We report herein a highly selective method for directly determining the trace Co^2+in highly concentrated zinc electrolyte.This novel method is based on a second derivative wave of catalytic adsorptive polarography ge...We report herein a highly selective method for directly determining the trace Co^2+in highly concentrated zinc electrolyte.This novel method is based on a second derivative wave of catalytic adsorptive polarography generated by complexing Co^2+with dimethylglyoxime and nitrite onto a dropping mercury electrode.By employing a medium with NH3-NH4Cl buffer,DMG and NaNO2 during determining the trace Co^2+,any interferences of highly concentrated Zn^2+and other coexisting metal ions in the electrolyte are completely eliminated due to the selective masking effect of EDTA.When the concentration of Co^2+is within 1.0×10^–10–3.2×10^–7 mol/L range,it shows a good linear relationship with the current peak.Detection limit is 1.0×10^–11 mol/L,and RSD≤2.7%for six successive assays.We have compared the efficiency of the current method to that obtained by cobalt nitroso-R-salt spectrophotometry,and the absolute values of relative deviations are≤4.2%.The method developed and described herein has been successfully employed in determining the trace Co2+in actual zinc electrolyte.展开更多
As the share of photovoltaic power generation in power system has increased year by year, the optimization choice of access system schemes become one of the first and most important problems in grid before admitting p...As the share of photovoltaic power generation in power system has increased year by year, the optimization choice of access system schemes become one of the first and most important problems in grid before admitting photovoltaic power generation. Therefore, this article takes a proposed distributed photovoltaic as an example to research and analyze two kinds of high density multiple access points distributed photovoltaic access system schemes. The emphasis is making a comprehensive comparison and selection among the aspect of active power loss and economic benefit, etc. In the premise of ensuring the normal power generation of the photovoltaic system, it puts forward the recommended scheme that can help to spontaneous self-consumption, elimination on the spot, effectively decrease network loss and economic benefit.展开更多
基金Projects(61533021,61773403)supported by the National Natural Science Foundation of China
文摘We report herein a highly selective method for directly determining the trace Co^2+in highly concentrated zinc electrolyte.This novel method is based on a second derivative wave of catalytic adsorptive polarography generated by complexing Co^2+with dimethylglyoxime and nitrite onto a dropping mercury electrode.By employing a medium with NH3-NH4Cl buffer,DMG and NaNO2 during determining the trace Co^2+,any interferences of highly concentrated Zn^2+and other coexisting metal ions in the electrolyte are completely eliminated due to the selective masking effect of EDTA.When the concentration of Co^2+is within 1.0×10^–10–3.2×10^–7 mol/L range,it shows a good linear relationship with the current peak.Detection limit is 1.0×10^–11 mol/L,and RSD≤2.7%for six successive assays.We have compared the efficiency of the current method to that obtained by cobalt nitroso-R-salt spectrophotometry,and the absolute values of relative deviations are≤4.2%.The method developed and described herein has been successfully employed in determining the trace Co2+in actual zinc electrolyte.
文摘As the share of photovoltaic power generation in power system has increased year by year, the optimization choice of access system schemes become one of the first and most important problems in grid before admitting photovoltaic power generation. Therefore, this article takes a proposed distributed photovoltaic as an example to research and analyze two kinds of high density multiple access points distributed photovoltaic access system schemes. The emphasis is making a comprehensive comparison and selection among the aspect of active power loss and economic benefit, etc. In the premise of ensuring the normal power generation of the photovoltaic system, it puts forward the recommended scheme that can help to spontaneous self-consumption, elimination on the spot, effectively decrease network loss and economic benefit.
