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高强度超拉伸合成多肽聚天冬氨酸衍生物水凝胶研究
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作者 徐晓辉 《化工设计通讯》 CAS 2022年第1期114-116,共3页
通过化学碱水解法从聚琥珀酰亚胺(PSI)制得聚天冬氨酸(PASP)。引入1-乙基-3-(3-二甲氨基丙基)碳二亚胺(EDC)和N-羟基琥珀酰亚胺(NHS)后,通过取代反应接枝苯磺酸基团,制得聚天冬氨酸衍生聚合物PASP-SAA。最终通过引入交联剂1,4-丁二醇二... 通过化学碱水解法从聚琥珀酰亚胺(PSI)制得聚天冬氨酸(PASP)。引入1-乙基-3-(3-二甲氨基丙基)碳二亚胺(EDC)和N-羟基琥珀酰亚胺(NHS)后,通过取代反应接枝苯磺酸基团,制得聚天冬氨酸衍生聚合物PASP-SAA。最终通过引入交联剂1,4-丁二醇二缩水甘油醚,制备PASP-SAA水凝胶。通过对PASP-SAA水凝胶进行溶胀和力学性能测试,凝胶交联密度高,溶胀性较低,形态稳定性好,断裂强度约为3.8MPa,断裂伸长率为700%,具有良好的能量分散性和自回复性能。引入的苯磺酸基团,有效改善PASP-SAA凝胶的离子导电性,电导率为5.65mS/cm,其作为全固态柔性超级电容器的电解质极具潜力。 展开更多
关键词 聚天冬氨酸 水凝胶 强度
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LMU弹性缓冲系统配方设计研究 被引量:1
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作者 李凯 李新超 +2 位作者 刘保权 孙建帮 马美琴 《当代化工研究》 2018年第5期164-165,共2页
LMU竖向缓冲件(以下简称VE)对橡胶材料有着严苛的性能要求,产品压缩比高达30%以上,且对耐老化返原和耐撕裂性能也有较高要求。国产化的LMU缓冲件示范应用于文昌9-2/9-3CEP组块浮托安装项目,其中VE的压缩比达45%、制品厚度大、硫化时间... LMU竖向缓冲件(以下简称VE)对橡胶材料有着严苛的性能要求,产品压缩比高达30%以上,且对耐老化返原和耐撕裂性能也有较高要求。国产化的LMU缓冲件示范应用于文昌9-2/9-3CEP组块浮托安装项目,其中VE的压缩比达45%、制品厚度大、硫化时间长和特殊的设计结构等因素要求胶料具有100%定伸低、拉伸强度高、撕裂强度高、耐返原性能好、压缩永久变形低等特点,本文介绍了胶料进行的一些配方优化方案。 展开更多
关键词 压缩比达45% 100%定 拉伸强度高 配方优化方案
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Effects of weld reinforcement on tensile behavior and mechanical properties of 2219-T87 aluminum alloy TIG welded joints 被引量:6
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作者 王国庆 李权 +4 位作者 李艳军 吴爱萍 麻宁绪 鄢东洋 吴会强 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2017年第1期10-16,共7页
Tungsten inert gas (TIG) welded joints for 2219-T87 aluminum alloy are often used in the fuel tanks of large launch vehicles. Because of the massive loads these vehicles carry, dealing with weld reinforcement on TIG... Tungsten inert gas (TIG) welded joints for 2219-T87 aluminum alloy are often used in the fuel tanks of large launch vehicles. Because of the massive loads these vehicles carry, dealing with weld reinforcement on TIG joints represents an important issue in their manufacturing and strength evaluation. Experimental and numerical simulation methods were used to investigate the effects of weld toe shape and weld toe position on the tensile behavior and mechanical properties of these joints. The simulation results indicated that the relative difference in elongation could be as large as 96.9% caused by the difference in weld toe shape. The joints with weld toes located in the weld metal or in the partially melted zone (PMZ) exhibited larger elongation than joints with weld toes located at the juncture of the weld metal and the PMZ. 展开更多
关键词 tensile strength weld reinforcement 2219-T87 aluminum alloy TIG welding digital image correlation (DIC) technique
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Microstructure and creep properties of Mg-4Al-2Sn-1(Ca,Sr) alloys 被引量:4
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作者 B.H.KIM K.C.PARK +1 位作者 Y.H.PARK I.M.PARK 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2010年第7期1184-1191,共8页
The effects of Ca and Sr addition on the microstructure and creep properties of Mg-4Al-2Sn alloys were examined. Tensile tests at 25 ℃ and 200 ℃ and creep tests at 150 ℃ and 200 ℃ were carried out to estimate the ... The effects of Ca and Sr addition on the microstructure and creep properties of Mg-4Al-2Sn alloys were examined. Tensile tests at 25 ℃ and 200 ℃ and creep tests at 150 ℃ and 200 ℃ were carried out to estimate the room temperature and high temperature mechanical properties of these alloys. The microstrueture of the Mg-4Al-2Sn alloy showed dendritic a-Mg, Mg17Al12 and Mg2Sn phases. The latter two phases precipitated along the grain boundaries. The addition of Ca and Sr resulted in the formation of ternary CaMgSn and SrMgSn phases within the grain. The grain size was reduced slightly with the addition of Sr and Ca. The tensile strength was decreased by the addition of Ca and Sr at room temperature. However, the high temperature tensile strength was increased. The creep strength was improved by the addition of Ca and Sr. 展开更多
关键词 magnesium alloys CA SR void initiation mechanical properties creep mechanism
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Influence of exfoliation corrosion on tensile properties of a high strength Al-Zn-Mg-Cu alloy 被引量:3
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作者 刘胜胆 廖文博 +2 位作者 唐建国 张新明 刘心宇 《Journal of Central South University》 SCIE EI CAS 2013年第1期1-6,共6页
The influence of exfoliation corrosion on the tensile properties of a high strength Al-Zn-Mg-Cu alloy was investigated by ambient temperature tensile testing, optical microscopy, transmission electron microscopy (TEM... The influence of exfoliation corrosion on the tensile properties of a high strength Al-Zn-Mg-Cu alloy was investigated by ambient temperature tensile testing, optical microscopy, transmission electron microscopy (TEM), scanning electron microscopy (SEM) and electron backscatter diffraction (EBSD). After exfoliation corrosion immersion, blisters and corrosion pits can be seen on the sheet surface, which lead to loss of materials and notches. A number of intergranular cracks are observed to initiate at the bottom of the corrosion-induced notches and propagate rapidly into the bulk materials during tensile. Consequently, exfoliation corrosion results in significant loss of strength and brittle fracture. EBSD results show that the crack propagation path is primarily along the grain boundaries with misorientation of-45°, and coincidence site lattice (CSL) boundaries are slightly more resistant to crack. 展开更多
关键词 EXFOLIATION tensile properties FRACTURE grain boundaries Al-Zn-Mg-Cu alloy
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Effect laws and mechanisms of different temperatures on isothermal tensile fracture morphologies of high-strength boron steel 被引量:1
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作者 刘佳宁 宋燕利 +1 位作者 路珏 郭巍 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第4期1191-1202,共12页
The fracture behaviour and morphologies of high-strength boron steel were investigated at different temperatures at a constant strain rate of 0.1 s-1 based on isothermal tensile tests. Fracture mechanisms were also an... The fracture behaviour and morphologies of high-strength boron steel were investigated at different temperatures at a constant strain rate of 0.1 s-1 based on isothermal tensile tests. Fracture mechanisms were also analyzed based on the relationship between microstructure transformation and continuous cooling transformation(CCT) curves. It is found that 1) fractures of the investigated steel at high temperatures are dimple fractures; 2) the deformation of high-strength boron steel at high temperatures accelerates diffusion transformations; thus, to obtain full martensite, a higher cooling rate is needed; and 3) the investigated steel has the best plasticity when the deformation temperature is 750 °C. 展开更多
关键词 high-strength boron steel fracture morphology isothermal tensile test
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