Although different NbO_(x) units are present in Nb_(2)O_(5)‐based catalysts,the correlations between these structures and activity remain unclear,which considerably hinders the further development of Nb_(2)O_(5) phot...Although different NbO_(x) units are present in Nb_(2)O_(5)‐based catalysts,the correlations between these structures and activity remain unclear,which considerably hinders the further development of Nb_(2)O_(5) photocatalysis.Herein,we utilized N‐hydroxyphthalimide(NHPI)as the probe molecule to distinguish the role of different NbO_(x) units in the activation of C–H bond under visible light irradia‐tion.With the addition of NHPI,Nb_(2)O_(5) catalysts with highly disordered NbO_(6) units exhibited higher activities than that with slightly disordered NbO_(6) units(419‒495 vs.82μmol·g^(-1)·h^(-1))in photocata‐lytic selective oxidation of ethylbenzene.Revealed by Raman spectra,electron paramagnetic reso‐nance spectra,and transmission‐electron‐microscopy images,highly disordered NbO_(6) units were confirmed to act as the active sites for the transfer of photogenerated electrons from NHPI,pro‐moting the generation of phthalimide‐N‐oxyl(PINO)radicals for the enhanced conversion of ethylbenzene under visible light irradiation.This study provides guidance on the role of local NbO_(x) units in Nb_(2)O_(5) photocatalysis.展开更多
Taizhou Yangtze River Highway Bridge is the first three-pylon two-span suspension bridge in China. The main girder adopts flat steamline steel closed box girder which has well wind-resistant capability and is technica...Taizhou Yangtze River Highway Bridge is the first three-pylon two-span suspension bridge in China. The main girder adopts flat steamline steel closed box girder which has well wind-resistant capability and is technically mature besides beautiful appearance. Straight web plates of the steel box girder in longitudinal direction are proposed in order to ensure the integrity of the steel box girder, and to keep the stress of the steel box girder continuous in the middle pylon, as well as to reduce the gradient of the middle pylon columns. The cross section of the box girder has one box with three cells. Solid-web diaphragm plate with good integrity and high torsional stiffness is adopted. The lifting lugs are utilized in the anchors of suspender cable. In this paper, selection of the cross section of the steel box girder, the general structure design, local structure design and main structure calculation results of Taizhou Yangtze River Bridge are introduced emphatically.展开更多
Twisted trilayer graphene(TLG)may be the simplest realistic system so far,which has flat bands with nontrivial topology.Here,we give a comprehensive calculation about its band structures and the band topology,i.e.,val...Twisted trilayer graphene(TLG)may be the simplest realistic system so far,which has flat bands with nontrivial topology.Here,we give a comprehensive calculation about its band structures and the band topology,i.e.,valley Chern number of the nearly flat bands,with the continuum model.With realistic parameters,the magic angle of twisted TLG is about 1.12°,at which two nearly flat bands appears.Unlike the twisted bilayer graphene,a small twist angle can induce a tiny gap at all the Dirac points,which can be enlarged further by a perpendicular electric field.The valley Chern numbers of the two nearly flat bands in the twisted TLG depends on the twist angleθand the perpendicular electric field E⊥.Considering its topological flat bands,the twisted TLG should be an ideal experimental platform to study the strongly correlated physics in topologically nontrivial flat band systems.And,due to its reduced symmetry,the correlated states in twisted TLG should be quite different from that in twisted bilayer graphene and twisted double bilayer graphene.展开更多
The design of the re-entry space vehicles and high-speed aircraft structures requires special attention to the non-linear thermoelastic and aerodynamic instabilities.The thermal effects are important since temperature...The design of the re-entry space vehicles and high-speed aircraft structures requires special attention to the non-linear thermoelastic and aerodynamic instabilities.The thermal effects are important since temperature environment influences significantly the static and dynamic behaviors of flight structures in supersonic/hypersonic regimes.The dynamic behavior of a double-wedge lifting surface with combined freeplay and cubic stiffening structural nonlinearities in both plunging and pitching degrees-of-freedom(DOF) operating in supersonic/hypersonic flight speed regimes has been analyzed.In addition a third order piston theory aerodynamics(PTA) is used to evaluate the non-linear unsteady aerodynamic loads applied to the wing section.Loss of torsional stiffness that may be incurred by lifting surfaces subjected to axial stresses induced by aerodynamic heating is also considered.The aerodynamic heating effect is estimated based on the adiabatic wall temperature due to high speed airstreams.It is demonstrated that serious losses of torsional stiffness may occur in such lifting surfaces;the influence of various parameters such as flight condition,thickness ratio,freeplays and pitching stiffness nonlinearity are discussed.展开更多
文摘Although different NbO_(x) units are present in Nb_(2)O_(5)‐based catalysts,the correlations between these structures and activity remain unclear,which considerably hinders the further development of Nb_(2)O_(5) photocatalysis.Herein,we utilized N‐hydroxyphthalimide(NHPI)as the probe molecule to distinguish the role of different NbO_(x) units in the activation of C–H bond under visible light irradia‐tion.With the addition of NHPI,Nb_(2)O_(5) catalysts with highly disordered NbO_(6) units exhibited higher activities than that with slightly disordered NbO_(6) units(419‒495 vs.82μmol·g^(-1)·h^(-1))in photocata‐lytic selective oxidation of ethylbenzene.Revealed by Raman spectra,electron paramagnetic reso‐nance spectra,and transmission‐electron‐microscopy images,highly disordered NbO_(6) units were confirmed to act as the active sites for the transfer of photogenerated electrons from NHPI,pro‐moting the generation of phthalimide‐N‐oxyl(PINO)radicals for the enhanced conversion of ethylbenzene under visible light irradiation.This study provides guidance on the role of local NbO_(x) units in Nb_(2)O_(5) photocatalysis.
基金National Science and Technology Support Program of China ( No. 2009BAG15B01) Key Programs for Science and Technology Development of Chinese Transportation Industry( No. 2008-353-332-170)
文摘Taizhou Yangtze River Highway Bridge is the first three-pylon two-span suspension bridge in China. The main girder adopts flat steamline steel closed box girder which has well wind-resistant capability and is technically mature besides beautiful appearance. Straight web plates of the steel box girder in longitudinal direction are proposed in order to ensure the integrity of the steel box girder, and to keep the stress of the steel box girder continuous in the middle pylon, as well as to reduce the gradient of the middle pylon columns. The cross section of the box girder has one box with three cells. Solid-web diaphragm plate with good integrity and high torsional stiffness is adopted. The lifting lugs are utilized in the anchors of suspender cable. In this paper, selection of the cross section of the steel box girder, the general structure design, local structure design and main structure calculation results of Taizhou Yangtze River Bridge are introduced emphatically.
基金the National Natural Science Foundation of China(11534001,11874160,11274129,11874026,and 61405067)the National Key Research and Development Program of China(2017YFA0403501)+1 种基金the Fundamental Research Funds for the Central Universities(HUST:2017KFYXJJ027)the National Basic Research Program of China(2015CB921102).
文摘Twisted trilayer graphene(TLG)may be the simplest realistic system so far,which has flat bands with nontrivial topology.Here,we give a comprehensive calculation about its band structures and the band topology,i.e.,valley Chern number of the nearly flat bands,with the continuum model.With realistic parameters,the magic angle of twisted TLG is about 1.12°,at which two nearly flat bands appears.Unlike the twisted bilayer graphene,a small twist angle can induce a tiny gap at all the Dirac points,which can be enlarged further by a perpendicular electric field.The valley Chern numbers of the two nearly flat bands in the twisted TLG depends on the twist angleθand the perpendicular electric field E⊥.Considering its topological flat bands,the twisted TLG should be an ideal experimental platform to study the strongly correlated physics in topologically nontrivial flat band systems.And,due to its reduced symmetry,the correlated states in twisted TLG should be quite different from that in twisted bilayer graphene and twisted double bilayer graphene.
基金the China Post Doctor National Fund (No.AD4122,2008)
文摘The design of the re-entry space vehicles and high-speed aircraft structures requires special attention to the non-linear thermoelastic and aerodynamic instabilities.The thermal effects are important since temperature environment influences significantly the static and dynamic behaviors of flight structures in supersonic/hypersonic regimes.The dynamic behavior of a double-wedge lifting surface with combined freeplay and cubic stiffening structural nonlinearities in both plunging and pitching degrees-of-freedom(DOF) operating in supersonic/hypersonic flight speed regimes has been analyzed.In addition a third order piston theory aerodynamics(PTA) is used to evaluate the non-linear unsteady aerodynamic loads applied to the wing section.Loss of torsional stiffness that may be incurred by lifting surfaces subjected to axial stresses induced by aerodynamic heating is also considered.The aerodynamic heating effect is estimated based on the adiabatic wall temperature due to high speed airstreams.It is demonstrated that serious losses of torsional stiffness may occur in such lifting surfaces;the influence of various parameters such as flight condition,thickness ratio,freeplays and pitching stiffness nonlinearity are discussed.