Hexagonal boron nitride(h-BN)ceramics have become exceptional materials for heat-resistant components in hypersonic vehicles,owing to their superior thermal stability and excellent dielectric properties.However,their ...Hexagonal boron nitride(h-BN)ceramics have become exceptional materials for heat-resistant components in hypersonic vehicles,owing to their superior thermal stability and excellent dielectric properties.However,their densification during sintering still poses challenges for researchers,and their mechanical properties are rather unsatisfactory.In this study,SrAl_(2)Si_(2)O_(8)(SAS),with low melting point and high strength,was introduced into the h-BN ceramics to facilitate the sintering and reinforce the strength and toughness.Then,BN-SAS ceramic composites were fabricated via hot press sintering using h-BN,SrCO_(3),Al_(2)O_(3),and SiO_(2) as raw materials,and effects of sintering pressure on their microstructure,mechanical property,and thermal property were investigated.The thermal shock resistance of BN-SAS ceramic composites was evaluated.Results show that phases of as-preparedBN-SAS ceramic composites are h-BN and h-SrAl_(2)Si_(2)O_(8).With the increase of sintering pressure,the composites’densities increase,and the mechanical properties shew a rising trend followed by a slight decline.At a sintering pressure of 20 MPa,their bending strength and fracture toughness are(138±4)MPa and(1.84±0.05)MPa·m^(1/2),respectively.Composites sintered at 10 MPa exhibit a low coefficient of thermal expansion,with an average of 2.96×10^(-6) K^(-1) in the temperature range from 200 to 1200℃.The BN-SAS ceramic composites prepared at 20 MPa display higher thermal conductivity from 12.42 to 28.42 W·m^(-1)·K^(-1) within the temperature range from room temperature to 1000℃.Notably,BN-SAS composites exhibit remarkable thermal shock resistance,with residual bending strength peaking and subsequently declining sharply under a thermal shock temperature difference ranging from 600 to 1400℃.The maximum residual bending strength is recorded at a temperature difference of 800℃,with a residual strength retention rate of 101%.As the thermal shock temperature difference increase,the degree of oxidation on the ceramic surface and cracks due to thermal stress are also increased gradually.展开更多
The evolution of mechanical properties,localized corrosion resistance of a high purity Al-Zn-Mg-Cu alloy during non-isothermal aging(NIA)was investigated by hardness test,electrical conductivity test,tensile test,inte...The evolution of mechanical properties,localized corrosion resistance of a high purity Al-Zn-Mg-Cu alloy during non-isothermal aging(NIA)was investigated by hardness test,electrical conductivity test,tensile test,intergranular corrosion test,exfoliation corrosion test,slow strain rate tensile test and electrochemical test,and the mechanism has been discussed based on microstructure examination by optical microscopy,electron back scattered diffraction,scanning electron microscopy and scanning transmission electron microscopy.The NIA treatment includes a heating stage from 40℃to 180℃with a rate of 20℃/h and a cooling stage from 180℃to 40℃with a rate of 10℃/h.The results show that the hardness and strength increase rapidly during the heating stage of NIA since the increasing temperature favors the nucleation and the growth of strengthening precipitates and promotes the transformation of Guinier-Preston(GPI)zones toη'phase.During the cooling stage,the sizes ofη'phase increase with a little change in the number density,leading to a further slight increase of the hardness and strength.As NIA proceeds,the corroded morphology in the alloy changes from a layering feature to a wavy feature,the maximum corrosion depth decreases,and the reason has been analyzed based on the microstructural and microchemical feature of precipitates at grain boundaries and subgrain boundaries.展开更多
[Objective]The aim was to study the effects of sunflower artificial aging on seed vigor and physiological characteristics.[Method] The varieties of seed germination capacity,vigor of germination,germination index,vigo...[Objective]The aim was to study the effects of sunflower artificial aging on seed vigor and physiological characteristics.[Method] The varieties of seed germination capacity,vigor of germination,germination index,vigor index,peroxidase(POD) activity,superoxide dismutase(SOD) activity and malondialdehyde(MDA) content for four sunflower germplasms such as'SunM20','Deep Purple Minle','Da San Kui Hua 4'and'Ji Kui 24'were studied under high temperature and high humidity conditions(100% RH,45 ℃) for different days(0 d,2 d,4 d,6 d,8 d,10 d).[Result]The result showed that the germination capacity,vigor of germination,germination index,vigor index,POD activity,SOD activity declined gradually with the increase of seed aging days,whereas MDA content enhanced by degrees;The diggerences of resistance to artifical aging existed among the four accessions,'SunM20'was the most resistant one,and exhibited the strongest seed vigor,highest activities of two protective enzyme(POD,SOD) and lowest content of MDA at the uniform condition,moreover,the seed vigor and protective enzyme activities of'SunM20'changed slowest among the four materials during the aging process.[Conclusion]The distinct reduction of POD,SOD activities maybe the main reasons for the decrease of sunflower seed vigor at the artificial aging,and the gradual accumulation of a few MDA accelerated seeds aging.展开更多
For a deeper understanding of the shear resistance performance of the steel-concrete-steel composite shear wall, the main influence factors such as the thicknesses of the steel plates and the concrete, the strength gr...For a deeper understanding of the shear resistance performance of the steel-concrete-steel composite shear wall, the main influence factors such as the thicknesses of the steel plates and the concrete, the strength grades of the concrete and the span-depth ratios of the composite wall, which have impacts on the shear resistance performance of the composite shear wail, are analyzed by the numerical simulation method. Meanwhile, the simplified calculation formulae of the initial elastic lateral-resisting stiffness and the shear bearing capacity of the composite shear wall are also proposed. The research shows that with the increase in the thicknesses of the steel plates and the concrete and the increase in the strength grades of the concrete, the shear performance of the shear wall improves obviously; the span-depth ratios of the composite wall have a significant effect on the initial elastic lateral- resisting stiffness, but a small effect on the shear bearing capacity. Comparing the results of the simplified calculation formulae with those of the nonlinear finite element method, it is obvious that the presented formulae are reasonable and meet the real force state of the structure. These conclusions can serve as a preliminary design reference for the steel-concrete- steel composite shear wall.展开更多
To investigate the feasibility and seismic performance of the horizontal joints in an innovative precast shear wall system, two test walls were fabricated, and the monotonic and cyclic loading tests were performed on ...To investigate the feasibility and seismic performance of the horizontal joints in an innovative precast shear wall system, two test walls were fabricated, and the monotonic and cyclic loading tests were performed on the two test walls, respectively. Then, the lateral load-top displacement curves, load beating capacity, ductility, lateral stiffness, strains of steel bars, strain distribution on the connecting steel frame (CSF), and relative slippages between the CSF and embedded limbic steel frame (ELSF) were discussed in detail. The test results show that the load bearing capacity and ductility of the test wall are both favorable with a displacement ductility factor of more than 3.7. The normal and shear stresses in the CSF except for the compression end are far smaller than the yield stresses throughout the test procedure. Certain slippages of about 1.13 mm occurs between the CSF and ELSF on the compression side of the test wall, while almost no slippages occurs on the tension side. The seismic performance of the test wall is favorable and the new-type scheme of the horizontal joints is both feasible and reliable.展开更多
Microstructure, mechanical property and oxidation resistance of MCrAlYX coatings prepared by detonation gun (D-gun) and HVOF spraying were investigated. Lamellar microstructure and uniform microstructure formed in D-g...Microstructure, mechanical property and oxidation resistance of MCrAlYX coatings prepared by detonation gun (D-gun) and HVOF spraying were investigated. Lamellar microstructure and uniform microstructure formed in D-gun sprayed MCrAlYX coating and HVOF sprayed coating, respectively. Element redistribution and formation of new phase took place during the detonation process. Besides, the porosity of D-gun sprayed coating was much lower than that of HVOF sprayed coating. On the mechanical property, the micro-hardnesses of the two coatings were in the same level (~HV 910). However, D-gun sprayed MCrAlYX coating exhibited larger standard deviation of microhardness due to its lamellar microstructure, and exhibited better bend bonding strength owing to the existence of residual compressive stress between the layers and particles. Meanwhile, due to the much more compact microstructure, D-gun sprayed MCrAlYX coating showed superior oxidation resistance to the HVOF sprayed coating. The continuous dense protective layer can form earlier in D-gun sprayed coating and thus suppress further oxidation and control the oxide thickness at a relatively low level.展开更多
In order to investigate the appIication effects of microbial ecoIogical agents as repIacements for antibiotics in weaned pigIets, a total of 120 28 d oId healthy Duroc ×Landrace ×Large White weaned pigIets...In order to investigate the appIication effects of microbial ecoIogical agents as repIacements for antibiotics in weaned pigIets, a total of 120 28 d oId healthy Duroc ×Landrace ×Large White weaned pigIets with simiIar bogy weights and body fats and cIose birth dates were seIected. They were randomIy divided into three groups, incIuding controI group (CK), antibiotic group (A) and microbial ecoIogical agent group (MEA). The growth performance, health status and economic benefits of the weaned pigIets were measured. The resuIts showed that the A and MEA groups couId better enhance the immunity of weaned pigIets and improve the economic benefits in the whoIe experimental period compared to the CK group (P〈0.01). How-ever, there were no significant differences in pigIet immunity and economic benefits between the A and MEA groups (P〉0.05). It is indicated that the Rujunbao, a mi-crobial ecoIogical agent, can be promoted in weaned pigIet production as a repIace-ment for antibiotic.展开更多
TiC particle reinforced 420 stainless steel matrix composites were fabricated, and the microstructure, tensile properties and wear resistance of the composites were studied. The experimental results indicate that the ...TiC particle reinforced 420 stainless steel matrix composites were fabricated, and the microstructure, tensile properties and wear resistance of the composites were studied. The experimental results indicate that the distribution of TiC particles with size of 5 to 10 μm in diameter is uniform if the volume fraction of TiC is lower than 6%. However, slight agglomeration can be observed when the TiC content exceeds 6%. With the increase of TiC content the tensile and yield strength of the composites prepared increases and reaches the maximum when the volume fraction of TiC increases to 5%. Further increase of TiC content causes reductions of yield and tensile strength. The ductility of the composites shows a monotone decrease with the increase of TiC addition. The introduction of TiC into 420 stainless steel results in significant improvement on wear resistance, which reaches a steady level when the volume fraction of TiC increases to 11% and does not show obvious variation if the TiC content is further increased.展开更多
[Objective] This study aimed to determine the effect of rare earth biological regulator LaCl3 on the absorptive capacity to formaldehyde of four indoor ornamental plants, and to screen out the plant whose absorptive c...[Objective] This study aimed to determine the effect of rare earth biological regulator LaCl3 on the absorptive capacity to formaldehyde of four indoor ornamental plants, and to screen out the plant whose absorptive capacity to formaldehyde can be increased most greatly by LaCl3. [Method] Effect of LaCl3 on absorptive capacity to formaldehyde of four indoor ornamental plants was studied through fumigating in laboratory. Simultaneously, the indoor ornamental plant, which could significantly en- hance the degradation capacity of formaldehyde, was screened out to study the physiological and biochemical mechanisms of formaldehyde resistance. [Result] The ability to absorb formaldehyde of four indoor ornamental plants was enhanced by dif- ferent ranges after spraying with LaCl3 at suitable concentrations. The ability to ab- sorb formaldehyde of Hedera nepalensis var. sinensis, Chlorophytum comosum, Scindapsus aureun and Sansevieria trifasciata increased by 15.16%, 4.72%, 19.75% and 7.68%, respectively. In the four indoor ornamental plants, the capacity of S. au- reun to absorb formaldehyde was greatly improved by spraying LaCl3. When S. au- reun was stressed by formaldehyde, its chlorophyll content decreased by 39.87%, membrane permeability, MDA accumulation and POD activity increased by 8.17%, 56.92%, and 11.32%, respectively. However, compared the pre-spraying group with the no-spraying group under formaldehyde stress, chlorophyll content of S. aureun reduced less, membrane permeability and MDA cumulative both increased less, but POD activity increased more. [Conclusion] The formaldehyde absorption capacity of S. aureun was mostly improved after LaCl3 was sprayed.展开更多
基金National Natural Science Foundation of China (52072088, 52072089)Natural Science Foundation of Heilongjiang Province (LH2023E061)+1 种基金Scientific and Technological Innovation Leading Talent of Harbin Manufacturing (2022CXRCCG001)Fundamental Research Funds for the Central Universities (3072023CFJ1003)。
文摘Hexagonal boron nitride(h-BN)ceramics have become exceptional materials for heat-resistant components in hypersonic vehicles,owing to their superior thermal stability and excellent dielectric properties.However,their densification during sintering still poses challenges for researchers,and their mechanical properties are rather unsatisfactory.In this study,SrAl_(2)Si_(2)O_(8)(SAS),with low melting point and high strength,was introduced into the h-BN ceramics to facilitate the sintering and reinforce the strength and toughness.Then,BN-SAS ceramic composites were fabricated via hot press sintering using h-BN,SrCO_(3),Al_(2)O_(3),and SiO_(2) as raw materials,and effects of sintering pressure on their microstructure,mechanical property,and thermal property were investigated.The thermal shock resistance of BN-SAS ceramic composites was evaluated.Results show that phases of as-preparedBN-SAS ceramic composites are h-BN and h-SrAl_(2)Si_(2)O_(8).With the increase of sintering pressure,the composites’densities increase,and the mechanical properties shew a rising trend followed by a slight decline.At a sintering pressure of 20 MPa,their bending strength and fracture toughness are(138±4)MPa and(1.84±0.05)MPa·m^(1/2),respectively.Composites sintered at 10 MPa exhibit a low coefficient of thermal expansion,with an average of 2.96×10^(-6) K^(-1) in the temperature range from 200 to 1200℃.The BN-SAS ceramic composites prepared at 20 MPa display higher thermal conductivity from 12.42 to 28.42 W·m^(-1)·K^(-1) within the temperature range from room temperature to 1000℃.Notably,BN-SAS composites exhibit remarkable thermal shock resistance,with residual bending strength peaking and subsequently declining sharply under a thermal shock temperature difference ranging from 600 to 1400℃.The maximum residual bending strength is recorded at a temperature difference of 800℃,with a residual strength retention rate of 101%.As the thermal shock temperature difference increase,the degree of oxidation on the ceramic surface and cracks due to thermal stress are also increased gradually.
基金Project(202302AB080024)supported by the Department of Science and Technology of Yunnan Province,China。
文摘The evolution of mechanical properties,localized corrosion resistance of a high purity Al-Zn-Mg-Cu alloy during non-isothermal aging(NIA)was investigated by hardness test,electrical conductivity test,tensile test,intergranular corrosion test,exfoliation corrosion test,slow strain rate tensile test and electrochemical test,and the mechanism has been discussed based on microstructure examination by optical microscopy,electron back scattered diffraction,scanning electron microscopy and scanning transmission electron microscopy.The NIA treatment includes a heating stage from 40℃to 180℃with a rate of 20℃/h and a cooling stage from 180℃to 40℃with a rate of 10℃/h.The results show that the hardness and strength increase rapidly during the heating stage of NIA since the increasing temperature favors the nucleation and the growth of strengthening precipitates and promotes the transformation of Guinier-Preston(GPI)zones toη'phase.During the cooling stage,the sizes ofη'phase increase with a little change in the number density,leading to a further slight increase of the hardness and strength.As NIA proceeds,the corroded morphology in the alloy changes from a layering feature to a wavy feature,the maximum corrosion depth decreases,and the reason has been analyzed based on the microstructural and microchemical feature of precipitates at grain boundaries and subgrain boundaries.
文摘[Objective]The aim was to study the effects of sunflower artificial aging on seed vigor and physiological characteristics.[Method] The varieties of seed germination capacity,vigor of germination,germination index,vigor index,peroxidase(POD) activity,superoxide dismutase(SOD) activity and malondialdehyde(MDA) content for four sunflower germplasms such as'SunM20','Deep Purple Minle','Da San Kui Hua 4'and'Ji Kui 24'were studied under high temperature and high humidity conditions(100% RH,45 ℃) for different days(0 d,2 d,4 d,6 d,8 d,10 d).[Result]The result showed that the germination capacity,vigor of germination,germination index,vigor index,POD activity,SOD activity declined gradually with the increase of seed aging days,whereas MDA content enhanced by degrees;The diggerences of resistance to artifical aging existed among the four accessions,'SunM20'was the most resistant one,and exhibited the strongest seed vigor,highest activities of two protective enzyme(POD,SOD) and lowest content of MDA at the uniform condition,moreover,the seed vigor and protective enzyme activities of'SunM20'changed slowest among the four materials during the aging process.[Conclusion]The distinct reduction of POD,SOD activities maybe the main reasons for the decrease of sunflower seed vigor at the artificial aging,and the gradual accumulation of a few MDA accelerated seeds aging.
基金The Basic Scientific Research Funds of Hohai University (No. B1020133)
文摘For a deeper understanding of the shear resistance performance of the steel-concrete-steel composite shear wall, the main influence factors such as the thicknesses of the steel plates and the concrete, the strength grades of the concrete and the span-depth ratios of the composite wall, which have impacts on the shear resistance performance of the composite shear wail, are analyzed by the numerical simulation method. Meanwhile, the simplified calculation formulae of the initial elastic lateral-resisting stiffness and the shear bearing capacity of the composite shear wall are also proposed. The research shows that with the increase in the thicknesses of the steel plates and the concrete and the increase in the strength grades of the concrete, the shear performance of the shear wall improves obviously; the span-depth ratios of the composite wall have a significant effect on the initial elastic lateral- resisting stiffness, but a small effect on the shear bearing capacity. Comparing the results of the simplified calculation formulae with those of the nonlinear finite element method, it is obvious that the presented formulae are reasonable and meet the real force state of the structure. These conclusions can serve as a preliminary design reference for the steel-concrete- steel composite shear wall.
文摘To investigate the feasibility and seismic performance of the horizontal joints in an innovative precast shear wall system, two test walls were fabricated, and the monotonic and cyclic loading tests were performed on the two test walls, respectively. Then, the lateral load-top displacement curves, load beating capacity, ductility, lateral stiffness, strains of steel bars, strain distribution on the connecting steel frame (CSF), and relative slippages between the CSF and embedded limbic steel frame (ELSF) were discussed in detail. The test results show that the load bearing capacity and ductility of the test wall are both favorable with a displacement ductility factor of more than 3.7. The normal and shear stresses in the CSF except for the compression end are far smaller than the yield stresses throughout the test procedure. Certain slippages of about 1.13 mm occurs between the CSF and ELSF on the compression side of the test wall, while almost no slippages occurs on the tension side. The seismic performance of the test wall is favorable and the new-type scheme of the horizontal joints is both feasible and reliable.
基金Project(51201156)supported by the National Natural Science Foundation of China
文摘Microstructure, mechanical property and oxidation resistance of MCrAlYX coatings prepared by detonation gun (D-gun) and HVOF spraying were investigated. Lamellar microstructure and uniform microstructure formed in D-gun sprayed MCrAlYX coating and HVOF sprayed coating, respectively. Element redistribution and formation of new phase took place during the detonation process. Besides, the porosity of D-gun sprayed coating was much lower than that of HVOF sprayed coating. On the mechanical property, the micro-hardnesses of the two coatings were in the same level (~HV 910). However, D-gun sprayed MCrAlYX coating exhibited larger standard deviation of microhardness due to its lamellar microstructure, and exhibited better bend bonding strength owing to the existence of residual compressive stress between the layers and particles. Meanwhile, due to the much more compact microstructure, D-gun sprayed MCrAlYX coating showed superior oxidation resistance to the HVOF sprayed coating. The continuous dense protective layer can form earlier in D-gun sprayed coating and thus suppress further oxidation and control the oxide thickness at a relatively low level.
基金Vegetable Basket Projects of Beijing Vocational College of Agriculture for Improving Scientific and Technological Capabilities of New Business Entities~~
文摘In order to investigate the appIication effects of microbial ecoIogical agents as repIacements for antibiotics in weaned pigIets, a total of 120 28 d oId healthy Duroc ×Landrace ×Large White weaned pigIets with simiIar bogy weights and body fats and cIose birth dates were seIected. They were randomIy divided into three groups, incIuding controI group (CK), antibiotic group (A) and microbial ecoIogical agent group (MEA). The growth performance, health status and economic benefits of the weaned pigIets were measured. The resuIts showed that the A and MEA groups couId better enhance the immunity of weaned pigIets and improve the economic benefits in the whoIe experimental period compared to the CK group (P〈0.01). How-ever, there were no significant differences in pigIet immunity and economic benefits between the A and MEA groups (P〉0.05). It is indicated that the Rujunbao, a mi-crobial ecoIogical agent, can be promoted in weaned pigIet production as a repIace-ment for antibiotic.
文摘TiC particle reinforced 420 stainless steel matrix composites were fabricated, and the microstructure, tensile properties and wear resistance of the composites were studied. The experimental results indicate that the distribution of TiC particles with size of 5 to 10 μm in diameter is uniform if the volume fraction of TiC is lower than 6%. However, slight agglomeration can be observed when the TiC content exceeds 6%. With the increase of TiC content the tensile and yield strength of the composites prepared increases and reaches the maximum when the volume fraction of TiC increases to 5%. Further increase of TiC content causes reductions of yield and tensile strength. The ductility of the composites shows a monotone decrease with the increase of TiC addition. The introduction of TiC into 420 stainless steel results in significant improvement on wear resistance, which reaches a steady level when the volume fraction of TiC increases to 11% and does not show obvious variation if the TiC content is further increased.
基金Supported by the Qing Lan Project for Excellent Young Key Teachers of Colleges and Universities of Jiangsu Province in 2010 [Jiangsu Teacher(2010)27]Undergraduate Practice and Innovation Training Program of Colleges and Universities of Jiangsu Province in 2010 and 2012 [Jiangsu Education Department(2010)27,Jiangsu Education Department Office(2012)3]+2 种基金Fund of Jiangsu R&D Center for Engineering Technology of Preventing and Treating Rural Environmental Pollution [(2011)13]Science and Technology Program of Nantong City(DE2009006S2009019)~~
文摘[Objective] This study aimed to determine the effect of rare earth biological regulator LaCl3 on the absorptive capacity to formaldehyde of four indoor ornamental plants, and to screen out the plant whose absorptive capacity to formaldehyde can be increased most greatly by LaCl3. [Method] Effect of LaCl3 on absorptive capacity to formaldehyde of four indoor ornamental plants was studied through fumigating in laboratory. Simultaneously, the indoor ornamental plant, which could significantly en- hance the degradation capacity of formaldehyde, was screened out to study the physiological and biochemical mechanisms of formaldehyde resistance. [Result] The ability to absorb formaldehyde of four indoor ornamental plants was enhanced by dif- ferent ranges after spraying with LaCl3 at suitable concentrations. The ability to ab- sorb formaldehyde of Hedera nepalensis var. sinensis, Chlorophytum comosum, Scindapsus aureun and Sansevieria trifasciata increased by 15.16%, 4.72%, 19.75% and 7.68%, respectively. In the four indoor ornamental plants, the capacity of S. au- reun to absorb formaldehyde was greatly improved by spraying LaCl3. When S. au- reun was stressed by formaldehyde, its chlorophyll content decreased by 39.87%, membrane permeability, MDA accumulation and POD activity increased by 8.17%, 56.92%, and 11.32%, respectively. However, compared the pre-spraying group with the no-spraying group under formaldehyde stress, chlorophyll content of S. aureun reduced less, membrane permeability and MDA cumulative both increased less, but POD activity increased more. [Conclusion] The formaldehyde absorption capacity of S. aureun was mostly improved after LaCl3 was sprayed.