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阳极氧化铝模板上扩散聚合法制备聚苯胺纳米管(线)阵列 被引量:3
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作者 张璐 姚素薇 +1 位作者 张卫国 王宏智 《功能材料》 EI CAS CSCD 北大核心 2005年第11期1765-1768,共4页
以多孔阳极氧化铝(AAO)为模板,利用扩散聚合法让苯胺单体溶液和氧化剂溶液在一维纳米孔道中相互扩散,在孔内形成聚苯胺(PANI)纳米管和纳米线阵列。利用SEM、TEM、IR和XRD等检测技术对阵列进行表征。结果表明,聚合反应优先发生在孔壁上,... 以多孔阳极氧化铝(AAO)为模板,利用扩散聚合法让苯胺单体溶液和氧化剂溶液在一维纳米孔道中相互扩散,在孔内形成聚苯胺(PANI)纳米管和纳米线阵列。利用SEM、TEM、IR和XRD等检测技术对阵列进行表征。结果表明,聚合反应优先发生在孔壁上,并沿孔壁逐层生长,直至形成实心的纳米线阵列。在孔径为60nm的AAO模板内,扩散聚合40min可形成聚苯胺纳米管阵列,2h后形成聚苯胺纳米线阵列;聚苯胺纳米管(线)中同时包含结晶相和无定型相结构。用二探针法测量PANI/AAO复合阵列电阻,计算出单根聚苯胺纳米线的电导率为21.4S/cm。此外,对扩散聚合过程中聚苯胺纳米管(线)阵列的形成原因进行了初步分析和探讨。 展开更多
关键词 聚苯胺 多孔阳极氧化铝 扩散聚合法 纳米 阵列 电导率
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分子印迹聚合物在药物分析中的应用 被引量:7
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作者 蒲家志 汤又文 胡小刚 《华西药学杂志》 CAS CSCD 2003年第2期122-124,共3页
简要介绍分子印迹聚合物 (MIP)的制备过程 ,并利用MIP对药物分子特殊的选择性和识别能力 ,广泛应用于药物分析 ,以及手性药物的分离、富集和提纯。重点综述MIP技术在药物分析方面的应用。
关键词 药物分析 分子印迹聚合 制备技术 共价 非共价 封管聚合 原位聚合 扩散聚合法 悬浮聚合 应用
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A Multi-agent Model to Simulate Regional Land Use Change with an Application to the Poyang Lake Area of China 被引量:1
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作者 闫丹 黄河清 +2 位作者 刘高焕 潘理虎 刘志佳 《Journal of Resources and Ecology》 CSCD 2012年第4期349-358,共10页
In many regions both urban expansion and rural development take place simultaneously, and for the purpose of understanding the dynamic process of land use/cover change (LUCC) in such large areas, this study develops... In many regions both urban expansion and rural development take place simultaneously, and for the purpose of understanding the dynamic process of land use/cover change (LUCC) in such large areas, this study develops a multi-agent based land use model. Taking the Poyang Lake area of China as a typical case, this study applies the mechanism of diffusion-limited aggregation to simulate the behavior of urban agents, while rural land use is illustrated with a bottom-up based model consisting of agent and environment layers. In the agent layer, each household agent makes its own decisions on land use, and at each time interval a government agent takes control of land use by implementing policies. According to incomes and the rate of migrant workers, household agents are divided into six categories, among which different decision rules are followed. For complex LUCC in the Poyang Lake area of China from 1985 to 2005, the artificial society model developed in this study yields results highly consistent with observations. Importantly, it is shown that governmental policies can impose significant effects on the decisions of individual household agents on land use and the multi-agent-based land use model developed in this study provides a robust means for assessing the effectiveness of governmental policies. 展开更多
关键词 land use/cover change (LUCC) multi-agent model urban expansion rural land use diffusion- limited aggregation (DLA)
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