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气相色谱法测定车间空气挥发性有机毒物 被引量:2
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作者 孙辑凯 《齐齐哈尔医学院学报》 2007年第9期1083-1084,共2页
目的为石油化工企业车间空气中的多种有害污染物提供快速准确的定性、定量分析方法。方法用活性炭管采集被污染车间中一定量的空气,用二硫化碳解吸后,在毛细管柱气相色谱仪上进行分析,测定其方法的工作曲线、最低检出限、测量范围、解... 目的为石油化工企业车间空气中的多种有害污染物提供快速准确的定性、定量分析方法。方法用活性炭管采集被污染车间中一定量的空气,用二硫化碳解吸后,在毛细管柱气相色谱仪上进行分析,测定其方法的工作曲线、最低检出限、测量范围、解吸效率等。结果2006年9月和12月,用此法分两次对齐齐哈尔某石油化工企业车间空气成功进行了监测分析。结论此法对存在多种有害成分污染的车间空气,用活性炭管采样后进行分析,试验结果符合实验方法的要求。 展开更多
关键词 气相色谱法 毛细管色谱柱 石油化工车间空气 挥发性有机毒物
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挥发性有机毒物测定标准曲线斜率值及斜率指数K值的应用 被引量:1
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作者 崔强 钟磊 +3 位作者 伍岳 张妍 杨礼萍 沈壮 《职业与健康》 CAS 2016年第17期2351-2355,共5页
目的探讨气相色谱测定空气中有机毒物标准曲线斜率值及斜率指数K值的应用。方法经过长期试验,总结32种工作场所常见毒物色谱标准物标准曲线回归方程的斜率b值,观察色谱仪条件不变和使用同一支色谱柱时不同毒物色谱标准物所产生斜率b值... 目的探讨气相色谱测定空气中有机毒物标准曲线斜率值及斜率指数K值的应用。方法经过长期试验,总结32种工作场所常见毒物色谱标准物标准曲线回归方程的斜率b值,观察色谱仪条件不变和使用同一支色谱柱时不同毒物色谱标准物所产生斜率b值的大小,计算斜率特性指数K值。结果用气相色谱非极性毛细管DB-1柱做工作场所常见毒物色谱标准物标准曲线,保持色谱条件一直不变。既使浓度相同,不同的化学物质由于其分子组成和分子结构的差异,导致在FID检测器出峰积分面积的不同。把一种色谱标准物标线的b值与甲苯标线的b值之比值作为斜率指数K值。四氯化碳的斜率指数K值最小,为0.050 3,二甲苯的斜率指数K值最大,为1.07,其余30种毒物色谱标准物标准曲线的斜率指数K值在两者之间。结论同一种毒物标准物的K值,在一定色谱条件下,是一个固定值,是一种毒物标准物的特征参数。利用这种特征参数的规律,可以判断标准曲线做的是否准确。做混标时,可以判断哪个色谱峰代表的是哪种标准物。 展开更多
关键词 挥发性有机毒物 气相色谱标准曲线 斜率b值和斜率特性指数K值
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Novel Air Purification System for Installation in Air Handling Units: Development, Assembly and Experimental Analysis
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作者 Rafael Simao Ferreira de Sousa 《Journal of Chemistry and Chemical Engineering》 2013年第9期885-891,共7页
Nowadays, people pass 90% of their time in closed spaces, therefore, an increasing care in the creation and upkeep of healthier environments as a personal and as professional level become a major issue. The present pr... Nowadays, people pass 90% of their time in closed spaces, therefore, an increasing care in the creation and upkeep of healthier environments as a personal and as professional level become a major issue. The present project has as goal the verification and optimization of the implicit need of an OCRAMclima~ AHU (air handling units) in IAQ (indoor air quality) and its effectiveness in treatment and/or air purification, having as basis the legal national and European requirements for IAQ. This work was based on the study of the state of the art of the techniques in air purification and in the evaluation of their performance, culminating in the production of the prototype OCRAMclima~ NPS (nano purifying system). The purifying phenomena involved are UVGI (ultraviolet germicidal irradiation) and catalytic ionization of air. The performance test was accomplished in a closed loop circuit, which results, obtained by an independent IAQ analyst, were satisfactory, indicating the viability of application of this system to indoor air disinfection. The outcome revealed that the conjugating of both phenomena, the air sterilizing by UV and catalytic ionization, is efficient when used for air purification, mainly for volatile organic compounds and bioaerosols. 展开更多
关键词 Indoor air quality ultraviolet germicidal irradiation catalytic ionization titanium dioxide air microbiologicalpurification volatile organic compounds oxidation.
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