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熔融Cu-Al及Al-Si-Mg合金在304不锈钢表面的溶解及反应润湿
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作者 陈勇 郑智斌 +2 位作者 靳德民 李雪 陈俊宏 《机械制造文摘(焊接分册)》 2021年第3期17-24,共8页
利用座滴法在高真空条件下研究了Cu-Al和Al-Mg合金分别在1100~1200℃,700~800℃与304不锈钢的润湿行为。研究表明,铜-钢体系为典型的溶解润湿,铝-钢体系为典型的反应润湿,且最终润湿性随着温度的升高而改善;铜-钢体系中,钢表面的氧化膜... 利用座滴法在高真空条件下研究了Cu-Al和Al-Mg合金分别在1100~1200℃,700~800℃与304不锈钢的润湿行为。研究表明,铜-钢体系为典型的溶解润湿,铝-钢体系为典型的反应润湿,且最终润湿性随着温度的升高而改善;铜-钢体系中,钢表面的氧化膜限制固-液界面传质从而导致差的润湿性,破除氧化膜及Fe在Cu中的扩散作用为熔滴铺展提供驱动力,铺展活化能为51.2 kJ/mol,该活化能对应于Fe在Cu中的扩散激活能(约10 kJ/mol)及破除氧化膜后表面由Fe-O氧化膜转变为纯净Fe时,Fe和Fe 3 O 4单位摩尔表面能的变化(44.9 kJ/mol);铝-钢体系中,前驱膜的产生能够有效促进润湿,前驱膜为界面反应层在三相线外的延伸;铺展动力学可由RPC模型描述,铺展活化能为46.6 kJ/mol,该活化能对应于界面反应生成单位摩尔的Fe_(2)Al_(5)(约25 kJ/mol)及FeAl_(3)(约21 kJ/mol)的反应吉布斯自由能。 展开更多
关键词 反应润湿 扩散润湿 前驱膜 界面行为 304不锈钢
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Development of Al-12Si-xTi system active ternary filler metals for Al metal matrix composites 被引量:5
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作者 张贵锋 苏伟 +1 位作者 张建勋 A.SUZUMURA 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2012年第3期596-603,共8页
To improve the wettability of Al metal matrix composites(Al-MMCs) by common filler metals,Al-12Si-xTi(x=0.1,0.5,1,3.0;mass fraction,%) system active ternary filler metals were prepared.It was demonstrated that alt... To improve the wettability of Al metal matrix composites(Al-MMCs) by common filler metals,Al-12Si-xTi(x=0.1,0.5,1,3.0;mass fraction,%) system active ternary filler metals were prepared.It was demonstrated that although the added Ti existed within Ti(Al1-xSix)3(0≤x≤0.15) phase,the shear strength and shear fracture surface of the developed Al-12Si-xTi brazes were quite similar to those of traditional Al-12Si braze due to the presence of similar microstructure of Al-Si eutectic microstructure with large volume fraction.So,small Ti addition(~1%) did not make the active brazes brittle and hard compared with the conventional Al-12Si braze.The measured melting range of each Al-12Si-xTi foil was very similar,i.e.,580-590 ℃,because the composition was close to that of eutectic.For wettability improvement,with increasing Ti content,the interfacial gap between the Al2O3 reinforcement and filler metal(R/M) could be eliminated,and the amount of the remainder of the active fillers on the composite substrate decreased after sessile drop test at 610 ℃ for 30 min.So,the wettability improvement became easy to observe repeatedly with increasing Ti content.Additionally,the amount and size of Ti(AlSi)3 phase were sensitive to the Ti content(before brazing) and Si content(after brazing). 展开更多
关键词 Al metal matrix composites BRAZING transient liquid phase bonding WETTABILITY filler metal
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