Polyurea microcapsules containing NiCl2 were prepared by interracial polymerization between diisocyanate and water with triethylamine as a catalyst in water-in-oil emulsion system. The influence of preparation conditi...Polyurea microcapsules containing NiCl2 were prepared by interracial polymerization between diisocyanate and water with triethylamine as a catalyst in water-in-oil emulsion system. The influence of preparation conditions such as the dosage and feed mode of the catalyst, concentration of the encapsulated NiCl2, and concentration and structure of diisocyanates on the breakage of the microcapsules have been evaluated. The results show thatbreakage is strongly dependent on the rate of polymerization and stability of initial emulsion. The improved microcapsules with low breakage have been produced under the optimum conditions. Furthermore, the obtained microcapsules capsules immobilizing NiCl2 as a recyclable catalyst is successfully used in benzaldehyde reduction.展开更多
High-density CdS hollow nanospheres are successfully synthesized by a simple chemical vapor deposition technology.The crystal structure,compositional information,and morphological structure are characterized by X-ray ...High-density CdS hollow nanospheres are successfully synthesized by a simple chemical vapor deposition technology.The crystal structure,compositional information,and morphological structure are characterized by X-ray diffraction(XRD),scanning electronic microscopy(SEM),transmission electronic microscopy(TEM),and energy-dispersive X-ray spectrometer(EDX).The results show that the as-prepared CdS hollow nanospheres have uniform size about 1-3 μm in diameter.The Kirkendall phenomenon is proposed for the formation of the CdS nanostructures.A strong emission located at 580 nm is observed.展开更多
基金Supported by the National Natural Science Foundation of China （No.20576045）, the Opening Foundation of Zhejiang Provincial Top Key Discipline, and the Program for New Century Excellent Talents in University （No.NCET-06-740）.
文摘Polyurea microcapsules containing NiCl2 were prepared by interracial polymerization between diisocyanate and water with triethylamine as a catalyst in water-in-oil emulsion system. The influence of preparation conditions such as the dosage and feed mode of the catalyst, concentration of the encapsulated NiCl2, and concentration and structure of diisocyanates on the breakage of the microcapsules have been evaluated. The results show thatbreakage is strongly dependent on the rate of polymerization and stability of initial emulsion. The improved microcapsules with low breakage have been produced under the optimum conditions. Furthermore, the obtained microcapsules capsules immobilizing NiCl2 as a recyclable catalyst is successfully used in benzaldehyde reduction.
文摘High-density CdS hollow nanospheres are successfully synthesized by a simple chemical vapor deposition technology.The crystal structure,compositional information,and morphological structure are characterized by X-ray diffraction(XRD),scanning electronic microscopy(SEM),transmission electronic microscopy(TEM),and energy-dispersive X-ray spectrometer(EDX).The results show that the as-prepared CdS hollow nanospheres have uniform size about 1-3 μm in diameter.The Kirkendall phenomenon is proposed for the formation of the CdS nanostructures.A strong emission located at 580 nm is observed.
