In order to understand the kinetic characteristics of coal gas desorption based on the pulsating injection （PI）, the research experimentally studied the kinetic process of methane desorption in terms of the PI and h...In order to understand the kinetic characteristics of coal gas desorption based on the pulsating injection （PI）, the research experimentally studied the kinetic process of methane desorption in terms of the PI and hydrostatic injection （HI）. The results show that the kinetic curves of methane desorption based on PI and HI are consistent with each other, and the diffusion model can best describe the characteristics of meth- ane desorption. Initial velocity, diffusion capacity and ultimate desorption amount of methane desorption after P! are greater than those after HI, and the ultimate desorption amount increases by 16.7-39.7%. Methane decay rate over the time is less than that of the HI. The PI influences the diffusion model param- eters, and it makes the mass transfer Biot number B＇_i decrease and the mass transfer Fourier series F＇_0 increase. As a result, PI makes the methane diffusion resistance in the coal smaller, methane diffusion rate greater, mass transfer velocity faster and the disturbance range of methane concentration wider than HI. Therefore, the effect of methane desorption based on PI is better than that of HI.展开更多
基金financially supported by the National Basic Research Program of China (No. 2011CB201205)the National Natural Science Foundation of China (No. 51274195)+2 种基金the Natural Science Foundation of Jiangsu Province of China (No. BK2012571)the National Major Scientific Instrument and Equipment Development Project of China (No. 2013YQ17046309)the Education Department Science and Technology Key Project of Henan Province of China (14B440007)
文摘In order to understand the kinetic characteristics of coal gas desorption based on the pulsating injection （PI）, the research experimentally studied the kinetic process of methane desorption in terms of the PI and hydrostatic injection （HI）. The results show that the kinetic curves of methane desorption based on PI and HI are consistent with each other, and the diffusion model can best describe the characteristics of meth- ane desorption. Initial velocity, diffusion capacity and ultimate desorption amount of methane desorption after P! are greater than those after HI, and the ultimate desorption amount increases by 16.7-39.7%. Methane decay rate over the time is less than that of the HI. The PI influences the diffusion model param- eters, and it makes the mass transfer Biot number B＇_i decrease and the mass transfer Fourier series F＇_0 increase. As a result, PI makes the methane diffusion resistance in the coal smaller, methane diffusion rate greater, mass transfer velocity faster and the disturbance range of methane concentration wider than HI. Therefore, the effect of methane desorption based on PI is better than that of HI.
