion exchange,the resulting Cu/SSZ‐13@SiC catalyst exhibited enhanced activity in NH3‐SCR in the high‐temperature region compared with the unsupported Cu/SSZ‐13.Thus,the application temperature was extended with the use of SiC as the support.?2018,Dalian Institute of Chemical Physics,Chinese Academy of Sciences.Published by Elsevier B.V.All rights reserved.
基金supported by the National Natural Science Foundation of China(2137626121173270)+4 种基金the National High Technology Research and Development Program of China(863 Program2015AA034603)the Beijing Natural Science Foundation(2142027)the China University of Petroleum Fund(201300071100072462015QZDX04)~~
文摘A series of meso‐microporous copper‐supporting chabazite molecular sieve(CuSAPO‐34) catalysts with excellent performance in low‐temperature ammonia selective catalytic reduction(NH3‐SCR)have been synthesized via a one‐pot hydrothermal crystallization method. The physicochemical properties of the catalysts were characterized by scanning electron microscopy, transmission electron microscopy, N2 adsorption‐desorption measurements, X‐ray diffraction, 27 Al magic angle spinning nuclear magnetic resonance, diffuse reflectance ultraviolet‐visible spectroscopy, inductively coupled plasma‐atomic emission spectroscopy, X‐ray photoelectron spectroscopy, temperature‐programmed reduction measurements, and electron paramagnetic resonance analysis. The formation of micro‐mesopores in the Cu‐SAPO‐34 catalysts decreases diffusion resistance and greatly improves the accessibility of reactants to catalytic active sites. The main active sites for NH3‐SCR reaction are the isolated Cu^2+ species displaced into the ellipsoidal cavity of the Cu‐SAPO‐34 catalysts.
基金supported by the National Natural Science Foundation of China (21272268 and 21472237)~~
文摘An efficient new method has been developed to synthesize N2‐alkyl 1,2,3‐triazole products by tol‐uenesulfonic acid (TsOH) catalyzed addition of N1‐Ts substituted 1,2,3‐triazoles to olefins. The reac‐tions of monosubstituted and unsubstituted triazole substrates with various olefins, including vinyl esters, are explored.
基金supported by the National Natural Science Foundation of China(21573031 and 21428301)the Fundamental Research Funds for the Central Universities(DUT15ZD106 and DUT15RC(4)09)~~
文摘A catalyst consisting of platinum nanoparticles on a ZIF-8 support(Pt@ZIF-8) was synthesized in a straightforward one-step procedure,by adding a nanostructured platinum sol during the formation of ZIF-8 at room temperature.Pt@ZIF-8 was highly porous and well crystallized.The Pt nanoparticles were well dispersed within the ZIF-8 support.In the hydrogenation of 1,4-butynediol,Pt@ZIF-8 exhibited high activity,excellent selectivity for 1,4-butenediol of greater than 94%,and reusability.The Pt@ZIF-8 catalyst did not require further additives.The favorable catalytic performance was attributed primarily to the modification of the ZIF-8 support by the platinum nanoparticles.
基金ACKNOWLEDGEMENTS This work is supported by Natural Science Foundation of China (No. 61340035) and Guangzhou science and technology plan projects (2014-132000764).
文摘Most of studies on Distributed Antenna System(DAS) focus on maximizing the sum capacity and perfect channel state information at transmitter(CSIT).However,CSI is inevitable imperfect in practical wireless networks.Based on the sources of error,there are two models.One assumes error lies in a bounded region,the other assumes random error.Accordingly,we propose two joint antenna selection(AS) and robustbeamforming schemes aiming to minimize the total transmit power at antenna nodes subject to quality of service(QoS) guarantee for all the mobile users(MUs) in multicell DAS.This problem is mathematically intractable.For the bounded error model,we cast it into a semidefinite program(SDP) using semidefinite relaxation(SDR) and S-procedure.For the second,we first design outage constrained robust beamforming and then formulate it as an SDP based on the Bernstein-type inequality,which we generalize it to the multi-cell DAS.Simulation results verify the effectiveness of the proposed methods.
基金Acknowledgments: The work was supported by the National Nature Science Foundation of China (No. 50574046, 50164002) and National Natural Science Foundation of Major Research Projects (No. 90610035), Natural Science Foundation of Yunnan Province (No. 2004E0058Q), High School Doctoral Subject Special Science and Research Foundation of Ministry of Education (No. 20040674005).
文摘Promoter MgO on 10% CeO2/Al2O3 oxygen carrier was investigated for direct partial oxidation of methane to syngas in molten salt. The MgO content of 0.5%, 1%, 2%, 3% and 4% on the 10%CeO2/Al2O3 oxygen carriers in experiments were prepared at the temperature of 750℃, respectively. The methane conversion, H2 and CO selectivity was measured on these prepared oxygen carriers at different reaction temperature. The results showed that the 3% MgO on 10%CeO2/Al2O3 had the best activity, and the CH4 conversion and CO selectivity reached 92.58% and 87.64% at 875℃, respectively. The effect of different calcination temperature on 3% MgO as promoter on 10% CeO2/Al2O3 oxygen carrier was investigated. The results of BET indicated that oxygen carrier had the largest surface area at 750℃. When the calcined temperature was too high there would be a negative effect on oxygen carrier activity.
文摘HIV/AIDS is one of the most serious public health challenges globally. Despite the great efforts that are being devoted to prevent,treat and to better understand the disease,it is one of the main causes of morbidity and mortality worldwide. Currently,there are 30 drugs or combinations of drugs approved by FDA. Because of the side-effects,price and drug resistance,it is essential to discover new targets,to develop new technology and to find new anti-HIV drugs. This review summarizes the major targets and assays currently used in anti-HIV drug screening.
基金The National Natural Science Foundation of China (No 70372056)
文摘Recently, the product remanufacturing has been a hot topic in the field of operational management, and more manufacturers are beginning to recover the value in their end of life (EOI.) products hy remanufacturing. This paper focuses on the closed loop supply chain where the retailer takes charge of not only retail, but also col- lection. There are two possible types of the retailer's collection cost as an assumption, i.e. high cost or low cost, and the retailer knows his type, whereas the manufacturer only has a prior prohability over the two possible cost types. This paper deploys the contracts with which the manufacturer can screen the type of the retailer to improve her profit under incomplete information. As a result, the pooling contract can perfectly coordinate the decentral- ized system under incomplete information, but the manufacturer obtains the lower profit; nevertheless, with the separating contracts the manufacturer obtains the larger profits though the system profit is lower.
基金Supported by the Science and Technology Development Planning of Shandong Province(2011GSF11716)China Scholarship Council for Researching in University of Birmingham
文摘The V/O5-WO3-MoOy'TiO2 honeycomb catalyst was prepared with industrial grade chemicals. The structural and physico-chemical properties were analyzed with X-ray diffraction (XRD), scanning electron micrograph (SEM) and mercury porosimetry. The NOx conversion and durability were investigated on a pilot plant test set under the actual operational conditions of a coal fired boiler. The catalyst monolith had good formability with mass per- centage of V : W : Mo : TiO2 : fiber glass = 1 : 4.5 : 4.5 : 72 : 18. Vanadium, tungsten and molybdenum species were highly dispersed on anatase TiO2 without causing the transformation of anatase TiO2 to ruffle by calcining under a current of air at 450℃ for 4.5 h, but there were some degrees of crystal distortion. The catalyst particle sizes were almost uniform with close pile-up and the pore structure was regular with complete macro-pore formation and large specific surface area. The NOx conversion was sensitive to temperature but nearly insensitive to NH3. The catalyst showed strong adaptability to NOx concentration with activity above 80% in the range of 615 1640 mg.m-3. Within the range of 720-8640 h continuous operation, the NOx conversion dropped at a rate of about 1% reduction per 600 h.
文摘We compare the optimal operating cost of the two bicriterion policies, <p,T> and <p,N>, for an M/G/1 queueing system with second optional service, in which the length of the vacation period is randomly controlled either by the number of arrivals during the idle period or by a timer. After all the customers are served in the queue exhaustively, the server immediately takes a vacation and may operate <p,T> policy or <p,N> policy. For the two bicriterion policies, the total average cost function per unit time is developed to search the optimal stationary operating policies at a minimum cost. Based upon the optimal cost the explicit forms for joint optimum threshold values of (p,T) and (p,N) are obtained.