油菜素内酯提高小麦萌发期间抗盐性机理初探

通过实验确定 0 .1mg LBR为盐胁迫下提高小麦抗盐性的最适浸种浓度 ;在不同浓度NaCl处理下 ,0 .1mg LBR浸种的小麦胚芽鞘长度、地上部分高度、根长、根数、地上部分干重、根干重均明显高于同等浓度NaCl处理的清水浸种的小麦 ;

Electrochemical behaviors of Mg^(2+) and B^(3+) deposition in fluoride molten salts

By using cyclic and linear sweep voltammetry,the electrochemical deposition behaviors of Mg^2＋ and B^3＋ in fluorides molten salts of KF-MgF2 and KF-KBF4 at 880℃ were investigated,respectively.The results show that the electrochemical reduction of Mg^2＋ is a one-step reaction as Mg^2＋＋2e-→Mg in KF-1%MgF2 molten salt,and the electrochemical reduction of B^3＋ is also a one-step reaction as B^3＋＋3e-→B in KF-KBF4 （1%,2% KBF4） molten salts.Both the cathodic reduction reactions of Mg^2＋ and B^3＋ are controlled by diffusion process.The diffusion coefficients of Mg^2＋ in KF-MgF2 molten salts and B^3＋ in KF-KBF4 molten salts are 6.8×10^-7 cm^2/s and 7.85×10^-7 cm^2/s,respectively.Moreover,the electrochemical synthesis of MgB2 by co-deposition of Mg and B was carried out in the KF-MgF2-KBF4 （molar ratio of 6：1：2） molten salt at 750℃.The X-ray diffraction analysis indicates that MgB2 can be deposited on graphite cathode in the KF-MgF2-KBF4 molten salt at 750℃.

Electrochemical behavior of Pb(Ⅱ) in LiCl-KCl-MgCl_2-PbCl_2 melts on Mo electrode

Cyclic voltammetry and chronopotentiometry were used to study the reaction mechanism of Pb（Ⅱ） and the co-deposition of Pb,Mg and Li on molybdenum electrodes in LiCl-KCl-PbCl2-MgCl2 melts.The diffusion coefficient of lead ions in the melts was determined by different electrochemical techniques.The results obtained by cyclic voltammetry and chronopotentiometry indicated that the underpotential deposition of lithium on pre-deposited Pb leads to the formation of a liquid Li-Pb alloy,and the Mg-Li-Pb alloys are formed after the addition of MgCl2.X-ray diffraction confirmed that in the Mg-Li-Pb alloy,PbLi3,Mg2Pb and Li7Pb2 phases exist by galvanostatic electrolysis at 6.21 A/cm2 for 2 h at 873 K and the phases can be controlled by changing the concentration of PbCl2 and MgCl2.

Double-diffusive Fluxes of Salt and Heat in the Upper Layer of North Pacific Intermediate Water

Almost half of the oceanic water columns exhibit double-diffusion. The importance of double-diffusion in global oceans’ salt and heat fluxes, water-mass formation and mixing, and circulation is increasingly recognized. However, such an important physical process in the ocean has not been well studied. One of the reasons is the difficulty of parameterizing and quantifying the processes. The paper presented here attempts to quantify the double-diffusive fluxes of salt and heat in the ocean. Previous qualitative analysis by applying the water-mass Turner angle, mTu, to the North Pacific Intermediate Water (NPIW) layer showed a favorable condition for salt-fingering in the upper NPIW due to the overlying warm/salty water above the cold/fresh NPIW core, and a doubly-stable condition in the lower NPIW where potential temperature decreases with depth while salinity increases, inducing double stratification with respect to both potential temperature and salinity. The present study gives a quantitative estimate of double-diffusive fluxes of salt and heat contributed by salt-fingering in the upper NPIW layer.

Effect of Phosphate on Zinc Transport in Lou Soil

A study on the transport characteristics of zinc in lou soil with phosphate at different concentrations was carried out by the method of step input. The effects of phosphate and temperature on zinc transport were studied through analysing the diffusion-dispersion coefficients (D) and the retardation factor (R) obtained by the program CXTFIT. The results showed that D decreased and R increased with increasing concentration of phosphate so that it was difficult for zinc to break through the soil column, and zinc stopped to break through the column at high temperature. One order equation, double constant equation and the Elovich equation were all suitable for the description of zinc dynamica. Effects of phosphate and temperature on zinc transport were further confirmed by the analysis on pseudo-thermodynamic parameters of zinc transport.

Diffusion Coefficients of l-Lysine Hydrochloride and l-Arginine Hydrochloride in Their Aqueous Solutions at 25℃

The diffusion coefficients of l-lysine hydrochloride and I-arginine hydrochloride in their aqueous solutions at 25℃ were determined by the metallic diaphragm cell method which is characterized by accuracy, promptness and convenience. Meanwhile, the densities and viscosities of the solutions were also determined. Based on all these data a semi-empirical model for correlating the diffusion coefficients of solid organic salts in their aqueous solutions at 25℃ was proposed. The fitting result of this model is comparatively satisfactory. Compared to a former model, Gordon Model, this model can avoid a number of difficulties and arduous work.

Effects of Concentration and Freeze-Thaw on the First Hydration Shell Structure of Zn^(2+) Ions

To investigate the effects of salt concentration and freeze-thaw (FT) on the first hydration shell of Zn2+ ions in Zn(NO_3)_2 aqueous solutions, extended X-ray absorption fine structure (EXAFS) spectroscopy was used to examine Zn K-edge EXAFS spectra of Zn(NO_3)_2 aqueous solutions with various concentrations before and after FT treatment. The influences of salt concentration and freeze-thaw on the structural parameters of the first hydration shell of Zn2+ ions, including hydration number, Zn-O distance and thermal disorder, were analyzed. The results show that Zn2+ ions have 3.2―6.8 nearest oxygen neighbors with the Zn-O distance being 0.202―0.207 nm. In highly concen-trated solutions, Zn2+ ions are hydrated with four water molecules in a tetrahedral form. The dilution of Zn(NO_3)_2 aqueous solutions increases the number of water molecules in the first hydration shell of Zn2+ ions to six with their octahedral arrangement. Both the hydration number in the first hydration shell of Zn2+ ions and the degree of thermal disorder increase when the FT treatment is operated in Zn(NO_3)_2 aqueous solutions.

Characteristics of Channeling Flow in Cultivated Horizon of Saline Rice Soil

By applying bromide ion as tracer, the channeling flow has been quantitatively described in saline rice soil and alkaline soil of Da＇an City, Jilin Province of China. Breakthrough curves of bromide ion in the saline rice soils after 1-year cultivation and 5-year cultivation and alkaline soil have been attained. Results show that the rice cultivation practice can improve the alkaline soil structure, however, it can accelerate the development of channeling flow pathway. Therefore, the channeling flow pathway has been developed widely in saline rice soil, but rarely in the alkaline soil. Three models of convection-dispersion equation （CDE）, transfer functional model （TFM） and Back-Progation Network （BP Network） were used to simulate the transportation process of bromide ion. The peaks of probability density function of saline rice soil are higher with left skewed feature compared with that of the alkaline soil. It shows that the TIM and CDE can simulate the transportation process of the bromide ion in saline rice soil after 5-year cultivation, however, some deviation exists when it was used to simulate transportation process of bromide ion in saline rice soil after 1-year cultivation and alkaline soil; BP network can effectively simulate transportation process of bromide ion in both saline rice soil and alkaline soil.

Recursive calibration for a lithium iron phosphate battery for electric vehicles using extended Kalman filtering

In this paper,an efficient model structure composed of a second-order resistance-capacitance network and a simply analytical open circuit voltage versus state of charge(SOC) map is applied to characterize the voltage behavior of a lithium iron phosphate battery for electric vehicles(EVs).As a result,the overpotentials of the battery can be depicted using a second-order circuit network and the model parameterization can be realized under any battery loading profile,without a special characterization experiment.In order to ensure good robustness,extended Kalman filtering is adopted to recursively implement the calibration process.The linearization involved in the calibration algorithm is realized through recurrent derivatives in a recursive form.Validation results show that the recursively calibrated battery model can accurately delineate the battery voltage behavior under two different transient power operating conditions.A comparison with a first-order model indicates that the recursively calibrated second-order model has a comparable accuracy in a major part of the battery SOC range and a better performance when the SOC is relatively low.

Occurrence andmineral chemistry of chromite and xieite in the Suizhou L6 chondrite

The occurrence and mineral chemistry of chromite and its high-pressure phase xieite in the Suizhou meteorite were studied by different modem micromineralogical techniques. Three types of occurrences for chromite were observed in the Suizhou L6 chondrite： coarse chromite grains, cluster of chromite fragments in molten plagioclase, and exsolution lamellar chromite in oli- vine. All the chromite grains of the first two types are remarkably similar in chemical compositions, but the composition of exsolution chromite is inhomogeneous and variable in A1203 content. Xieite is a post-spinel CT-phase of chromite firstly found in the Suizhou meteorite. Three types of occurrences of xieite have also been revealed in this meteorite： coarse xieite grains, complex three-zone-grains consisting of the inner xieite, the intermediate lamellae-like CF-phase and the outer chromite phase, and two-phase-grains consisting of xieite and one of the high-pressure silicate minerals lingunite, ringwoodite or majorite. The curved boundary between xieite and the silicate half in two-phase grains is indicative of some partial or even full melting of the silicate phase. EPMA and EDS results show that the compositions of xieite inside/contacting the shock veins are also identical to that of chromite outside the veins. However, some element diffusion appeared in between the xieite and the silicate half in the two-phase grains, namely, some of Al^3＋ from lingunite, or Fe^2＋ from ringwoodite migrated to xieite, and some of Cr^3＋ migrated from xieite to lingunite or ringwoodite. Majorite in two-phase grains shows remarkable decrease of SiO2 and MgO, and notable increase of Al2O3 and CaO, indicating that its host mineral pyroxene was fully molten and mixed with the surrounding silicate melt of the vein matrix. The complexity in mineral chemistry of these two-phase grains in shock veins can be explained by the much higher shock peak temperature in shock veins （1800-2000℃） than in unmelted main body （-1000℃）, and by the much lower density of the silicate minerals （2.6-3.3 g/cm3） than that of chromite （4.43 g/cm^3）. Being a refractory and a rela-tively high-impedance material, chromite is chemically more stable and easier to reflect shock wave into the silicate half causing the partial or even full melting of silicate phases, upon which some diffusion of elements between the two phases them-selves, or even mixing of molten pyroxene and the surrounding silicate melt.