根据IASI(Infrared Atmospheric Sounding Interferometer)的资料特征和GRAPES(Global/Regional Assimilation and Prediction System)同化系统的具体情况,建立了适用于业务使用的关于IASI辐射率资料的偏差订正方案,该方案包括扫描...根据IASI(Infrared Atmospheric Sounding Interferometer)的资料特征和GRAPES(Global/Regional Assimilation and Prediction System)同化系统的具体情况,建立了适用于业务使用的关于IASI辐射率资料的偏差订正方案,该方案包括扫描偏差订正和气团偏差订正。统计表明,IASI资料的扫描偏差不像微波资料一样具有明显的纬度依赖性,但在2x2的像元内存在某种特殊的扫描偏差,临边测量相对于星下点的扫描偏差可以用"扫描角"作为自变量而消除,而2x2的像元内的偏差只能通过稀疏化来规避;气团偏差主要根据当时的天气条件进行订正,利用模式背景场作为预报因子定量给出天气条件,采用1 000~300 h Pa的厚度、200~50 h Pa的厚度、50~20 h Pa的厚度以及模式地表温度作为预报因子。订正方案的试验结果显示,偏差能够长时间维持在比较低的稳定水平,订正结果显著。展开更多
In this study,the sol-gel method was introduced to prepare the composite phase change material (CPCM). The CPCM was added to fabric with coating techniques and the thermal activity of modified fabric was studied. In a...In this study,the sol-gel method was introduced to prepare the composite phase change material (CPCM). The CPCM was added to fabric with coating techniques and the thermal activity of modified fabric was studied. In addition,the thermal property and the microstructure of CPCM were also discussed in detail by means of polarization microscope and differential scanning calorimeter,respectively. According to the analysis of main influencial factors of the property of CPCM,the optimal preparing technique was determined. It was proved that CPCM could exhibit a good thermal property while phase transformation process took place,and a better appearance of the fabric modified with CPCM could be obtained due to the fact that in a warm circumstance,the liquid-state phase change material could be firmly enwrapped and embedded in the three-dimensional network all the time during the phase transformation. Besides,the fabric treated with CPCM had a high phase-transition enthalpy and an appropriate phase-transition temperature. As a result,a desirable temperature-adjustable function appeared.展开更多
Expanded graphite (r-;G) shows higher adsorption capacity for oils than for dyes. To illustrate the different adsorption mechanism of EG for these pollutants, adsorption capacities of dyes and oil on EG were firs...Expanded graphite (r-;G) shows higher adsorption capacity for oils than for dyes. To illustrate the different adsorption mechanism of EG for these pollutants, adsorption capacities of dyes and oil on EG were firstly studied. And then stepwise adsorption for oils was carried out with EG which has been saturated firstly by dyes, the difference between adsorbance of oil on EG was checked with deviation analysis. Scanning electronic microscopy (SEM) analysis was used to show structure difference of EG adsorbed different adsorbates. These used adsorbates were SD300 oil, basic fuchsine, Auramine lake yellow O and acid brilliant red 3B. The adsorption isotherm of dyes on EG is type 11 or type 1, and their equilibrium adsorbances are less than 1.0 g/g. While, adsorbance for SD300 oil can reach 104.5 g/g. Deviation analysis for stepwise adsorbances of oil shows no statistical significance. EG saturated firstly by dyes, still has an average adsorption capacity of 35 g/g for SD300 oil, and it does not change with the initial dyes concentration. SEM photos illustrate the adsorption of oil on EG is mainly filling, In the adsorption of dyes, there is severe breakage of the V-type pore and shrinkage of the particle. Kinetic difference is analyzed also.展开更多
Twelve triphenylene discogens with unsaturated periphery (abbreviated as C18H6(OC5H11)6-x(OR)x(x=1,2,3), R=-C3H6CH==CH2(a),-C3H6C≡CH(b),-C2H4OCH==CH2(c)) were synthesized and characterized. The thermotropic liquid cr...Twelve triphenylene discogens with unsaturated periphery (abbreviated as C18H6(OC5H11)6-x(OR)x(x=1,2,3), R=-C3H6CH==CH2(a),-C3H6C≡CH(b),-C2H4OCH==CH2(c)) were synthesized and characterized. The thermotropic liquid crystal prop-erties were studied by using polarized optical microscopy, differential scanning calorimetry and X-ray diffractometry. The results showed that all triphenylenes exhibited hexagonal columnar mesophase. The thermotropic studies showed that series a (alkene periphery) exhibited higher clearing points than the corresponding series b (alkyne periphery), while series c (vinyloxy periphery) exhibited highest clearing points and widest mesophase temperature ranges. We also found that the symmetric discogens sym-C18H6(OC5H11)3(OR)3 displayed higher melting points and clearing points than the asymmetric ones asym-C18H6(OC5H11)3(OR)3.展开更多
文摘根据IASI(Infrared Atmospheric Sounding Interferometer)的资料特征和GRAPES(Global/Regional Assimilation and Prediction System)同化系统的具体情况,建立了适用于业务使用的关于IASI辐射率资料的偏差订正方案,该方案包括扫描偏差订正和气团偏差订正。统计表明,IASI资料的扫描偏差不像微波资料一样具有明显的纬度依赖性,但在2x2的像元内存在某种特殊的扫描偏差,临边测量相对于星下点的扫描偏差可以用"扫描角"作为自变量而消除,而2x2的像元内的偏差只能通过稀疏化来规避;气团偏差主要根据当时的天气条件进行订正,利用模式背景场作为预报因子定量给出天气条件,采用1 000~300 h Pa的厚度、200~50 h Pa的厚度、50~20 h Pa的厚度以及模式地表温度作为预报因子。订正方案的试验结果显示,偏差能够长时间维持在比较低的稳定水平,订正结果显著。
基金Fujian Province I mportant Science and Technology Development Fund,China (No.2005Z17)
文摘In this study,the sol-gel method was introduced to prepare the composite phase change material (CPCM). The CPCM was added to fabric with coating techniques and the thermal activity of modified fabric was studied. In addition,the thermal property and the microstructure of CPCM were also discussed in detail by means of polarization microscope and differential scanning calorimeter,respectively. According to the analysis of main influencial factors of the property of CPCM,the optimal preparing technique was determined. It was proved that CPCM could exhibit a good thermal property while phase transformation process took place,and a better appearance of the fabric modified with CPCM could be obtained due to the fact that in a warm circumstance,the liquid-state phase change material could be firmly enwrapped and embedded in the three-dimensional network all the time during the phase transformation. Besides,the fabric treated with CPCM had a high phase-transition enthalpy and an appropriate phase-transition temperature. As a result,a desirable temperature-adjustable function appeared.
文摘Expanded graphite (r-;G) shows higher adsorption capacity for oils than for dyes. To illustrate the different adsorption mechanism of EG for these pollutants, adsorption capacities of dyes and oil on EG were firstly studied. And then stepwise adsorption for oils was carried out with EG which has been saturated firstly by dyes, the difference between adsorbance of oil on EG was checked with deviation analysis. Scanning electronic microscopy (SEM) analysis was used to show structure difference of EG adsorbed different adsorbates. These used adsorbates were SD300 oil, basic fuchsine, Auramine lake yellow O and acid brilliant red 3B. The adsorption isotherm of dyes on EG is type 11 or type 1, and their equilibrium adsorbances are less than 1.0 g/g. While, adsorbance for SD300 oil can reach 104.5 g/g. Deviation analysis for stepwise adsorbances of oil shows no statistical significance. EG saturated firstly by dyes, still has an average adsorption capacity of 35 g/g for SD300 oil, and it does not change with the initial dyes concentration. SEM photos illustrate the adsorption of oil on EG is mainly filling, In the adsorption of dyes, there is severe breakage of the V-type pore and shrinkage of the particle. Kinetic difference is analyzed also.
基金supported by the National Natural Science Foundation of China (50973076 & 51073112)
文摘Twelve triphenylene discogens with unsaturated periphery (abbreviated as C18H6(OC5H11)6-x(OR)x(x=1,2,3), R=-C3H6CH==CH2(a),-C3H6C≡CH(b),-C2H4OCH==CH2(c)) were synthesized and characterized. The thermotropic liquid crystal prop-erties were studied by using polarized optical microscopy, differential scanning calorimetry and X-ray diffractometry. The results showed that all triphenylenes exhibited hexagonal columnar mesophase. The thermotropic studies showed that series a (alkene periphery) exhibited higher clearing points than the corresponding series b (alkyne periphery), while series c (vinyloxy periphery) exhibited highest clearing points and widest mesophase temperature ranges. We also found that the symmetric discogens sym-C18H6(OC5H11)3(OR)3 displayed higher melting points and clearing points than the asymmetric ones asym-C18H6(OC5H11)3(OR)3.