这个样板房最有特色的是它是个集住宅和营商用途于一体的单位。只有一百多平方米的空间,同时充当住宅和办公室的角色,这是一个比较新的定位,最适合事业刚起步的小公司以及 SOHO 一族人士。这个示范单位的主题是为从事 IT 行业的人士而...这个样板房最有特色的是它是个集住宅和营商用途于一体的单位。只有一百多平方米的空间,同时充当住宅和办公室的角色,这是一个比较新的定位,最适合事业刚起步的小公司以及 SOHO 一族人士。这个示范单位的主题是为从事 IT 行业的人士而设。设计师在确定了这次的主题之后,大胆地对房间结构进行改造。为改善之前长条型的房间结构,设计师使用了大面积玻璃扩大了视觉,使整个空间都开阔起来。在面山的那面墙上也使用了玻璃,把窗外的山色反映到室内来,丰富了室内的景色。展开更多
Fushun oil shale(FOS) was subjected to thermal dissolution(TD) under different conditions. The results show that the optimal solvent, temperature, time, and ratio of solvent to FOS are ethanol, 300 °C, 2 h, and 5...Fushun oil shale(FOS) was subjected to thermal dissolution(TD) under different conditions. The results show that the optimal solvent, temperature, time, and ratio of solvent to FOS are ethanol, 300 °C, 2 h, and 5 ml·g^(-1),respectively and the corresponding yield of the soluble portion(SP) is 32.2%(daf), which is much higher than the oil content of FOS(ca. 6%), suggesting that TD in ethanol is an excellent way to extract organics from FOS.According to 3 direct analyses, aliphatic moieties in FOS are the most abundant followed by C\\O-containing moieties and each cluster in FOS has 3 conjugated aromatic rings on average with fewer substituents. According to the analysis with a gas chromatograph/mass spectrometer, alkanes are predominant in all the SPs. A number of alkenes were identified in the SPs from the TD, while none of the alkenes were detected in acetone-SP obtained at room temperature, implying that the TD can destroy the π-π and intertwining interactions between alkenes and macromolecular structures in FOS. Moreover, a small amount of alkyl-substituted phenols and alkoxysubstituted phenols were detected in ethanol-SP from the TD, which could be the products from ethanolyzing the macromolecular moiety of FOS.展开更多
Chlorpyrifos and dimethoate are overused agricultural pesticides that can trigger trophic cascades, resulting in toxicity to both terrestrial and aquatic organisms as well as altered ecosystems. In previous studies, s...Chlorpyrifos and dimethoate are overused agricultural pesticides that can trigger trophic cascades, resulting in toxicity to both terrestrial and aquatic organisms as well as altered ecosystems. In previous studies, substantial attention has been given to the effects of pesticides on vertebrate species and, to a lesser extent, species of zooplankton. The present study was designed to show that the fission time effective concentration in ciliates is a potential aquatic detection index for environmental monitoring. The ciliate Urostyla grandis was treated with doses of chlorpyrifos and dimethoate. After exposed to the pesticides, the LC_(50)(i.e., concentration that killed 50% of the ciliate cells within 24 h) values were 0.029 mg L^(-1) for chlorpyrifos and 0.0685 mg L^(-1) for dimethoate. The fission time effective concentrations after 168 h of exposure were 0.0075–0.0093 mg L^(-1) for chlorpyrifos and 0.2640–0.2750 mg L^(-1) for dimethoate. These results show that the fission time effective concentration is lower than the LC_(50) value in ciliates, indicating that fission time effective concentration is more suitable than the LC_(50) value for environmental monitoring using ciliates. The effects of chlorpyrifos and dimethoate on ciliate cell ultrastructures included agglutination of chromatin in the macronucleus, protruded and discontinuous macronuclear and micronuclear membranes, loss of integrity of mitochondrial membranes and contents, and abscission and deformation of the adoral zone of membranelles.展开更多
In this work, commercially pure Zr sheets were subjected to β air cooling and then rolled to different reductions(10% and 50%)at room temperature. Microstructures of both the β-air-cooled and the rolled specimens we...In this work, commercially pure Zr sheets were subjected to β air cooling and then rolled to different reductions(10% and 50%)at room temperature. Microstructures of both the β-air-cooled and the rolled specimens were well characterized by electron channelling contrast imaging and electron backscatter diffraction techniques, with special attentions paid to their misorientation characteristics. Results show that the β-air-cooled specimen owns a Widmanst?tten structure featured by lamellar grains with typical phase transformation misorientations. The 10% rolling allows prismatic slip and tensile twinning({11-21}<11-2-6> and{10-12}<10-11>) to be activated profusely, which produce new low-angle(~3°–5°) and high-angle(~35° and ~85°) misorientation peaks, respectively. After increasing the rolling reduction to 50%, twinning is suppressed and dislocation slip becomes the dominant deformation mode, with the lamellar grains highly elongated and aligned towards the rolling direction.Meanwhile, only one strong low-angle misorientation peak related to the prismatic slip is presented in the 50%-rolled specimen,with all other peaks disappeared. Analyses on local misorientations reveal that hardly any residual strains exist in the β-air-cooled specimen, which should be related to their sufficient relaxation during slow cooling. Residual strains introduced by 10% rolling are heterogeneously distributed near grain/twin boundaries while heavier deformation(50% rolling) produces much larger residual strains pervasively existing throughout the specimen microstructure.展开更多
A dual-phase Zr-2.5 Nb alloy was rolled at room temperature to 50% reduction and then annealed at two temperatures(560 and580°C) near the monotectoid temperature. X-ray diffraction, electron channeling contrast i...A dual-phase Zr-2.5 Nb alloy was rolled at room temperature to 50% reduction and then annealed at two temperatures(560 and580°C) near the monotectoid temperature. X-ray diffraction, electron channeling contrast imaging and electron backscatter diffraction techniques were jointly used to characterize microstructural characteristics developed in the as-rolled and annealed specimens. Results show that plastic deformation occurs in both bulk α-Zr grains and thin β-Zr films during rolling, allowing large lattice strains to be accumulated in β-Zr and active dislocation slip(especially the prismatic áa?slip) to be initiated in α-Zr. During subsequent annealing at 580°C, the prior β-Zr films are transformed into submicron β-Zr particles, which lose coherency(the Burgers orientation relationship) with surrounding α grains. In the specimen annealed at 560°C, however, the prior β-Zr films are found to be decomposed into nanoscale β-Nb particles. In both the annealed specimens, the β-Zr and the β-Nb particles appeared to be linearly distributed along the rolling direction. Two types of α structures, i.e., small equiaxed crystallites formed by recovery of dislocation structures and coarse bamboo-like recrystallized grains, are revealed in the annealed specimens. Effective boundary pinning due to the dense β-phase particles is demonstrated to play a key role in forming such unusual bamboo-like grains.展开更多
Band structure and component content are the key factors for determining the activity of semiconductor heterojunction. In this study, a novel Bi5O7I/BiOBrxI1-x heterostructure was synthesized by a simple hydrobromic ...Band structure and component content are the key factors for determining the activity of semiconductor heterojunction. In this study, a novel Bi5O7I/BiOBrxI1-x heterostructure was synthesized by a simple hydrobromic （HBr） acid etching method through transforming partial of Bi5O7I to I ion doped BiOBr （BiOBrxI1-x） at room temperature without adding extra dopant. Both the band structure and component content of Bi5O7I/BiOBrxI1-x alter with the additive HBr acid. The Bi5O7I/BiOBrxI1-x （S3.0） sample exhibits the best photocatalytic activity, 6 times higher than that of pure Bis071, for the degradation of methyl orange under visible-light （2 〉 420 nm）. The activity enhancement of Bi5O7I/BiOBrxI1-x is primarily ascribed to the improved separation efficiency of photocharges, originated from the adjustable band structure and component content, The significant findings of this paper provide a facile way to construct highly efficient semiconductor heterojunction via playing the synergetic effect of adjustable band struc- ture and component content for purifying organic pollutants in wastewater.展开更多
Nonaromatic amino acids are generally believed to be nonemissive, owing to their lack of apparently remarkable conjugation within individual molecules. Here we report the intrinsic visible emission of nonaromatic amin...Nonaromatic amino acids are generally believed to be nonemissive, owing to their lack of apparently remarkable conjugation within individual molecules. Here we report the intrinsic visible emission of nonaromatic amino acids and poly(amino acids) in concentrated solutions and solid powders. This unique and widespread luminescent characteristic can be well rationalized by the clustering-triggered emission(CTE) mechanism, namely the clustering of nonconventional chromophores(i.e. amino, carbonyl,and hydroxyl) and subsequent electron cloud overlap with simultaneous conformation rigidification. Such CTE mechanism is further supported by the single crystal structure analysis, from which 3 D through space electronic communications are uncovered.Besides prompt fluorescence, room temperature phosphorescence(RTP) is also detected from the solids. Moreover, persistent RTP is observed in the powders of exampled poly(amino acids) of ε-poly-L-lysine(.-PLL) after ceasing UV irradiation. These results not only illustrate the feasibility of employing the building blocks of nonaromatic amino acids in the exploration of new luminescent biomolecules, but also provide significant implications for the emissions of peptides and proteins at aggregated or crystalline states. Meanwhile, they may also shed lights on further understanding of autofluorescence from biological systems.展开更多
文摘这个样板房最有特色的是它是个集住宅和营商用途于一体的单位。只有一百多平方米的空间,同时充当住宅和办公室的角色,这是一个比较新的定位,最适合事业刚起步的小公司以及 SOHO 一族人士。这个示范单位的主题是为从事 IT 行业的人士而设。设计师在确定了这次的主题之后,大胆地对房间结构进行改造。为改善之前长条型的房间结构,设计师使用了大面积玻璃扩大了视觉,使整个空间都开阔起来。在面山的那面墙上也使用了玻璃,把窗外的山色反映到室内来,丰富了室内的景色。
基金Supported by the Fundamental Research Funds for the Central Universities(2017BSCXB27)the Research and the Postgraduate Research&Practice Innovation Program of Jiangsu Province(KYCX17_1507)
文摘Fushun oil shale(FOS) was subjected to thermal dissolution(TD) under different conditions. The results show that the optimal solvent, temperature, time, and ratio of solvent to FOS are ethanol, 300 °C, 2 h, and 5 ml·g^(-1),respectively and the corresponding yield of the soluble portion(SP) is 32.2%(daf), which is much higher than the oil content of FOS(ca. 6%), suggesting that TD in ethanol is an excellent way to extract organics from FOS.According to 3 direct analyses, aliphatic moieties in FOS are the most abundant followed by C\\O-containing moieties and each cluster in FOS has 3 conjugated aromatic rings on average with fewer substituents. According to the analysis with a gas chromatograph/mass spectrometer, alkanes are predominant in all the SPs. A number of alkenes were identified in the SPs from the TD, while none of the alkenes were detected in acetone-SP obtained at room temperature, implying that the TD can destroy the π-π and intertwining interactions between alkenes and macromolecular structures in FOS. Moreover, a small amount of alkyl-substituted phenols and alkoxysubstituted phenols were detected in ethanol-SP from the TD, which could be the products from ethanolyzing the macromolecular moiety of FOS.
基金supported by the National Natural Science Foundation of China (Nos. 31601866 and 31501844)the Heilongjiang Province Colleges and Universities Youth Innovative Training Program (Nos. UNPYSCT2017178 and 2017180)
文摘Chlorpyrifos and dimethoate are overused agricultural pesticides that can trigger trophic cascades, resulting in toxicity to both terrestrial and aquatic organisms as well as altered ecosystems. In previous studies, substantial attention has been given to the effects of pesticides on vertebrate species and, to a lesser extent, species of zooplankton. The present study was designed to show that the fission time effective concentration in ciliates is a potential aquatic detection index for environmental monitoring. The ciliate Urostyla grandis was treated with doses of chlorpyrifos and dimethoate. After exposed to the pesticides, the LC_(50)(i.e., concentration that killed 50% of the ciliate cells within 24 h) values were 0.029 mg L^(-1) for chlorpyrifos and 0.0685 mg L^(-1) for dimethoate. The fission time effective concentrations after 168 h of exposure were 0.0075–0.0093 mg L^(-1) for chlorpyrifos and 0.2640–0.2750 mg L^(-1) for dimethoate. These results show that the fission time effective concentration is lower than the LC_(50) value in ciliates, indicating that fission time effective concentration is more suitable than the LC_(50) value for environmental monitoring using ciliates. The effects of chlorpyrifos and dimethoate on ciliate cell ultrastructures included agglutination of chromatin in the macronucleus, protruded and discontinuous macronuclear and micronuclear membranes, loss of integrity of mitochondrial membranes and contents, and abscission and deformation of the adoral zone of membranelles.
基金supported by the Fundamental and Cutting-Edge Research Plan of Chongqing(Grant Nos.cstc2017jcyj AX0114&cstc2016jcyj A0434)the National Natural Science Foundation of China(Grant Nos.51401040,51601075&51601165)
文摘In this work, commercially pure Zr sheets were subjected to β air cooling and then rolled to different reductions(10% and 50%)at room temperature. Microstructures of both the β-air-cooled and the rolled specimens were well characterized by electron channelling contrast imaging and electron backscatter diffraction techniques, with special attentions paid to their misorientation characteristics. Results show that the β-air-cooled specimen owns a Widmanst?tten structure featured by lamellar grains with typical phase transformation misorientations. The 10% rolling allows prismatic slip and tensile twinning({11-21}<11-2-6> and{10-12}<10-11>) to be activated profusely, which produce new low-angle(~3°–5°) and high-angle(~35° and ~85°) misorientation peaks, respectively. After increasing the rolling reduction to 50%, twinning is suppressed and dislocation slip becomes the dominant deformation mode, with the lamellar grains highly elongated and aligned towards the rolling direction.Meanwhile, only one strong low-angle misorientation peak related to the prismatic slip is presented in the 50%-rolled specimen,with all other peaks disappeared. Analyses on local misorientations reveal that hardly any residual strains exist in the β-air-cooled specimen, which should be related to their sufficient relaxation during slow cooling. Residual strains introduced by 10% rolling are heterogeneously distributed near grain/twin boundaries while heavier deformation(50% rolling) produces much larger residual strains pervasively existing throughout the specimen microstructure.
基金supported by the National Natural Science Foundation of China(Grant Nos.51401040,51371202,51531005&51421001)the Fundamental and Cutting-Edge Research Plan of Chongqing(Grant No.cstc2017jcyjAX0114)
文摘A dual-phase Zr-2.5 Nb alloy was rolled at room temperature to 50% reduction and then annealed at two temperatures(560 and580°C) near the monotectoid temperature. X-ray diffraction, electron channeling contrast imaging and electron backscatter diffraction techniques were jointly used to characterize microstructural characteristics developed in the as-rolled and annealed specimens. Results show that plastic deformation occurs in both bulk α-Zr grains and thin β-Zr films during rolling, allowing large lattice strains to be accumulated in β-Zr and active dislocation slip(especially the prismatic áa?slip) to be initiated in α-Zr. During subsequent annealing at 580°C, the prior β-Zr films are transformed into submicron β-Zr particles, which lose coherency(the Burgers orientation relationship) with surrounding α grains. In the specimen annealed at 560°C, however, the prior β-Zr films are found to be decomposed into nanoscale β-Nb particles. In both the annealed specimens, the β-Zr and the β-Nb particles appeared to be linearly distributed along the rolling direction. Two types of α structures, i.e., small equiaxed crystallites formed by recovery of dislocation structures and coarse bamboo-like recrystallized grains, are revealed in the annealed specimens. Effective boundary pinning due to the dense β-phase particles is demonstrated to play a key role in forming such unusual bamboo-like grains.
基金supported by the National Natural Science Foundation of China(51772118,51472005)State Key Laboratory of Structural Chemistry(20160014)+2 种基金Anhui Provincial Natural Science Foundation(1708085MB32)the Natural Science Foundation of Educational Committee of Anhui Province(gxyq ZD2016414,KJ2014B08)Innovation Team of Design and Application of Advanced Energetic Materials
文摘Band structure and component content are the key factors for determining the activity of semiconductor heterojunction. In this study, a novel Bi5O7I/BiOBrxI1-x heterostructure was synthesized by a simple hydrobromic （HBr） acid etching method through transforming partial of Bi5O7I to I ion doped BiOBr （BiOBrxI1-x） at room temperature without adding extra dopant. Both the band structure and component content of Bi5O7I/BiOBrxI1-x alter with the additive HBr acid. The Bi5O7I/BiOBrxI1-x （S3.0） sample exhibits the best photocatalytic activity, 6 times higher than that of pure Bis071, for the degradation of methyl orange under visible-light （2 〉 420 nm）. The activity enhancement of Bi5O7I/BiOBrxI1-x is primarily ascribed to the improved separation efficiency of photocharges, originated from the adjustable band structure and component content, The significant findings of this paper provide a facile way to construct highly efficient semiconductor heterojunction via playing the synergetic effect of adjustable band struc- ture and component content for purifying organic pollutants in wastewater.
基金supported by the National Natural Science Foundation of China(51473092)the Shanghai Rising-Star Program(15QA1402500)
文摘Nonaromatic amino acids are generally believed to be nonemissive, owing to their lack of apparently remarkable conjugation within individual molecules. Here we report the intrinsic visible emission of nonaromatic amino acids and poly(amino acids) in concentrated solutions and solid powders. This unique and widespread luminescent characteristic can be well rationalized by the clustering-triggered emission(CTE) mechanism, namely the clustering of nonconventional chromophores(i.e. amino, carbonyl,and hydroxyl) and subsequent electron cloud overlap with simultaneous conformation rigidification. Such CTE mechanism is further supported by the single crystal structure analysis, from which 3 D through space electronic communications are uncovered.Besides prompt fluorescence, room temperature phosphorescence(RTP) is also detected from the solids. Moreover, persistent RTP is observed in the powders of exampled poly(amino acids) of ε-poly-L-lysine(.-PLL) after ceasing UV irradiation. These results not only illustrate the feasibility of employing the building blocks of nonaromatic amino acids in the exploration of new luminescent biomolecules, but also provide significant implications for the emissions of peptides and proteins at aggregated or crystalline states. Meanwhile, they may also shed lights on further understanding of autofluorescence from biological systems.
