干柱色谱是借助毛细管作用或/和重力作用进行层析的色谱,其色谱柱形式有塑料干柱、尼龙柱[1]、加压玻璃柱[2]、减压干柱[3]和"高分辨制备型组件"(preparative high resolution segment,PHS)[4].因设备简单、分离速度快、展开...干柱色谱是借助毛细管作用或/和重力作用进行层析的色谱,其色谱柱形式有塑料干柱、尼龙柱[1]、加压玻璃柱[2]、减压干柱[3]和"高分辨制备型组件"(preparative high resolution segment,PHS)[4].因设备简单、分离速度快、展开剂量少、污染小、流动相选择范围广、上样量大、分辨率及色谱行为与TLC相当,干柱色谱曾一度成为实验室常规分离和制备的首选方法.但传统干柱装置具有两大缺陷:第一不可拆装,第二不承载压力.实际应用时,前者造成柱床填装不易和填料取出不便,后者无法使用柱床压缩技术以确保柱床填装密度的均一性,分辨率及柱效的可靠性难以保障,也不能使用小粒径填料以进一步提高柱效,在高效制备型色谱高度商业化的今天,干柱色谱大有趋向淘汰之势.展开更多
An experimental study, in which six columns were loaded concentrically toinvestigate the behavior of reinforced normal strength and high strength circular columns underconcentric compression, is described. The concret...An experimental study, in which six columns were loaded concentrically toinvestigate the behavior of reinforced normal strength and high strength circular columns underconcentric compression, is described. The concrete strengths of the columns were 30 MPa and 60 MPa.The primary variables considered were the concrete strength and the amount of transversereinforcement. Test results indicate that smaller hoop spacing provides higher column capacity andgreater strength enhancement in a confined concrete core of columns. For the same lateralconfinement, high strength concrete columns develop lower strength enhancement than normal strengthconcrete columns. Both the strength enhancement ratio (f'_(cc) /f'_(co)) and the column capacityratio (P_(test)/P_o) were observed to show linear increase variations with rho_s f_(yt)/f'_c incircular columns.展开更多
Based on the engineering project on a small coal pillar of 12,521 working face roadway in Xieqiao Coalmine, data regarding surface displacements of the coal pillar, deep displacements and mining stress have been colle...Based on the engineering project on a small coal pillar of 12,521 working face roadway in Xieqiao Coalmine, data regarding surface displacements of the coal pillar, deep displacements and mining stress have been collected and analyzed. The results show that macroscopic transverse fractures of the inner coal pillar are developed within 2–4 m of the roadway surface, which is located outside the coal pillar anchorage zone. There is a displacement of 530 mm at the monitoring point in the 6 m deep zone of the pillar. Transfer of the fracture zone is found in a small coal pillar and the fractures within 3–4 m of the coal-rock zone from the roadway surface undergo propagation and closure of cracks which means this fracture zone is transferred from 3–4 m outside the roadway to only 2–3 m from the roadway surface. In the monitoring zone, vertical and horizontal stresses increase with a feature that shows that acceleration in the deep zone of the pillar is greater than that in the shallow zone. Furthermore, the acceleration of vertical stress is also greater than that of horizontal stress with a peak value in the 4 m zone.The research findings provide a reference for the regulation of a reasonable width of coal pillar in coalmines and optimal control design of surrounding rock.展开更多
Hydrostatic slipper was often used in friction bearing design, allowing improvement of the latter's dynamic behavior. The influence of thermal effect on hydrostatic slipper bearing capacity of axial piston pump wa...Hydrostatic slipper was often used in friction bearing design, allowing improvement of the latter's dynamic behavior. The influence of thermal effect on hydrostatic slipper bearing capacity of axial piston pump was investigated. A set of lumped parameter mathematical models were developed based on energy conservation law of slipper/ swash plate pair. The results show that thermal equilibrium clearance due to solid thermal deformation periodically changes with shaft rotational angle. The slipper bearing capacity increases dramatically with decreasing thermal equilibrium clearance. In order to improve the slipper bearing capacity, length-to-diameter ratio of fixed damper varies from 3.5 to 8.75 and radius ratio of slipper varies from 1.5 to 2.0. In addition, the higher slipper thermal conductivity is useful to improve slipper bearing capability, but the thermal equilibrium clearance is not compromised.展开更多
Coal seams in Tashan Mine of Datong Coal Group in China average 15 m thick and have been mined by the top coal caving longwall mining method of large mining height. Mining height was 3.8 m and the top coal caving heig...Coal seams in Tashan Mine of Datong Coal Group in China average 15 m thick and have been mined by the top coal caving longwall mining method of large mining height. Mining height was 3.8 m and the top coal caving height was 11.2 m. The gateroad pillar between panels was 38 m. During retreat mining,serious bumps occurred in the gateroads on both sides of the pillar affecting safety production. Therefore,pillarless mining was experimented. Using numerical modeling and comparative study of cases of similar mining condition,it was decided to employ a 6 m wide pillar,rather than the previous 38 m wide pillar.Support system for the gateroads was designed and implemented. During gateroad development,pillar failure conditions and entry deformation were monitored. Hydraulic fracturing method was employed to cut off the K3 sandstone along the entry rib so as to reduce the abutment pressure induced during retreat mining. Support reinforcement method combining grouting and advanced reinforcement methods was proposed to insure stable gateroad ahead of mining. Methane drainage and nitrogen injection were implemented to eliminate hazards associated with mine fire and spontaneous combustion. Since the development of gateroad has just completed,and retreat mining has not begun,the effectiveness of the proposed methods is unknown at this point. However,monitoring will continue until after mining.The results will be published in a separate paper.展开更多
To better study the behavior of confined concrete, this paper presents the basic hypothesis of uhimate equilibrium of confined concrete and the unified yield criteria of confining material. Based on the static equilib...To better study the behavior of confined concrete, this paper presents the basic hypothesis of uhimate equilibrium of confined concrete and the unified yield criteria of confining material. Based on the static equilibrium condition and yield criteria of components, a unified bearing capacity model of confined concrete column is proposed, and a simplified calculating equation of the model is also given. The model captures the character of confined concrete column. Effects of the confinement effect ratio, the lateral confinement ratio, unconfined concrete strength and the properties of confining material on the bearing capacity of confined concrete column are carefully considered. The model may be applicable to the calculation of bearing capacity of steel-confined concrete, concrete filled steel tube and FRP-confined concrete. The predictions of the model agree well with test data.展开更多
文摘干柱色谱是借助毛细管作用或/和重力作用进行层析的色谱,其色谱柱形式有塑料干柱、尼龙柱[1]、加压玻璃柱[2]、减压干柱[3]和"高分辨制备型组件"(preparative high resolution segment,PHS)[4].因设备简单、分离速度快、展开剂量少、污染小、流动相选择范围广、上样量大、分辨率及色谱行为与TLC相当,干柱色谱曾一度成为实验室常规分离和制备的首选方法.但传统干柱装置具有两大缺陷:第一不可拆装,第二不承载压力.实际应用时,前者造成柱床填装不易和填料取出不便,后者无法使用柱床压缩技术以确保柱床填装密度的均一性,分辨率及柱效的可靠性难以保障,也不能使用小粒径填料以进一步提高柱效,在高效制备型色谱高度商业化的今天,干柱色谱大有趋向淘汰之势.
文摘An experimental study, in which six columns were loaded concentrically toinvestigate the behavior of reinforced normal strength and high strength circular columns underconcentric compression, is described. The concrete strengths of the columns were 30 MPa and 60 MPa.The primary variables considered were the concrete strength and the amount of transversereinforcement. Test results indicate that smaller hoop spacing provides higher column capacity andgreater strength enhancement in a confined concrete core of columns. For the same lateralconfinement, high strength concrete columns develop lower strength enhancement than normal strengthconcrete columns. Both the strength enhancement ratio (f'_(cc) /f'_(co)) and the column capacityratio (P_(test)/P_o) were observed to show linear increase variations with rho_s f_(yt)/f'_c incircular columns.
基金the Program for Changjiang Scholars and Innovative Research Team in University (No. IRT1084)the Open Fund of Hunan provincial Key Laboratory for Safe Mining Technology of Coal Mine (No. 201103)the National Natural Science Foundation of China (No. 51274193)
文摘Based on the engineering project on a small coal pillar of 12,521 working face roadway in Xieqiao Coalmine, data regarding surface displacements of the coal pillar, deep displacements and mining stress have been collected and analyzed. The results show that macroscopic transverse fractures of the inner coal pillar are developed within 2–4 m of the roadway surface, which is located outside the coal pillar anchorage zone. There is a displacement of 530 mm at the monitoring point in the 6 m deep zone of the pillar. Transfer of the fracture zone is found in a small coal pillar and the fractures within 3–4 m of the coal-rock zone from the roadway surface undergo propagation and closure of cracks which means this fracture zone is transferred from 3–4 m outside the roadway to only 2–3 m from the roadway surface. In the monitoring zone, vertical and horizontal stresses increase with a feature that shows that acceleration in the deep zone of the pillar is greater than that in the shallow zone. Furthermore, the acceleration of vertical stress is also greater than that of horizontal stress with a peak value in the 4 m zone.The research findings provide a reference for the regulation of a reasonable width of coal pillar in coalmines and optimal control design of surrounding rock.
基金Projects(51475332,51275356)supported by the National Natural Science Foundation of China
文摘Hydrostatic slipper was often used in friction bearing design, allowing improvement of the latter's dynamic behavior. The influence of thermal effect on hydrostatic slipper bearing capacity of axial piston pump was investigated. A set of lumped parameter mathematical models were developed based on energy conservation law of slipper/ swash plate pair. The results show that thermal equilibrium clearance due to solid thermal deformation periodically changes with shaft rotational angle. The slipper bearing capacity increases dramatically with decreasing thermal equilibrium clearance. In order to improve the slipper bearing capacity, length-to-diameter ratio of fixed damper varies from 3.5 to 8.75 and radius ratio of slipper varies from 1.5 to 2.0. In addition, the higher slipper thermal conductivity is useful to improve slipper bearing capability, but the thermal equilibrium clearance is not compromised.
基金funded by the United Foundation key project fund,Chinese Natural Science Committee (No.U1261207)Datong Coal Group,Tashan Coal Mine,and supported by the Natural Science Foundation of Ningbo of China (No.U1261207)
文摘Coal seams in Tashan Mine of Datong Coal Group in China average 15 m thick and have been mined by the top coal caving longwall mining method of large mining height. Mining height was 3.8 m and the top coal caving height was 11.2 m. The gateroad pillar between panels was 38 m. During retreat mining,serious bumps occurred in the gateroads on both sides of the pillar affecting safety production. Therefore,pillarless mining was experimented. Using numerical modeling and comparative study of cases of similar mining condition,it was decided to employ a 6 m wide pillar,rather than the previous 38 m wide pillar.Support system for the gateroads was designed and implemented. During gateroad development,pillar failure conditions and entry deformation were monitored. Hydraulic fracturing method was employed to cut off the K3 sandstone along the entry rib so as to reduce the abutment pressure induced during retreat mining. Support reinforcement method combining grouting and advanced reinforcement methods was proposed to insure stable gateroad ahead of mining. Methane drainage and nitrogen injection were implemented to eliminate hazards associated with mine fire and spontaneous combustion. Since the development of gateroad has just completed,and retreat mining has not begun,the effectiveness of the proposed methods is unknown at this point. However,monitoring will continue until after mining.The results will be published in a separate paper.
基金Sponsored by the National Natural Science Foundation of China(Grant No.50538060)the Excellent Young College Teacher Foundation of Anhui Prov-ince(Grant No.2009SQRZ081)
文摘To better study the behavior of confined concrete, this paper presents the basic hypothesis of uhimate equilibrium of confined concrete and the unified yield criteria of confining material. Based on the static equilibrium condition and yield criteria of components, a unified bearing capacity model of confined concrete column is proposed, and a simplified calculating equation of the model is also given. The model captures the character of confined concrete column. Effects of the confinement effect ratio, the lateral confinement ratio, unconfined concrete strength and the properties of confining material on the bearing capacity of confined concrete column are carefully considered. The model may be applicable to the calculation of bearing capacity of steel-confined concrete, concrete filled steel tube and FRP-confined concrete. The predictions of the model agree well with test data.