金属-氧化物-半导体结构电容-电压特性的扫描非线性介电显微镜表征(英文)

扫描非线性介电显微镜(SNDM)利用非线性介电效应检测电容的变化情况,分辨率达到亚纳米量级,精度达到10-22F,主要应用于材料微区的电性能研究,目前以这项技术进行的研究主要集中在铁电材料和半导体材料方面,相关的报道也较少。本研究用扫描非线性介电显微镜对集成电路中具有n型与p型掺杂的60μm×60μm区域进行二维表征,得到定点非线性电容与电压的关系曲线,并由积分得到对应的电容电压特性曲线,认为界面陷阱的作用是金属-氧化物-半导体非线性电容-电压特性曲线突变的影响因素。

扫描介电成像技术及其在生物体系的应用

通过实例介绍了近一二年新开发的一种扫描探针显微技术———扫描介电显微镜 (SDM)的基本原理、测量系统的构造和特点 。

Experimental Investigation of Dust Deposit within Ceramic Filter Medium during Filtration-Cleaning Cycles

The penetration and deposit of particles within the medium is thought to be one reason that the residual pressure drop of the rigid ceramic filter increase with cycle number.In this study,the change in the microstructure of a single layer ceramic filter candle during filtration-cleaning cycle was observed by scanning electron microscope(SEM) and the resistance property of the filter was monitored accordingly.The experimental results show that there exists a serious dust deposit within the filter medium,especially at the surface region.This should be responsible for the decrease of the filter permeability.The deposit law of dust in the filter medium during filtration-cleaning cycle was then studied by measuring the deposit depth,the deposit amount,the particles distribution within the medium,the size distribution of deposited particles,and so on.Particles migration and fine particles penetration were found to be the main reasons,for which dust deposit within the filter medium became aggravated with cycle number.Based on a differential form of Ergun equation,an expression for the pressure drop of a used ceramic filter was developed with a good agreement with experimental results.Then,the effect of dust deposit on the residual pressure drop was studied at the different face velocities and dust sizes.It was found that face velocity and dust size significantly influence dust deposit within filter medium,and then the operation performance of the filter.

Study on Hydrothermal Stability and Catalytic Activity of Al-SBA-15 Mesoporous Materials Prepared by Impregnation Method

The mesoporous Al-SBA-15 zeolite was obtained via impregnation of pure silica-based SBA-15 zeolite with aluminum nitrate.The Al-SBA-15 sample was calcined in air at 800 ℃ for 6 h and hydrothermally treated at near 100 ℃ for 120 h,respectively,and then the thermal and hydrothermal stability of Al-SBA-15 sample was investigated by X-ray diffractometry (XRD),scanning electron microscopy (SEM),transmission electron microscopy (TEM) and nitrogen adsorption and desorption techniques.The Al-SBA-15 sample was also studied by 27 Al nuclear magnetic resonance (27 Al NMR) and ammonia temperature programmed desorption (NH 3-TPD) techniques.In addition,the catalytic activity of Al-SBA-15 zeolite was investigated by the Friedel-Crafts reactions of 2,4-di-tert-butylphenol with cinnamyl alcohol.The test results showed that the thermal and hydrothermal stability of Al-SBA-15 zeolite was better than that of SBA-15 zeo-lite.The Al-SBA-15 zeolite sample prepared by impregnation method exhibits more framework aluminum species and Al-O-Si units.Therefore,the number of the surface hydroxyl groups was reduced,resulting in the stabilization of framework structure ofAl-SBA-15 zeolite.The aluminum species can form weak and medium-strong acid sites with catalytic activity.

Structure and stability of Li-Mn-Ni composite oxides as lithium ion sieve precursors in acidic medium

A series of spinel Li-Mn-Ni composite oxides with theoretical chemical formula of LiNixMn2-xO4 （0〈_x〈_1.0） were synthesized by liquid phase method. Their structure and morphology were characterized by X-ray diffractometry （XRD） and scanning electron microscopy （SEM）, respectively. The stability of these Ni-substituted spinel oxides prepared at different temperatures was investigated in acidic medium as well. The results show that Ni can be brought into the spinel framework completely to form well-crystallized product when x〈_0.5 and the optimized synthesis temperature is 800℃. LiNi0.4Mn1.6O4 prepared at 800℃ can maintain the spinel structure and morphology with Li extraction ratio of 30.37%, Mn extraction ratio of 8.78% and Ni extraction ratio of 1,82% during acid treatment. The incorporated Ni not only inhibits the dissolution of Mn, but also reduces the extraction of Li due to the lattice contraction

Hierarchical 3D mesoporous silicon@graphene nanoarchitectures for lithium ion batteries with superior performance

Silicon has been recognized as the most promising anode material for high capacity lithium ion batteries. However, large volume variations during charge and discharge result in pulverization of Si electrodes and fast capacity loss on cycling. This drawback of Si electrodes can be overcome by combination with well-organized graphene foam. In this work, hierarchical three-dimensional carbon-coated mesoporous Si nanospheres@graphene foam （C@Si@GF） nanoarchitectures were successfully synthesized by a thermal bubble ejection assisted chemical-vapor-deposition and magnesiothermic reduction method. The morphology and structure of the as-prepared nanocomposites were characterized by field emission scanning electron microscopy, transmission electron microscopy and Raman spectroscopy. When employed as anode materials in lithium ion batteries, C@Si@GF nanocomposites exhibited superior electrochemical per- formance including a high specific capacity of 1,200 mAh/g at the current density of 1A/g, excellent high rate capabilities and an outstanding cyclability. Post-mortem analyses identified that the morphology of 3D C@Si@GF electrodes after 200 cycles was well maintained. The synergistic effects arising from the combination of mesoporous Si nanospheres and graphene foam nanoarchitectures may address the intractable pulverization problem of Si electrode.

Clean transfer of graphene on Pt foils mediated by a carbon monoxide intercalation process

Noble metals such as Pt are a perfect substrate for the catalytic growth of monolayer graphene. However, the requirements of the subsequent transfer process are not compatible with the traditional etching method. In this work, we find that the interaction of graphene with Pt foil can be weakened through the intercalation of carbon monoxide （CO） under ambient pressure. This intercalation process occurs on both hexagonal-shape graphene islands and irregular graphene patches on changing the CO partial pressure from 0 to 0.6 MPa, as observed by scanning electron microscopy （SEM）, Raman spectroscopy and X-ray photoemission spectroscopy. We demonstrate that, on a practical timescale, the intercalation ratio is proportional to the partial pressure of CO. Furthermore, we develop a clean transfer method of CO-intercalated graphene with water as a peeling agent. We show that this method enables the transfer of tens of micrometer-scale graphene patches onto SiO2/Si, which are free from metal or oxide particle contamination. This transfer method should be a significant step towards the dean transfer of graphene, as well as the recydable use of noble metal substrates.