The first example of homochiral two dimensional neutral cobalt? 3 amino (S) tyrosine (ATYR) coordination polymer, bis(3 amino (S) tyrosinato )cobalt? 1 was synthesized under the hydrothermal reaction of Co(ClO4)2 ...The first example of homochiral two dimensional neutral cobalt? 3 amino (S) tyrosine (ATYR) coordination polymer, bis(3 amino (S) tyrosinato )cobalt? 1 was synthesized under the hydrothermal reaction of Co(ClO4)2 ·6H2O with ATYR in which 1 displays modest second harmonic generation response. CCDC: 214275.展开更多
A series of chiral salen\|Co(Ⅱ) complexes have been synthesized and characterized, and they are for the first time used as the catalyst for asymmetric borohydride reduction of aromatic ketone. Enantiometric exesses u...A series of chiral salen\|Co(Ⅱ) complexes have been synthesized and characterized, and they are for the first time used as the catalyst for asymmetric borohydride reduction of aromatic ketone. Enantiometric exesses up to 28.2% have been achieved at the room temperature. The influence of substituent on enantioselectivity of the reactions was studied.展开更多
文摘The first example of homochiral two dimensional neutral cobalt? 3 amino (S) tyrosine (ATYR) coordination polymer, bis(3 amino (S) tyrosinato )cobalt? 1 was synthesized under the hydrothermal reaction of Co(ClO4)2 ·6H2O with ATYR in which 1 displays modest second harmonic generation response. CCDC: 214275.
文摘A series of chiral salen\|Co(Ⅱ) complexes have been synthesized and characterized, and they are for the first time used as the catalyst for asymmetric borohydride reduction of aromatic ketone. Enantiometric exesses up to 28.2% have been achieved at the room temperature. The influence of substituent on enantioselectivity of the reactions was studied.
