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MoSi2涂层制备对于双组元离心发动机的影响分析 被引量:2
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作者 张榛 蔡坤 +4 位作者 贾中华 王娜 虞育松 汪凤山 毛晓芳 《西北工业大学学报》 EI CAS CSCD 北大核心 2020年第S01期120-126,共7页
涂覆在双组元发动机推力室表面的MoSi2涂层可以有效地防止金属基材在高温氧化氛围下形成低熔点的金属氧化物。通过真空离子镀和包渗硅化的制备方法,可以令MoSi2涂层更加致密和均匀,大大提高了涂层性能。其涂层试片在1800℃的静态高温下... 涂覆在双组元发动机推力室表面的MoSi2涂层可以有效地防止金属基材在高温氧化氛围下形成低熔点的金属氧化物。通过真空离子镀和包渗硅化的制备方法,可以令MoSi2涂层更加致密和均匀,大大提高了涂层性能。其涂层试片在1800℃的静态高温下可以耐受20 h以上,远远优于传统挂浆和喷涂法制备的试片耐温指标。同时,该工艺方法制备的涂层表面更加光洁致密,在这种条件下更容易令冷却液膜铺展和生存,也更有利于实现液体蒸发换热,以实现发动机燃烧室头部的高效冷却。经实验验证,涂覆了该涂层的发动机在喉部1400℃以上的点火温度下,头部温度仅约100℃,并顺利通过了累计4万秒的寿命摸底考核,这对于发动机性能提升和延寿有重要意义。但是,在MoSi2涂层的制备过程中,钼层的厚度和均匀性控制以及包渗硅化工艺的匹配性都会对发动机可靠性有着重要影响。一旦有钼层残留在涂层内部,就会导致涂层扩散层结构异常,严重影响涂层的结合性和热匹配性,在点火中产生贯穿性裂纹而失效。失效位置往往位于推力室喉部下游,因为该位置较大的温度梯度和相对贫氧的环境导致涂层内部产生应力裂纹并难以自愈合。针对这个问题,必须通过控制钼层厚度、延长包渗时间和称重法检测等措施,以保证钼层足以形成足够厚度的涂层,同时实现完全的硅化而没有残留。通过这些措施可以提高涂层制备质量,保证发动机的工作可靠性。 展开更多
关键词 双组元离心式发动机 MoSi2涂 扩散层结构 液膜冷却
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共沉淀-酸蚀法制备的磁性液体的稳定性分析 被引量:3
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作者 马小娟 李建 《西南师范大学学报(自然科学版)》 CAS CSCD 北大核心 2002年第5期713-717,共5页
以DLVO理论为基础利用扩散双电层结构解释了CoFe2 O4离子型磁性液体的稳定性 ,并分析了影响其稳定的因素 .
关键词 共沉淀-酸蚀法 制备 磁性液体 磁性微粒 稳定性 扩散双电结构 DLVO理论 稳定因素 胶体
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Modifying element diffusion pathway by transition layer structure in high-entropy alloy particle reinforced Cu matrix composites 被引量:2
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作者 Hao-yang YU Wei FANG +2 位作者 Ruo-bin CHANG Pu-guang JI Qing-zhou WANG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2019年第11期2331-2339,共9页
The Al0.3CoCrFeNi high-entropy alloy(HEA)particles reinforced Cu matrix composites(CMCs)were fabricated by mechanical alloying and sintering.Transition layer structure was obtained by multi-step ball milling to invest... The Al0.3CoCrFeNi high-entropy alloy(HEA)particles reinforced Cu matrix composites(CMCs)were fabricated by mechanical alloying and sintering.Transition layer structure was obtained by multi-step ball milling to investigate the related influence on element diffusion behavior and wear properties of CMCs.The results indicate that a new Cu transition layer is generated,and the thickness is about 5μm.Cr element diffuses into the interface via the transition layer,which forms the complex oxide.Because of the structure of Cu transition layer,the diffusion rates of Ni,Co and Fe increase,especially the Ni element.The wear resistance of CMCs is improved by 30%,which is due to the improvement of interface bonding strength,compared with the CMCs without transition layer.This method is applicable to the development of advanced HEA reinforced metallic matrix composites. 展开更多
关键词 high-entropy alloy copper-matrix composites transition layer structure diffusion WEAR
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Interaction Between Large-scale Vortex Structure and Dispersed Particles in a Three Dimensional Mixing Layer 被引量:4
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作者 罗坤 郑友取 +1 位作者 樊建人 岑可法 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2003年第4期377-382,共6页
In order to understand the interaction between large-scale vortex structure and particles, a two-way coupling temporal mixing layer laden with particles at a Stokes number of 5 with different mass loading planted init... In order to understand the interaction between large-scale vortex structure and particles, a two-way coupling temporal mixing layer laden with particles at a Stokes number of 5 with different mass loading planted initially in the upper half region is numerically studied. The pseudospectral method is used for the flow fluid and the Lagrangian approach is employed to trace particles. The momentum coupling effect introduced by a particle is approximated to a point force. The simulation results show that the coherent structures are still dominant in the mixing layer, but the large-scale vortex structure and particle dispersion are modulated. The length of large-scale vortex structure is shortened and the pairing is delayed. At the same time, the particles are distributed more evenly in the whole flow field as the mass loading is increased, but the particle dispersion along the transverse direction differs from that along the spanwise direction, which indicates that the effect by the addition of particle on the spanwise large-scale vortex structure is different from the streamwise counterpart. 展开更多
关键词 INTERACTION MODULATION two-way coupling large-scale vortex structures particle dispersion
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Annealing hardening and deformation behavior of layered gradient Zr–Ti composite 被引量:3
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作者 Yang ZHOU Wei-jun HE +2 位作者 Jia-teng MA Ze-jun CHEN Qing LIU 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2021年第8期2358-2371,共14页
To investigate potential strengthening approaches,multi-layered zirconium–titanium(Zr-Ti)composites were fabricated by hot-rolling bonding and annealing.The microstructures of these composites were characterized usin... To investigate potential strengthening approaches,multi-layered zirconium–titanium(Zr-Ti)composites were fabricated by hot-rolling bonding and annealing.The microstructures of these composites were characterized using scanning electron microscopy with energy dispersive spectroscopy(SEM-EDS)and electron backscatter diffractometry(EBSD).Their mechanical properties were evaluated by uniaxial tension and compression measurements.It was found that the fabricated Zr–Ti composites are composed of alternating Zr/diffusion/Ti layers,and chemical compositions of Zr and Ti showed a gradient distribution in the diffusion layer.Compared with as-rolled samples,annealing can strengthen the layered gradient Zr–Ti composite,and this is mainly caused by solid-solution strengthening and microstructure refinement-induced strengthening.Compared with the raw materials,a synergistic improvement of strength and ductility is achieved in the Zr–Ti composite as a result of the layered gradient microstructure.Tension–compression asymmetry is observed in the Zr–Ti composites,which may be attributed to twinning and microvoids induced by unbalanced diffusion. 展开更多
关键词 Zr–Ti layered structural material diffusion annealing strengthening tension–compression asymmetry yielding ductility
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