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单层二硫化钼力学性能温度和手性效应的分子动力学模拟 被引量:7
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作者 李明林 万亚玲 +1 位作者 胡建玥 王卫东 《物理学报》 SCIE EI CAS CSCD 北大核心 2016年第17期300-308,共9页
针对文献中单层二硫化钼力学性能随温度变化趋势的不明确,本文基于Stillinger-Weber原子间势函数,采用经典分子动力学方法对单层二硫化钼在不同热力学温度下(1—800 K)的力学行为进行了单轴拉伸模拟,研究温度和手性对其力学性能的影响.... 针对文献中单层二硫化钼力学性能随温度变化趋势的不明确,本文基于Stillinger-Weber原子间势函数,采用经典分子动力学方法对单层二硫化钼在不同热力学温度下(1—800 K)的力学行为进行了单轴拉伸模拟,研究温度和手性对其力学性能的影响.结果表明:单层二硫化钼的杨氏模量、抗拉强度、拉伸极限应变等力学性能均随温度的升高而显著减小;单层二硫化钼的杨氏模量和抗拉强度存在明显的手性效应,而不同手性方向的拉伸极限应变差别不大,可以忽略;温度低于800 K时,不同手性二硫化钼断裂之前受拉加载和卸载均没有明显的相变发生;温度在1 K时,沿锯齿方向受拉的单层二硫化钼在极限强度附近会有明显的局部相变发生,且卸载时相变结构能保持稳定.本文也测量出单层二硫化钼在温度1—800 K下沿扶手和锯齿方向的线膨胀系数. 展开更多
关键词 二硫化钼 力学性能 温度效应 手性效应
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光学活性金属卟啉的磁手性效应研究 被引量:2
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作者 应晓 刘海洋 +4 位作者 胡希明 姚钟平 黄锦汪 田 计亮年 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2000年第6期844-846,共3页
Strong magneto chiral effects in absorption of phenylalanine bridged chiral zinc bis porphyrin O,O C 2 Phe C 2 (TPP) 2Zn 2 were demonstrated through the comparison of natural circular dichroism and magnetic circular d... Strong magneto chiral effects in absorption of phenylalanine bridged chiral zinc bis porphyrin O,O C 2 Phe C 2 (TPP) 2Zn 2 were demonstrated through the comparison of natural circular dichroism and magnetic circular dichroism spectra of enantiomers. Magneto chiral circular dichroism spectra expressed as difference between the absorption coefficients of the left circularly polarized and right circularly polarized light are given. The observed intensive magneto chiral effect was suggested to be related with the chiral exciton coupling between two zinc porphyrin chromophores of the enantiomers. [WT5HZ] 展开更多
关键词 光学活性 手性效应 苯丙氨酸桥联锌双叶啉
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磁场中手性碳纳米环的类超导效应 被引量:2
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作者 张振华 彭景翠 +1 位作者 陈小华 王健雄 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 北大核心 2001年第3期345-349,共5页
利用导出的任意手性碳纳米环 (TCNTs)的电子状态—能量关系式 ,对磁场中任意手性TCNTs所具有的类似超导环的性质及持续电流的手性效应进行理论探讨。在T =0K时 ,金属型和半导体型TCNTs象介观一维正常金属环一样具有类似超导环的性质、... 利用导出的任意手性碳纳米环 (TCNTs)的电子状态—能量关系式 ,对磁场中任意手性TCNTs所具有的类似超导环的性质及持续电流的手性效应进行理论探讨。在T =0K时 ,金属型和半导体型TCNTs象介观一维正常金属环一样具有类似超导环的性质、即持续电流以磁通量子Φ0 为周期随Φ线性变化 ,且对手性角θ、环半径R极为敏感。手性TCNTs类似超导环的性质比高对称TCNTs明显得多 ,但随R增大而减弱 ,且减弱的快慢也与手性角θ有关。 展开更多
关键词 类超导效应 手性效应 持续电流 磁场 碳纳米管 手性碳纳米环 超导电性
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Stability and chirality effect on twist formation of collapsed double wall carbon nanotubes
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作者 肖建亮 刘彬 +2 位作者 黄永刚 黄克智 俞敏峰 《中国有色金属学会会刊:英文版》 CSCD 2006年第B02期776-779,共4页
This study is to reveal the effect of interlayer lattice registry on the formation of collapsed double wall carbon nanotubes (DWCNTs). It is found that collapsed carbon nanotubes can be energetically unstable, metasta... This study is to reveal the effect of interlayer lattice registry on the formation of collapsed double wall carbon nanotubes (DWCNTs). It is found that collapsed carbon nanotubes can be energetically unstable, metastable or stable, depending mainly on the diameter of the CNT. A fully collapsed DWCNT can adopt different structural morphologies, such as a straight ribbon, a warping ribbon or a twisted ribbon, depending on the chirality of the CNT, which is similar to single wall carbon nanotubes (SWCNTs). Different from SWCNTs, this study also shows some unique phenomena in the formation of collapsed DWCNTs. A fully collapsed DWCNT can have different combinations of the interlayer lattice registry effect within the inner and outer tube, thus the outer tube can influence the formation of the collapsed CNT via lattice registry effect, sometimes even dominates the twist of the CNT. 展开更多
关键词 双壁碳纳米管 扭曲形成 稳定性 手性效应 倒塌
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α-氨基丁酸对映异构体在DMF+水混合溶剂中的焓对作用 被引量:1
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作者 郭政 胡新根 +3 位作者 梁红玉 贾召鹏 程维娜 刘嘉敏 《物理化学学报》 SCIE CAS CSCD 北大核心 2012年第9期2015-2022,共8页
利用等温滴定微量热法(ITC)分别测定了298.15K时L-α-氨基丁酸和D-α-氨基丁酸两种对映异构体在不同组成的二甲基甲酰胺(DMF)+水混合溶剂中的稀释焓.根据统计热力学的McMillan-Mayer理论计算各溶剂组成下的同系焓对作用系数(hxx).从溶质... 利用等温滴定微量热法(ITC)分别测定了298.15K时L-α-氨基丁酸和D-α-氨基丁酸两种对映异构体在不同组成的二甲基甲酰胺(DMF)+水混合溶剂中的稀释焓.根据统计热力学的McMillan-Mayer理论计算各溶剂组成下的同系焓对作用系数(hxx).从溶质-溶质和溶质-溶剂相互作用的观点出发探讨了三元水溶液中疏水-疏水、疏水-亲水和亲水-亲水作用的竞争平衡.实验发现,在所研究的混合溶剂组成范围内(wDMF=0-0.3),α-氨基丁酸两种对映体的hxx都是较大的正值,且都随wDMF的增大而逐渐减小,而有趣的是L型对映体的hxx值普遍比D型的大(hLL>hDD),说明ITC可以区分对映异构体的同手性焓对作用.结果表明:在α-氨基丁酸+水+DMF三元溶液体系中,疏水-疏水和疏水-亲水作用在分子对作用过程中占优势;在α-氨基丁酸的同种对映体发生分子对作用时,L-L分子对比D-D分子对在构型上更有利于α-碳上疏水侧链(CH3CH2-)的靠拢,疏水基团的水合壳层发生交盖,局部破坏而释放出部分结构化的水,过程自发、吸热且伴随显著熵增(ΔG<0,ΔH>0,ΔS=(ΔH-ΔG)/T>0),因而在稀释时释放出更多热量,hxx具有较大的正值. 展开更多
关键词 α-氨基丁酸 对映异构体 DMF+水混合溶剂 等温滴定微量热法 稀释焓 焓对作用系数:手性区分效应
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Investigations on Left Hand Cut Contribution to Determination of κ(700) Pole
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作者 ZHOU Zhi-Yong 《Communications in Theoretical Physics》 SCIE CAS CSCD 2007年第5期883-886,共4页
The uncertainties of background contributions to J = 0 partial wave πK scattering phase shifts are carefully studied. We firstly point out that the circular cuts exhibit different characters in S1/1 and S3/2 waves. W... The uncertainties of background contributions to J = 0 partial wave πK scattering phase shifts are carefully studied. We firstly point out that the circular cuts exhibit different characters in S1/1 and S3/2 waves. While the former contributes negatively to the scattering length parameter, the latter contributes positively, i.e., has a wrong sign. This fact indicates that short range force contribu tions to the phase shift are non-negligible in the exotic channel. Nevertheless, it is verified that the κ pole will be affected only slightly with respect to the theoretical uncertainty in estimating the left hand cut contributions. 展开更多
关键词 πK scattering UNITARITY dispersion relations κ resonance
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Motor Compatibility Effect on the Comprehension of Complex Manual Action Sentences in L2:An ERP Study 被引量:1
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作者 Anqi ZANG Huili WANG +1 位作者 Hanning GUO Yan WANG 《Chinese Journal of Applied Linguistics》 2022年第2期176-193,316,共19页
Embodiment theories proposed that the comprehension of language involves sensory-motor simulation in the brain.The present study examined the brain response to motor compatibility effect in comprehending action-relate... Embodiment theories proposed that the comprehension of language involves sensory-motor simulation in the brain.The present study examined the brain response to motor compatibility effect in comprehending action-related linguistic materials for participants learning Chinese as a second language(L2).In this study,participants are required to read action-related sentences describing an agent performing two manual actions simultaneously or sequentially by manipulating temporal conjunctions.The sentences with simultaneous actions are marked by Chinese parallel structure一边……一边……(“while”)showing non-congruent motor condition while the sequential action sentences are marked by先……然后……(“after”)showing congruent motor condition.Event-Related Potentials(ERPs)were recorded with the second verb phrase.A larger fronto-central late positivity was observed for the sentences with simultaneous actions rather than the sentences with sequential actions due to body constraints,revealing that late L2 Chinese learners integrate embodied knowledge while processing action-related complex sentence despite demanding more cognitive resources,and longer processing time. 展开更多
关键词 EMBODIMENT manual action language motor compatibility effect late positivity L2
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Cowbirds, conservation, and coevolution: potential misconceptions and directions for future research
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作者 Brian D.PEER James W.RIVERS Stephen I.ROTHSTEIN 《Chinese Birds》 CSCD 2013年第1期15-30,共16页
Avian brood parasitism is a model system for studies of coevolution and ecological interactions between parasites and their hosts. However, recent work may have led to misconceptions concerning the Brown-headed Cowbir... Avian brood parasitism is a model system for studies of coevolution and ecological interactions between parasites and their hosts. However, recent work may have led to misconceptions concerning the Brown-headed Cowbird (Molothrus ater), the most widely studied brood parasitic bird in the world, and its effects on host species. Potential misconceptions about this species that could affect management issues are as follows: cowbird populations are increasing; cowbirds are relatively new to North America; recently exposed hosts are defenseless against parasitism; cowbirds have caused widespread declines of songbirds; and cowbird control is always effective in increasing the size of endangered host populations. Potential coevolutionary misconceptions are that cowbirds are typically 'host tolerant'; cowbirds evict host nestmates; and the mafia effect is widespread. It is important to clarify these issues because such misconceptions could hinder our understanding of parasite-host interactions, and thus obscure the direction of basic research and of management efforts taken to limit cowbird impacts on endangered species. We discuss these issues and suggest future research directions to enhance our understanding of this fascinating species. 展开更多
关键词 Brown-headed Cowbird coevolution cowbird control endangered species host tolerant MAFIA Molothrus ater nestling eviction
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Chiral Magnetic Effect and Chiral Phase Transition
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作者 付伟杰 刘玉鑫 吴岳良 《Communications in Theoretical Physics》 SCIE CAS CSCD 2011年第1期123-127,共5页
We study the influence of the chiral phase transition on the chiral magnetic effect. The azimuthal charge-particle correlations as functions of the temperature are calculated. It is found that there is a pronounced cu... We study the influence of the chiral phase transition on the chiral magnetic effect. The azimuthal charge-particle correlations as functions of the temperature are calculated. It is found that there is a pronounced cusp in the correlations as the temperature reaches its critical value for the QCD phase transition. It is predicted that there will be a drastic suppression of the charge-particle correlations as the collision energy in RHIC decreases to below a critical value. We show then the azimuthal charge-particle correlations can be the signal to identify the occurrence of the QCD phase transitions in RHIC energy scan experiments. 展开更多
关键词 QCD phase transitions chiral symmetry chiral magnetic effect
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DESIGN OF POLYMER-SUPPORTEDCHIRAL CATALYSTS
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作者 LEI Yaohui LI Hong HE Binglin 《Chinese Journal of Reactive Polymers》 1999年第1期95-101,共7页
Some structural factors to the design of polymer-supported Chiral Catalysts arediscussed, and some new approaches for designing of polymer-supported catalysts arereviewed in this paper
关键词 Polymer-supported chiral catalyst Microenvironmental control
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Quark Loop Effects on Dressed Gluon Propagator in Framework of Global Color Symmetry Model
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作者 ZONG Hong-Shi 《Communications in Theoretical Physics》 SCIE CAS CSCD 2006年第4X期717-722,共6页
Based on the global color symmetry mode/ (GCM), a method for obtaining the quark loop effects on the dressed gluon propagator in GCM is developed. In the chiral limit, it is found that the dressed gluon propagator c... Based on the global color symmetry mode/ (GCM), a method for obtaining the quark loop effects on the dressed gluon propagator in GCM is developed. In the chiral limit, it is found that the dressed gluon propagator containing the quark loop effects in the Nambu-Goldstone and Wigner phases are quite different. In solving the quark self-energy functions in the two different phases and subsequent study of bag constant one shouM use the above dressed gluon propagator as input. The above approach for obtaining the current quark mass effects on the dressed gluon propagator is quite general and can also be used to calculate the chemical potential dependence of the dressed gluon propagator. 展开更多
关键词 quark loop effects GCM explicit and dynamical chiral symmetry breaking
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有机手性分子器件的光电特性
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作者 解士杰 高腾 +1 位作者 杜梦昭 刘璇 《山东大学学报(理学版)》 CAS CSCD 北大核心 2021年第10期72-78,共7页
目前多种有机手性分子器件虽已研制成功,但其内在的物理机理仍有许多未解之谜,其中手性分子的圆二色性精细结构、手性诱导的自旋选择效应等是有机手性分子研究的核心。为设计基于手性的新型有机功能器件提供理论指导,考虑有机手性分子... 目前多种有机手性分子器件虽已研制成功,但其内在的物理机理仍有许多未解之谜,其中手性分子的圆二色性精细结构、手性诱导的自旋选择效应等是有机手性分子研究的核心。为设计基于手性的新型有机功能器件提供理论指导,考虑有机手性分子螺旋势场诱导的自旋-轨道耦合,围绕分子的光电特性及其调控展开了系列研究。根据光致跃迁理论,得到手性分子的光吸收谱和圆二色谱,发现光吸收峰发生劈裂,圆二色谱由轨道磁矩和自旋磁矩共同贡献。此外,从极化子输运的图像解释了手性诱导自旋选择效应的来源,并利用其电输运特性,设计了手性异质结器件,发现其手性电阻可达7%,整流比达48。 展开更多
关键词 手性 手性诱导的自旋选择效应 自旋过滤 圆二色性 自旋-轨道耦合
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Symmetry Breaking in the Strong Interaction – The Chiral Magnetic Effect
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作者 WANG Fuqiang 《原子核物理评论》 CAS CSCD 北大核心 2024年第1期1-10,共10页
The chiral magnetic effect (CME) refers to a charge separation along a strong magnetic field due to an imbalanced chirality of quarks from interactions with the vacuum topological gluon field. This chiral anomaly is a... The chiral magnetic effect (CME) refers to a charge separation along a strong magnetic field due to an imbalanced chirality of quarks from interactions with the vacuum topological gluon field. This chiral anomaly is a fundamental property of quantum chromodynamics (QCD) and, therefore, an observation of the CME would have far-reaching impact on our understanding of QCD and Nature. The measurements of the CME-sensitive azimuthal correlator Δγ observable in heavy-ion collisions are contaminated by a major background induced by elliptic flow anisotropy. Several novel approaches have been carried out, including a dedicated isobar collision program, to address this flow-induced background. Further background effects, arising from nonflow correlations, have been studied. While the isobar data are consistent with zero CME signal with an upper limit of 10% of the measured Δγ, the Au+Au midcentral data suggest a positive CME signal on the order of 10% of the measured Δγ with a significance of ~2 standard deviations. Future increased statistics and improved detector capability should yield a firm conclusion on the existence (or the lack) of the CME in relativistic heavy-ion collisions. 展开更多
关键词 chiral magnetic effect charge separation Δγcorrelator flow-induced background nonflow
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