Hexagonal boron nitride(h-BN)ceramics have become exceptional materials for heat-resistant components in hypersonic vehicles,owing to their superior thermal stability and excellent dielectric properties.However,their ...Hexagonal boron nitride(h-BN)ceramics have become exceptional materials for heat-resistant components in hypersonic vehicles,owing to their superior thermal stability and excellent dielectric properties.However,their densification during sintering still poses challenges for researchers,and their mechanical properties are rather unsatisfactory.In this study,SrAl_(2)Si_(2)O_(8)(SAS),with low melting point and high strength,was introduced into the h-BN ceramics to facilitate the sintering and reinforce the strength and toughness.Then,BN-SAS ceramic composites were fabricated via hot press sintering using h-BN,SrCO_(3),Al_(2)O_(3),and SiO_(2) as raw materials,and effects of sintering pressure on their microstructure,mechanical property,and thermal property were investigated.The thermal shock resistance of BN-SAS ceramic composites was evaluated.Results show that phases of as-preparedBN-SAS ceramic composites are h-BN and h-SrAl_(2)Si_(2)O_(8).With the increase of sintering pressure,the composites’densities increase,and the mechanical properties shew a rising trend followed by a slight decline.At a sintering pressure of 20 MPa,their bending strength and fracture toughness are(138±4)MPa and(1.84±0.05)MPa·m^(1/2),respectively.Composites sintered at 10 MPa exhibit a low coefficient of thermal expansion,with an average of 2.96×10^(-6) K^(-1) in the temperature range from 200 to 1200℃.The BN-SAS ceramic composites prepared at 20 MPa display higher thermal conductivity from 12.42 to 28.42 W·m^(-1)·K^(-1) within the temperature range from room temperature to 1000℃.Notably,BN-SAS composites exhibit remarkable thermal shock resistance,with residual bending strength peaking and subsequently declining sharply under a thermal shock temperature difference ranging from 600 to 1400℃.The maximum residual bending strength is recorded at a temperature difference of 800℃,with a residual strength retention rate of 101%.As the thermal shock temperature difference increase,the degree of oxidation on the ceramic surface and cracks due to thermal stress are also increased gradually.展开更多
The evolution of mechanical properties,localized corrosion resistance of a high purity Al-Zn-Mg-Cu alloy during non-isothermal aging(NIA)was investigated by hardness test,electrical conductivity test,tensile test,inte...The evolution of mechanical properties,localized corrosion resistance of a high purity Al-Zn-Mg-Cu alloy during non-isothermal aging(NIA)was investigated by hardness test,electrical conductivity test,tensile test,intergranular corrosion test,exfoliation corrosion test,slow strain rate tensile test and electrochemical test,and the mechanism has been discussed based on microstructure examination by optical microscopy,electron back scattered diffraction,scanning electron microscopy and scanning transmission electron microscopy.The NIA treatment includes a heating stage from 40℃to 180℃with a rate of 20℃/h and a cooling stage from 180℃to 40℃with a rate of 10℃/h.The results show that the hardness and strength increase rapidly during the heating stage of NIA since the increasing temperature favors the nucleation and the growth of strengthening precipitates and promotes the transformation of Guinier-Preston(GPI)zones toη'phase.During the cooling stage,the sizes ofη'phase increase with a little change in the number density,leading to a further slight increase of the hardness and strength.As NIA proceeds,the corroded morphology in the alloy changes from a layering feature to a wavy feature,the maximum corrosion depth decreases,and the reason has been analyzed based on the microstructural and microchemical feature of precipitates at grain boundaries and subgrain boundaries.展开更多
Microstructure, mechanical property and oxidation resistance of MCrAlYX coatings prepared by detonation gun (D-gun) and HVOF spraying were investigated. Lamellar microstructure and uniform microstructure formed in D-g...Microstructure, mechanical property and oxidation resistance of MCrAlYX coatings prepared by detonation gun (D-gun) and HVOF spraying were investigated. Lamellar microstructure and uniform microstructure formed in D-gun sprayed MCrAlYX coating and HVOF sprayed coating, respectively. Element redistribution and formation of new phase took place during the detonation process. Besides, the porosity of D-gun sprayed coating was much lower than that of HVOF sprayed coating. On the mechanical property, the micro-hardnesses of the two coatings were in the same level (~HV 910). However, D-gun sprayed MCrAlYX coating exhibited larger standard deviation of microhardness due to its lamellar microstructure, and exhibited better bend bonding strength owing to the existence of residual compressive stress between the layers and particles. Meanwhile, due to the much more compact microstructure, D-gun sprayed MCrAlYX coating showed superior oxidation resistance to the HVOF sprayed coating. The continuous dense protective layer can form earlier in D-gun sprayed coating and thus suppress further oxidation and control the oxide thickness at a relatively low level.展开更多
TiC particle reinforced 420 stainless steel matrix composites were fabricated, and the microstructure, tensile properties and wear resistance of the composites were studied. The experimental results indicate that the ...TiC particle reinforced 420 stainless steel matrix composites were fabricated, and the microstructure, tensile properties and wear resistance of the composites were studied. The experimental results indicate that the distribution of TiC particles with size of 5 to 10 μm in diameter is uniform if the volume fraction of TiC is lower than 6%. However, slight agglomeration can be observed when the TiC content exceeds 6%. With the increase of TiC content the tensile and yield strength of the composites prepared increases and reaches the maximum when the volume fraction of TiC increases to 5%. Further increase of TiC content causes reductions of yield and tensile strength. The ductility of the composites shows a monotone decrease with the increase of TiC addition. The introduction of TiC into 420 stainless steel results in significant improvement on wear resistance, which reaches a steady level when the volume fraction of TiC increases to 11% and does not show obvious variation if the TiC content is further increased.展开更多
The effects of T916 thermo-mechanical process on microstructures, mechanical properties and ballistic resistance of 2519A aluminum alloy were investigated by optical microscopy (OM), transmission electron microscopy...The effects of T916 thermo-mechanical process on microstructures, mechanical properties and ballistic resistance of 2519A aluminum alloy were investigated by optical microscopy (OM), transmission electron microscopy (TEM), tensile tests and ballistic resistance test. After T916 treatment, the yield strength, tensile strength and elongation rate of 2519A aluminum alloy reach 501 MPa, 540 MPa and 14%, respectively. And the ballistic limit velocity of 2519A-T916 alloy (30 mm in thickness) is 715 rn/s. The microstructure varies near the sidewalls of crater. The interrupted ageing contributes to these excellent properties of the alloy. During T916 process, the precipitation of Guinier Preston (GP) zone is finer and denser during the interrupted ageing, thus resulting in well precipitated strengthening phase.展开更多
The seismic behavior of planar frames with concrete-filled T-section columns to steel beam was experimentally and numerically studied. A finite element analysis (FEA) model was developed to investigate the engineeri...The seismic behavior of planar frames with concrete-filled T-section columns to steel beam was experimentally and numerically studied. A finite element analysis (FEA) model was developed to investigate the engineering properties of the planar frames. Two 1:2.5 reduced-scale specimens of T-section concrete-filled steel tubular column and steel beam of single-story and single-bay plane frames were designed and fabricated based on the design principles of strong-column, weak-beam and stronger-joint. One three-dimensional entity model of the investigated frame structure was built using a large-scale nonlinear finite-element analysis software ABAQUS. Experimental results show that the axial compression ratio has no effect on the failure mode of the structure, while with the increase of axial compression ratio and the dissipated energy ability increasing, the structural ductility decreased. The results from both experiments and simulations agree with each other, which verifies the validity and accuracy of the developed finite element model. Furthermore, the developed finite element model helps to reflect the detailed stress status of the investigated frame at different time and different positions.展开更多
This research develops a new mathematical modeling method by combining industrial big data and process mechanism analysis under the framework of generalized additive models(GAM)to generate a practical model with gener...This research develops a new mathematical modeling method by combining industrial big data and process mechanism analysis under the framework of generalized additive models(GAM)to generate a practical model with generalization and precision.Specifically,the proposed modeling method includes the following steps.Firstly,the influence factors are screened using mechanism knowledge and data-mining methods.Secondly,the unary GAM without interactions including cleaning the data,building the sub-models,and verifying the sub-models.Subsequently,the interactions between the various factors are explored,and the binary GAM with interactions is constructed.The relationships among the sub-models are analyzed,and the integrated model is built.Finally,based on the proposed modeling method,two prediction models of mechanical property and deformation resistance for hot-rolled strips are established.Industrial actual data verification demonstrates that the new models have good prediction precision,and the mean absolute percentage errors of tensile strength,yield strength and deformation resistance are 2.54%,3.34%and 6.53%,respectively.And experimental results suggest that the proposed method offers a new approach to industrial process modeling.展开更多
To find suitable biodegradable materials for implant applications,Mg−6Zn−0.3Mn−xCa(x=0,0.2 and 0.5,wt.%)alloys were prepared by semi-continuous casting followed by hot-extrusion technique.The microstructure and mechan...To find suitable biodegradable materials for implant applications,Mg−6Zn−0.3Mn−xCa(x=0,0.2 and 0.5,wt.%)alloys were prepared by semi-continuous casting followed by hot-extrusion technique.The microstructure and mechanical properties of Mg−6Zn−0.3Mn−xCa alloys were investigated using the optical microscope,scanning electron microscope and tensile testing.Results indicated that minor Ca addition can slightly refine grains of the extruded Mg−6Zn−0.3Mn alloy and improve its strength.When 0.2 wt.%and 0.5 wt.%Ca were added,the grain sizes of the as-extruded alloys were refined from 4.8 to 4.6 and 4.2μm,respectively.Of the three alloys studied,the alloy with 0.5 wt.%Ca exhibits better combined mechanical properties with the ultimate tensile strength and elongation of 334 MPa and 20.3%.The corrosion behaviour,cell viability and antibacterial activities of alloys studied were also evaluated.Increasing Ca content deteriorates the corrosion resistance of alloys due to the increase of amount of effective cathodic sites caused by the formation of more Ca2Mg6Zn3 phases.Cytotoxicity evaluation with L929 cells shows higher cell viability of the Mg−6Zn−0.3Mn−0.5Ca alloy compared to Mg−6Zn−0.3Mn and Mg−6Zn−0.3Mn−0.2Ca alloys.The antibacterial activity against Staphylococcus aureus is enhanced with increasing the Ca content due to its physicochemical and biological performance in bone repairing process.展开更多
3D carbon fiber needled felt and polycarbosilane-derived SiC coating were selected as reinforcement and interfacial coating,respectively,and the sol-impregnation-drying-heating(SIDH)route was used to fabricate C/Al2O3...3D carbon fiber needled felt and polycarbosilane-derived SiC coating were selected as reinforcement and interfacial coating,respectively,and the sol-impregnation-drying-heating(SIDH)route was used to fabricate C/Al2O3 composites.The effects of Si C interfacial coating on the mechanical properties,oxidation resistance and thermal shock resistance of C/Al2O3 composites were investigated.It is found that the fracture toughness of C/Al2O3 composites was remarkably superior to that of monolithic Al2O3 ceramics.The introduction of SiC interfacial coating obviously improved the strengths of C/Al2O3 composites although the fracture work diminished to some extent.Owing to the tight bonding between SiC coating and carbon fiber,the C/SiC/Al2O3 composites showed much better oxidation and thermal shock resistance over C/Al2O3 composites under static air.展开更多
Massive vanadium additions as hard phases in powder metallurgy high-speed steels(PM HSS)lead to higher cost and bad machinability.In this study,ultrahigh alloy PM HSS with CPM121(10W-5Mo-4Cr-10V-9Co,wt.%)as the basic ...Massive vanadium additions as hard phases in powder metallurgy high-speed steels(PM HSS)lead to higher cost and bad machinability.In this study,ultrahigh alloy PM HSS with CPM121(10W-5Mo-4Cr-10V-9Co,wt.%)as the basic composition,was directly compacted and activation sintered with near-full density(>99.0%)using pre-oxidized and ball-mixed element and carbide powders.Niobium-alloyed steels(w(V)+w(Nb)=10 wt.%)show higher hardness and wear resistance,superior secondary-hardening ability and temper resistance.But excess niobium addition(>5 wt.%)leads to coarsened carbides and deteriorated toughness.EPMA results proved that niobium tends to distribute in MC carbides and forces element W to form M6C and WC carbides.Further,the role of rotary forging on properties of niobium-alloyed steels(S3)was researched.After rotary forging with deformation of 40%,the bending strength and fracture toughness of niobium-alloyed steels could be further improved by 20.74%and 43.86%compared with those of sample S3 without rotary forging,respectively.展开更多
The effect of T6I6 treatment on the dynamic mechanical and microstructure behaviour of Al-Si-Mg-Cu cast alloy was investigated using split Hopkinson pressure bar(SHPB), transmission electron microscopy(TEM), and highr...The effect of T6I6 treatment on the dynamic mechanical and microstructure behaviour of Al-Si-Mg-Cu cast alloy was investigated using split Hopkinson pressure bar(SHPB), transmission electron microscopy(TEM), and highresolution transmission electron microscopy(HRTEM). Besides, the impact resistances of T6I6 and T6 motor shells of new energy vehicles made of Al-Si-Mg-Cu cast alloy were compared using a trolley crash test. The results indicated that the main strengthening-phases of the T6 peak-aged and T6I6 peak-aged alloy were GP zone and β″ precipitates. T6I6treatment can increase the density and size of β″ precipitates in peak-aged alloy and enhance both its tensile strength(σb)and elongation(δ). The dynamic toughness values of T6I6 samples are 50.34 MJ/m^(3) at 2000 s^(-1) and 177.34 MJ/m^(3) at 5000 s^(-1) which are 20% and 12% higher than those of T6 samples, respectively. Compared with a T6 shell, the overall deformation of T6I6 shell is more uniform during the crash test. At an impact momentum of 3.5×10;kg·m/s, the T6I6shell breaks down at 0.38 s which is 0.10 s later than the T6 shell.展开更多
To prepare the three-dimensional braided carbon fiber reinforced mullite (3D C/mullite) composites, an Al2O3-SiO2 solwith a solid content of 20% (mass fraction) and an Al2O3/SiO2 mass ratio of 2:1 was selected as...To prepare the three-dimensional braided carbon fiber reinforced mullite (3D C/mullite) composites, an Al2O3-SiO2 solwith a solid content of 20% (mass fraction) and an Al2O3/SiO2 mass ratio of 2:1 was selected as the raw material. Characteristics andmullitization of the sol were analyzed throughly. It is found that the formation of mullite is basically completed at 1300℃ and thegel powders exhibit favorable sintering shrinkage. The 3D C/mullite composites without interfacial coating were fabricated throughthe route of vacuum impregnation-drying-heat treatment. Satisfied mechanical properties with a flexural strength of 241.2 MPa anda fracture toughness of 10.9 MPa·m1/2are obtained although the total porosity reaches 26.0%. Oxidation resistances of the compositesat 1200, 1400 and 1600 ℃ were investigated. Due to the further densification of matrix, the 3D C/mullite composites show tiny massloss and their mechanical properties are well retained after oxidation at 1600 ℃ for 30 min.展开更多
In this paper, nanotechnology for the improvement of dental composite resins has been reviewed in the background of the existing shortcomings, focusing on the improvement for polymerization shrinkage, anti-bacterial p...In this paper, nanotechnology for the improvement of dental composite resins has been reviewed in the background of the existing shortcomings, focusing on the improvement for polymerization shrinkage, anti-bacterial properties and mechanical properties of composite resins. The results show that the use of nanotechnology and nano materials can be an effective method to improve the performance of dental composite resins in a various ways. At last, the paper also discusses the perspective about the dental composite resins.展开更多
基金National Natural Science Foundation of China (52072088, 52072089)Natural Science Foundation of Heilongjiang Province (LH2023E061)+1 种基金Scientific and Technological Innovation Leading Talent of Harbin Manufacturing (2022CXRCCG001)Fundamental Research Funds for the Central Universities (3072023CFJ1003)。
文摘Hexagonal boron nitride(h-BN)ceramics have become exceptional materials for heat-resistant components in hypersonic vehicles,owing to their superior thermal stability and excellent dielectric properties.However,their densification during sintering still poses challenges for researchers,and their mechanical properties are rather unsatisfactory.In this study,SrAl_(2)Si_(2)O_(8)(SAS),with low melting point and high strength,was introduced into the h-BN ceramics to facilitate the sintering and reinforce the strength and toughness.Then,BN-SAS ceramic composites were fabricated via hot press sintering using h-BN,SrCO_(3),Al_(2)O_(3),and SiO_(2) as raw materials,and effects of sintering pressure on their microstructure,mechanical property,and thermal property were investigated.The thermal shock resistance of BN-SAS ceramic composites was evaluated.Results show that phases of as-preparedBN-SAS ceramic composites are h-BN and h-SrAl_(2)Si_(2)O_(8).With the increase of sintering pressure,the composites’densities increase,and the mechanical properties shew a rising trend followed by a slight decline.At a sintering pressure of 20 MPa,their bending strength and fracture toughness are(138±4)MPa and(1.84±0.05)MPa·m^(1/2),respectively.Composites sintered at 10 MPa exhibit a low coefficient of thermal expansion,with an average of 2.96×10^(-6) K^(-1) in the temperature range from 200 to 1200℃.The BN-SAS ceramic composites prepared at 20 MPa display higher thermal conductivity from 12.42 to 28.42 W·m^(-1)·K^(-1) within the temperature range from room temperature to 1000℃.Notably,BN-SAS composites exhibit remarkable thermal shock resistance,with residual bending strength peaking and subsequently declining sharply under a thermal shock temperature difference ranging from 600 to 1400℃.The maximum residual bending strength is recorded at a temperature difference of 800℃,with a residual strength retention rate of 101%.As the thermal shock temperature difference increase,the degree of oxidation on the ceramic surface and cracks due to thermal stress are also increased gradually.
基金Project(202302AB080024)supported by the Department of Science and Technology of Yunnan Province,China。
文摘The evolution of mechanical properties,localized corrosion resistance of a high purity Al-Zn-Mg-Cu alloy during non-isothermal aging(NIA)was investigated by hardness test,electrical conductivity test,tensile test,intergranular corrosion test,exfoliation corrosion test,slow strain rate tensile test and electrochemical test,and the mechanism has been discussed based on microstructure examination by optical microscopy,electron back scattered diffraction,scanning electron microscopy and scanning transmission electron microscopy.The NIA treatment includes a heating stage from 40℃to 180℃with a rate of 20℃/h and a cooling stage from 180℃to 40℃with a rate of 10℃/h.The results show that the hardness and strength increase rapidly during the heating stage of NIA since the increasing temperature favors the nucleation and the growth of strengthening precipitates and promotes the transformation of Guinier-Preston(GPI)zones toη'phase.During the cooling stage,the sizes ofη'phase increase with a little change in the number density,leading to a further slight increase of the hardness and strength.As NIA proceeds,the corroded morphology in the alloy changes from a layering feature to a wavy feature,the maximum corrosion depth decreases,and the reason has been analyzed based on the microstructural and microchemical feature of precipitates at grain boundaries and subgrain boundaries.
基金Project(51201156)supported by the National Natural Science Foundation of China
文摘Microstructure, mechanical property and oxidation resistance of MCrAlYX coatings prepared by detonation gun (D-gun) and HVOF spraying were investigated. Lamellar microstructure and uniform microstructure formed in D-gun sprayed MCrAlYX coating and HVOF sprayed coating, respectively. Element redistribution and formation of new phase took place during the detonation process. Besides, the porosity of D-gun sprayed coating was much lower than that of HVOF sprayed coating. On the mechanical property, the micro-hardnesses of the two coatings were in the same level (~HV 910). However, D-gun sprayed MCrAlYX coating exhibited larger standard deviation of microhardness due to its lamellar microstructure, and exhibited better bend bonding strength owing to the existence of residual compressive stress between the layers and particles. Meanwhile, due to the much more compact microstructure, D-gun sprayed MCrAlYX coating showed superior oxidation resistance to the HVOF sprayed coating. The continuous dense protective layer can form earlier in D-gun sprayed coating and thus suppress further oxidation and control the oxide thickness at a relatively low level.
文摘TiC particle reinforced 420 stainless steel matrix composites were fabricated, and the microstructure, tensile properties and wear resistance of the composites were studied. The experimental results indicate that the distribution of TiC particles with size of 5 to 10 μm in diameter is uniform if the volume fraction of TiC is lower than 6%. However, slight agglomeration can be observed when the TiC content exceeds 6%. With the increase of TiC content the tensile and yield strength of the composites prepared increases and reaches the maximum when the volume fraction of TiC increases to 5%. Further increase of TiC content causes reductions of yield and tensile strength. The ductility of the composites shows a monotone decrease with the increase of TiC addition. The introduction of TiC into 420 stainless steel results in significant improvement on wear resistance, which reaches a steady level when the volume fraction of TiC increases to 11% and does not show obvious variation if the TiC content is further increased.
基金Project(2012CB619501)supported by the National Basic Research Program of China
文摘The effects of T916 thermo-mechanical process on microstructures, mechanical properties and ballistic resistance of 2519A aluminum alloy were investigated by optical microscopy (OM), transmission electron microscopy (TEM), tensile tests and ballistic resistance test. After T916 treatment, the yield strength, tensile strength and elongation rate of 2519A aluminum alloy reach 501 MPa, 540 MPa and 14%, respectively. And the ballistic limit velocity of 2519A-T916 alloy (30 mm in thickness) is 715 rn/s. The microstructure varies near the sidewalls of crater. The interrupted ageing contributes to these excellent properties of the alloy. During T916 process, the precipitation of Guinier Preston (GP) zone is finer and denser during the interrupted ageing, thus resulting in well precipitated strengthening phase.
基金Projects(51378077,51478047,51778066)supported by the National Natural Science Foundation of ChinaProject(D20151304)supported by Science and Technology Research Project of Education Department of Hubei Province,ChinaProject(2017CFA070)supported by Hubei Provincial Natural Science Foundation,China
文摘The seismic behavior of planar frames with concrete-filled T-section columns to steel beam was experimentally and numerically studied. A finite element analysis (FEA) model was developed to investigate the engineering properties of the planar frames. Two 1:2.5 reduced-scale specimens of T-section concrete-filled steel tubular column and steel beam of single-story and single-bay plane frames were designed and fabricated based on the design principles of strong-column, weak-beam and stronger-joint. One three-dimensional entity model of the investigated frame structure was built using a large-scale nonlinear finite-element analysis software ABAQUS. Experimental results show that the axial compression ratio has no effect on the failure mode of the structure, while with the increase of axial compression ratio and the dissipated energy ability increasing, the structural ductility decreased. The results from both experiments and simulations agree with each other, which verifies the validity and accuracy of the developed finite element model. Furthermore, the developed finite element model helps to reflect the detailed stress status of the investigated frame at different time and different positions.
基金Project(51774219)supported by the National Natural Science Foundation of China
文摘This research develops a new mathematical modeling method by combining industrial big data and process mechanism analysis under the framework of generalized additive models(GAM)to generate a practical model with generalization and precision.Specifically,the proposed modeling method includes the following steps.Firstly,the influence factors are screened using mechanism knowledge and data-mining methods.Secondly,the unary GAM without interactions including cleaning the data,building the sub-models,and verifying the sub-models.Subsequently,the interactions between the various factors are explored,and the binary GAM with interactions is constructed.The relationships among the sub-models are analyzed,and the integrated model is built.Finally,based on the proposed modeling method,two prediction models of mechanical property and deformation resistance for hot-rolled strips are established.Industrial actual data verification demonstrates that the new models have good prediction precision,and the mean absolute percentage errors of tensile strength,yield strength and deformation resistance are 2.54%,3.34%and 6.53%,respectively.And experimental results suggest that the proposed method offers a new approach to industrial process modeling.
基金the financial supports from the Natural Science Foundation of Shanxi Province, China (201901D211310)the National Natural Science Foundation of China (52071227)+2 种基金the Transformation of Scientific and Technological Achievements Programs of Higher Education Institutions in Shanxi, China (TSTAP)Science and Technology Major Projects of Shanxi Province, China (20191102004, 201903D111008)the Central Special Funds Guiding the Development of Local Science and Technology, China (YDZX20181400002967)
文摘To find suitable biodegradable materials for implant applications,Mg−6Zn−0.3Mn−xCa(x=0,0.2 and 0.5,wt.%)alloys were prepared by semi-continuous casting followed by hot-extrusion technique.The microstructure and mechanical properties of Mg−6Zn−0.3Mn−xCa alloys were investigated using the optical microscope,scanning electron microscope and tensile testing.Results indicated that minor Ca addition can slightly refine grains of the extruded Mg−6Zn−0.3Mn alloy and improve its strength.When 0.2 wt.%and 0.5 wt.%Ca were added,the grain sizes of the as-extruded alloys were refined from 4.8 to 4.6 and 4.2μm,respectively.Of the three alloys studied,the alloy with 0.5 wt.%Ca exhibits better combined mechanical properties with the ultimate tensile strength and elongation of 334 MPa and 20.3%.The corrosion behaviour,cell viability and antibacterial activities of alloys studied were also evaluated.Increasing Ca content deteriorates the corrosion resistance of alloys due to the increase of amount of effective cathodic sites caused by the formation of more Ca2Mg6Zn3 phases.Cytotoxicity evaluation with L929 cells shows higher cell viability of the Mg−6Zn−0.3Mn−0.5Ca alloy compared to Mg−6Zn−0.3Mn and Mg−6Zn−0.3Mn−0.2Ca alloys.The antibacterial activity against Staphylococcus aureus is enhanced with increasing the Ca content due to its physicochemical and biological performance in bone repairing process.
文摘3D carbon fiber needled felt and polycarbosilane-derived SiC coating were selected as reinforcement and interfacial coating,respectively,and the sol-impregnation-drying-heating(SIDH)route was used to fabricate C/Al2O3 composites.The effects of Si C interfacial coating on the mechanical properties,oxidation resistance and thermal shock resistance of C/Al2O3 composites were investigated.It is found that the fracture toughness of C/Al2O3 composites was remarkably superior to that of monolithic Al2O3 ceramics.The introduction of SiC interfacial coating obviously improved the strengths of C/Al2O3 composites although the fracture work diminished to some extent.Owing to the tight bonding between SiC coating and carbon fiber,the C/SiC/Al2O3 composites showed much better oxidation and thermal shock resistance over C/Al2O3 composites under static air.
基金Projects(51771237,51704257)supported by the National Natural Science Foundation of ChinaProject(2019JJ60019)supported by the Joint Fund of Hunan Province,ChinaProject(17QDZ25)supported by the School Level Fund of Xiangtan University,China。
文摘Massive vanadium additions as hard phases in powder metallurgy high-speed steels(PM HSS)lead to higher cost and bad machinability.In this study,ultrahigh alloy PM HSS with CPM121(10W-5Mo-4Cr-10V-9Co,wt.%)as the basic composition,was directly compacted and activation sintered with near-full density(>99.0%)using pre-oxidized and ball-mixed element and carbide powders.Niobium-alloyed steels(w(V)+w(Nb)=10 wt.%)show higher hardness and wear resistance,superior secondary-hardening ability and temper resistance.But excess niobium addition(>5 wt.%)leads to coarsened carbides and deteriorated toughness.EPMA results proved that niobium tends to distribute in MC carbides and forces element W to form M6C and WC carbides.Further,the role of rotary forging on properties of niobium-alloyed steels(S3)was researched.After rotary forging with deformation of 40%,the bending strength and fracture toughness of niobium-alloyed steels could be further improved by 20.74%and 43.86%compared with those of sample S3 without rotary forging,respectively.
基金Projects(52075166, 51875197) supported by the National Natural Science Foundation of ChinaProjects(2019RS2064,2019GK5043) supported by the Science and Technology Planning Project of Hunan Province,China。
文摘The effect of T6I6 treatment on the dynamic mechanical and microstructure behaviour of Al-Si-Mg-Cu cast alloy was investigated using split Hopkinson pressure bar(SHPB), transmission electron microscopy(TEM), and highresolution transmission electron microscopy(HRTEM). Besides, the impact resistances of T6I6 and T6 motor shells of new energy vehicles made of Al-Si-Mg-Cu cast alloy were compared using a trolley crash test. The results indicated that the main strengthening-phases of the T6 peak-aged and T6I6 peak-aged alloy were GP zone and β″ precipitates. T6I6treatment can increase the density and size of β″ precipitates in peak-aged alloy and enhance both its tensile strength(σb)and elongation(δ). The dynamic toughness values of T6I6 samples are 50.34 MJ/m^(3) at 2000 s^(-1) and 177.34 MJ/m^(3) at 5000 s^(-1) which are 20% and 12% higher than those of T6 samples, respectively. Compared with a T6 shell, the overall deformation of T6I6 shell is more uniform during the crash test. At an impact momentum of 3.5×10;kg·m/s, the T6I6shell breaks down at 0.38 s which is 0.10 s later than the T6 shell.
基金Project(SAST2015043)supported by the Science Innovation Foundation of Shanghai Academy of Spaceflight Technology,ChinaProject(614291102010117)supported by the Open Foundation of Science and Technology on Thermostructural Composite Materials Laboratory,ChinaProject(11572277)supported by the National Natural Science Foundation of China
文摘To prepare the three-dimensional braided carbon fiber reinforced mullite (3D C/mullite) composites, an Al2O3-SiO2 solwith a solid content of 20% (mass fraction) and an Al2O3/SiO2 mass ratio of 2:1 was selected as the raw material. Characteristics andmullitization of the sol were analyzed throughly. It is found that the formation of mullite is basically completed at 1300℃ and thegel powders exhibit favorable sintering shrinkage. The 3D C/mullite composites without interfacial coating were fabricated throughthe route of vacuum impregnation-drying-heat treatment. Satisfied mechanical properties with a flexural strength of 241.2 MPa anda fracture toughness of 10.9 MPa·m1/2are obtained although the total porosity reaches 26.0%. Oxidation resistances of the compositesat 1200, 1400 and 1600 ℃ were investigated. Due to the further densification of matrix, the 3D C/mullite composites show tiny massloss and their mechanical properties are well retained after oxidation at 1600 ℃ for 30 min.
文摘In this paper, nanotechnology for the improvement of dental composite resins has been reviewed in the background of the existing shortcomings, focusing on the improvement for polymerization shrinkage, anti-bacterial properties and mechanical properties of composite resins. The results show that the use of nanotechnology and nano materials can be an effective method to improve the performance of dental composite resins in a various ways. At last, the paper also discusses the perspective about the dental composite resins.