Two different types of potential oscillations have been identified for the first time during dichromate reduction on a gold electrode in a solution of dilute sulfuric acid. One occurs before hydrogen evolution due to ...Two different types of potential oscillations have been identified for the first time during dichromate reduction on a gold electrode in a solution of dilute sulfuric acid. One occurs before hydrogen evolution due to the formation and dissolution of passivating films of low-valence chromium oxides, and the other generates, accompanying periodic hydrogen evolution, from the coupling of electrochemical reactions with diffusive and convective mass transport. More interestingly, these two types of oscillations correspond to two crossing loops in the cyclic voltammogram （CV）. Such a relation of oscillations with crossed CVs will provide a new way to find electrochemical oscillatory systems systematically and rapidly.展开更多
In order to explain the oscillation heat transfer dynamics of closed loop oscillation heat pipe (CLOHP) with two liquid slugs,analysis on the forces and heat transfer process of the partial gas-liquid phase system inv...In order to explain the oscillation heat transfer dynamics of closed loop oscillation heat pipe (CLOHP) with two liquid slugs,analysis on the forces and heat transfer process of the partial gas-liquid phase system involving multiple parameters was carried out,and a new type oscillation heat transfer dynamic model of the CLOHP was set up based on conservation laws of mass,momentum and energy.Application results indicate that its oscillation heat transfer dynamics features depend largely on the filling rate,pipe diameter and difference in temperature.Besides,oscillation intensity and transfer performance can be improved to a large extent by increasing the temperature difference properly and enlarging the pipe diameter within a certain range under a certain filling rate.展开更多
Self-sustained oscillation and the sound radiation of flow over an open cavity is of great importance in nature and industry.Influences of filled porous media in the cavity are investigated numerically by using a latt...Self-sustained oscillation and the sound radiation of flow over an open cavity is of great importance in nature and industry.Influences of filled porous media in the cavity are investigated numerically by using a lattice Boltzmann method in two-dimensional space.It is shown that the outcomes of the porous patch depend on the location of the patch and the original flow mode,namely shear layer(SL)and wake mode(WM).For SL flow,the porous patch either damps the vortical flow or suppresses the generation of the secondary vortex sheet on the wall.The later effect destabilizes the SL.Consequently,the radiated sound is reduced as the patch is on the trailing edge,and increased with porous patch on the floor,respectively.For flow in WM,a transition from WM to SL mode is found when the porous patch is set either on the floor or behind the leading wall.In the cases,the recirculating flow on large scale is blocked significantly due to the porous patch,therefore,the WM flow is not sustained.On the other hand,the porous patch on the trailing edge slightly weakens the sound due to dissipation.The study shows that assembling of porous media in the flow field decreases the radiated sound level only if it is done carefully.展开更多
文摘Two different types of potential oscillations have been identified for the first time during dichromate reduction on a gold electrode in a solution of dilute sulfuric acid. One occurs before hydrogen evolution due to the formation and dissolution of passivating films of low-valence chromium oxides, and the other generates, accompanying periodic hydrogen evolution, from the coupling of electrochemical reactions with diffusive and convective mass transport. More interestingly, these two types of oscillations correspond to two crossing loops in the cyclic voltammogram （CV）. Such a relation of oscillations with crossed CVs will provide a new way to find electrochemical oscillatory systems systematically and rapidly.
基金Project(531107040300)supported by the Fundamental Research Funds for the Central Universities in ChinaProject(51176045)supported by the National Natural Science Foundation of China
文摘In order to explain the oscillation heat transfer dynamics of closed loop oscillation heat pipe (CLOHP) with two liquid slugs,analysis on the forces and heat transfer process of the partial gas-liquid phase system involving multiple parameters was carried out,and a new type oscillation heat transfer dynamic model of the CLOHP was set up based on conservation laws of mass,momentum and energy.Application results indicate that its oscillation heat transfer dynamics features depend largely on the filling rate,pipe diameter and difference in temperature.Besides,oscillation intensity and transfer performance can be improved to a large extent by increasing the temperature difference properly and enlarging the pipe diameter within a certain range under a certain filling rate.
基金supported by the National Natural Science Foundation of China(Grant No.11872315)the Natural Science Basic Research Program of Shaanxi(Grant No.2019JM-105).
文摘Self-sustained oscillation and the sound radiation of flow over an open cavity is of great importance in nature and industry.Influences of filled porous media in the cavity are investigated numerically by using a lattice Boltzmann method in two-dimensional space.It is shown that the outcomes of the porous patch depend on the location of the patch and the original flow mode,namely shear layer(SL)and wake mode(WM).For SL flow,the porous patch either damps the vortical flow or suppresses the generation of the secondary vortex sheet on the wall.The later effect destabilizes the SL.Consequently,the radiated sound is reduced as the patch is on the trailing edge,and increased with porous patch on the floor,respectively.For flow in WM,a transition from WM to SL mode is found when the porous patch is set either on the floor or behind the leading wall.In the cases,the recirculating flow on large scale is blocked significantly due to the porous patch,therefore,the WM flow is not sustained.On the other hand,the porous patch on the trailing edge slightly weakens the sound due to dissipation.The study shows that assembling of porous media in the flow field decreases the radiated sound level only if it is done carefully.
