Bilayer graphene with a twist angle O between the layers generates a superlattice structure known as a Moir6 pattern. This superlattice provides a O-dependent q wavevector that activates phonons in the interior of the...Bilayer graphene with a twist angle O between the layers generates a superlattice structure known as a Moir6 pattern. This superlattice provides a O-dependent q wavevector that activates phonons in the interior of the Brillouin zone. Here we show that this superlattice-induced Raman scattering can be used to probe the phonon dispersion in twisted bilayer graphene （tBLG）. The effect reported here is different from the widely studied double-resonance in graphene-related materials in many aspects, and despite the absence of stacking order in tBLG, layer breathing vibrations （namely ZO＇ phonons） are observed.展开更多
Owing to its distinguished mechanical stiffness and strength, graphene has become an ideal reinforcing material in kinds of composite materials. In this work, the graphene（reduced graphene oxide） reinforced aluminum...Owing to its distinguished mechanical stiffness and strength, graphene has become an ideal reinforcing material in kinds of composite materials. In this work, the graphene（reduced graphene oxide） reinforced aluminum（Al）matrix composites were fabricated by flaky powder metallurgy. Tensile tests of pure Al matrix and graphene/Al composites with bioinspired layered structures are conducted.By means of an independently developed Python-based structural modeling program, three-dimensional microscopic structural models of graphene/Al composites can be established, in which the size, shape, orientation, location and content of graphene can be reconstructed in line with the actual graphene/Al composite structures. Elastoplastic mechanical properties, damaged materials behaviors, grapheneAl interfacial behaviors and reasonable boundary conditions are introduced and applied to perform the simulations. Based on the experimental and numerical tensile behaviors of graphene/Al composites, the effects of graphene morphology,graphene-Al interface, composite configuration and failure behavior within the tensile mechanical deformations of graphene/Al composites can be revealed and indicated, respectively.From the analysis above, a good understanding can be brought to light for the deformation mechanism of graphene/Al composites.展开更多
文摘Bilayer graphene with a twist angle O between the layers generates a superlattice structure known as a Moir6 pattern. This superlattice provides a O-dependent q wavevector that activates phonons in the interior of the Brillouin zone. Here we show that this superlattice-induced Raman scattering can be used to probe the phonon dispersion in twisted bilayer graphene （tBLG）. The effect reported here is different from the widely studied double-resonance in graphene-related materials in many aspects, and despite the absence of stacking order in tBLG, layer breathing vibrations （namely ZO＇ phonons） are observed.
基金financial supports by the National Natural Science Foundation (51501111, 51131004)the Ministry of Science and Technology of China (2016YFE0130200)+1 种基金Science & Technology Committee of Shanghai (14DZ2261200, 1452 0710100 and 14JC14033 00)111 Project (B16032)
文摘Owing to its distinguished mechanical stiffness and strength, graphene has become an ideal reinforcing material in kinds of composite materials. In this work, the graphene（reduced graphene oxide） reinforced aluminum（Al）matrix composites were fabricated by flaky powder metallurgy. Tensile tests of pure Al matrix and graphene/Al composites with bioinspired layered structures are conducted.By means of an independently developed Python-based structural modeling program, three-dimensional microscopic structural models of graphene/Al composites can be established, in which the size, shape, orientation, location and content of graphene can be reconstructed in line with the actual graphene/Al composite structures. Elastoplastic mechanical properties, damaged materials behaviors, grapheneAl interfacial behaviors and reasonable boundary conditions are introduced and applied to perform the simulations. Based on the experimental and numerical tensile behaviors of graphene/Al composites, the effects of graphene morphology,graphene-Al interface, composite configuration and failure behavior within the tensile mechanical deformations of graphene/Al composites can be revealed and indicated, respectively.From the analysis above, a good understanding can be brought to light for the deformation mechanism of graphene/Al composites.
