To obtain a balance between strength and ductility in NiFeCoCrMn high-entropy alloy, the degree of dislocation strengthening was tuned via partial recrystallization during traditional thermomechanical processing(cold ...To obtain a balance between strength and ductility in NiFeCoCrMn high-entropy alloy, the degree of dislocation strengthening was tuned via partial recrystallization during traditional thermomechanical processing(cold rolling and recrystallization). The tensile properties in each state were then examined. Significant improvements in uniform elongation and work hardening rate, with decrease in yield strength and ultimate tensile strength, are associated with increase in the recrystallized fraction, i.e., reductions in the degree of strain hardening. In particular, recrystallized fractions of 37% and 74% are obtained by annealing at 650 ℃ for 10 min and 15 min, respectively, which results in yield strengths of 1003 MPa and 742 MPa and uniform elongations of 4% and 24%, respectively. The strengthening is due to the unrecrystallized grains with a high density of dislocations, whereas the ductility benefits from the presence of recrystallized strain-free grains.展开更多
Optical microscope,X-ray diffractometer,scanning electron microscope,tensile tester and dynamic mechanical analyzer(DMA) were applied to investigate the effects of Y and Zn additions on microstructure,mechanical prope...Optical microscope,X-ray diffractometer,scanning electron microscope,tensile tester and dynamic mechanical analyzer(DMA) were applied to investigate the effects of Y and Zn additions on microstructure,mechanical properties and damping capacity of Mg-3Cu-1Mn(CM31) alloy.The results show that with the increase of Y and Zn contents,the secondary dendrite arm spacing of alloys is reduced;meanwhile,the yield strength is increased.In low strain amplitude,the damping capacity of alloys with Y and Zn addition is lower than that of CM31 alloy.However,in strain amplitude over 5×10-3,the damping capacity of alloy with a trace of Y and Zn addition(1%Y and 2%Zn,mass fraction) increases abnormally with the increase of strain amplitude and is near to that of pure Mg,probably due to the increase of dislocation density caused by the precipitation of secondary phase.The temperature dependence of damping capacity of above alloy was also tested and discussed.展开更多
AZ91 Mg alloy recycled by a solid state process and equal channel angular pressing(ECAP)exhibited a superior strength. The mechanical properties of AZ91 Mg alloy recycled from machined chips by extrusion at 623 K and ...AZ91 Mg alloy recycled by a solid state process and equal channel angular pressing(ECAP)exhibited a superior strength. The mechanical properties of AZ91 Mg alloy recycled from machined chips by extrusion at 623 K and ECAP at 573 K and 623 K were compared with those of the reference alloy which was produced from an as-received AZ91 Mg alloy block under the same conditions as the recycled alloy.The recycled specimens show a higher strength at room temperature than the reference alloy.The improvement of the tensile properties is attributed not only to the small grain size,but also to the dispersed oxide contaminants.展开更多
From the point of growth units, the growth mechanism of hydrotalcite (HT) crystal is investigated in this paper. Results show that the growth morphology of HT is consistent with the model of anion coordination polyhed...From the point of growth units, the growth mechanism of hydrotalcite (HT) crystal is investigated in this paper. Results show that the growth morphology of HT is consistent with the model of anion coordination polyhedron growth units. The Raman shift of growth solutions of HT, Cu-HTlc, and Cu-Zn-HTlc are monitored using Raman spectroscopy. In the experiment, the growth units of Mg-Al-hydrotalcite are [Mg-(OH)6]4- and [Al-(OH)6]3-, and the growth units of Cu-Htlc and Cu-Zn-HTlc are [Mg-(OH)6]4- and [Al-(OH)6]3-, respectively. The growth process of hydrotalcite is as follows: growth units first incorpo- rate into metal layers, then metal layers adsorb An- and H2O, and the growth units incorporate into layer compounds according to this rule. Growth units will have different incorporations and growth morphologies caused by different growth surroundings. Furthermore, the reason why Cu-HTlc is difficult to synthesize is also interpreted in this paper.展开更多
基金sponsored by the National Natural Science Foundation of China (Nos. 51301123, 51971099)the open funds of State Key Laboratory of Materials Processing and Die & Mould Technology, China (No. P2019-005)。
文摘To obtain a balance between strength and ductility in NiFeCoCrMn high-entropy alloy, the degree of dislocation strengthening was tuned via partial recrystallization during traditional thermomechanical processing(cold rolling and recrystallization). The tensile properties in each state were then examined. Significant improvements in uniform elongation and work hardening rate, with decrease in yield strength and ultimate tensile strength, are associated with increase in the recrystallized fraction, i.e., reductions in the degree of strain hardening. In particular, recrystallized fractions of 37% and 74% are obtained by annealing at 650 ℃ for 10 min and 15 min, respectively, which results in yield strengths of 1003 MPa and 742 MPa and uniform elongations of 4% and 24%, respectively. The strengthening is due to the unrecrystallized grains with a high density of dislocations, whereas the ductility benefits from the presence of recrystallized strain-free grains.
基金Project(10876045) supported by the National Natural Science Foundation of China and China Academy of Engineering PhysicsProject(2007CB613704) supported by the National Basic Research Program of ChinaProject(CSTS2008AB4114) supported by Chongqing Science and Technology Commission,China
文摘Optical microscope,X-ray diffractometer,scanning electron microscope,tensile tester and dynamic mechanical analyzer(DMA) were applied to investigate the effects of Y and Zn additions on microstructure,mechanical properties and damping capacity of Mg-3Cu-1Mn(CM31) alloy.The results show that with the increase of Y and Zn contents,the secondary dendrite arm spacing of alloys is reduced;meanwhile,the yield strength is increased.In low strain amplitude,the damping capacity of alloys with Y and Zn addition is lower than that of CM31 alloy.However,in strain amplitude over 5×10-3,the damping capacity of alloy with a trace of Y and Zn addition(1%Y and 2%Zn,mass fraction) increases abnormally with the increase of strain amplitude and is near to that of pure Mg,probably due to the increase of dislocation density caused by the precipitation of secondary phase.The temperature dependence of damping capacity of above alloy was also tested and discussed.
基金Projects(50201005,50571031)supported by the National Natural Science Foundation of ChinaProject(2009DFA51830)supported by the Ministry of Science and Technology,China
文摘AZ91 Mg alloy recycled by a solid state process and equal channel angular pressing(ECAP)exhibited a superior strength. The mechanical properties of AZ91 Mg alloy recycled from machined chips by extrusion at 623 K and ECAP at 573 K and 623 K were compared with those of the reference alloy which was produced from an as-received AZ91 Mg alloy block under the same conditions as the recycled alloy.The recycled specimens show a higher strength at room temperature than the reference alloy.The improvement of the tensile properties is attributed not only to the small grain size,but also to the dispersed oxide contaminants.
基金supported by the National Natural Science Foundation of China (Grant Nos.40776071,40976074)
文摘From the point of growth units, the growth mechanism of hydrotalcite (HT) crystal is investigated in this paper. Results show that the growth morphology of HT is consistent with the model of anion coordination polyhedron growth units. The Raman shift of growth solutions of HT, Cu-HTlc, and Cu-Zn-HTlc are monitored using Raman spectroscopy. In the experiment, the growth units of Mg-Al-hydrotalcite are [Mg-(OH)6]4- and [Al-(OH)6]3-, and the growth units of Cu-Htlc and Cu-Zn-HTlc are [Mg-(OH)6]4- and [Al-(OH)6]3-, respectively. The growth process of hydrotalcite is as follows: growth units first incorpo- rate into metal layers, then metal layers adsorb An- and H2O, and the growth units incorporate into layer compounds according to this rule. Growth units will have different incorporations and growth morphologies caused by different growth surroundings. Furthermore, the reason why Cu-HTlc is difficult to synthesize is also interpreted in this paper.