Solid sorbents adsorption is considered as one of the potential options for CO2 capture process. CO2 adsorption on MCM-68 (Si/AI ratio 22) sorbent material was investigated. MCM-68 was synthesized using N,N,N',N'-...Solid sorbents adsorption is considered as one of the potential options for CO2 capture process. CO2 adsorption on MCM-68 (Si/AI ratio 22) sorbent material was investigated. MCM-68 was synthesized using N,N,N',N'-tetraethylbicyclo [2.2.2] oct-7-ene-2,3:5,6-dipyrrolidinium diiodide (TEBOP^2+(I^+)2) as a structure-directing agent (SDA). CO2 adsorption capacity on MCM-68 sorbent was measured at a broad temperature window i.e. 60 ℃, 300 ℃ and at 400 ℃. The presence of ordered mesoporous structure, high surface area (456 me/g) and high thermal stability (TGA analysis up to 900℃) in MCM-68 are thought to be to be advantageous for the CO2 adsorption in broad temperature window.展开更多
To prevent CO_2 accumulation in the atmosphere generated from scorching of fossil fuels, carbon capture and sequestration(CCS) technology is considered as a potential route to mitigate the emissions of CO_2 from reach...To prevent CO_2 accumulation in the atmosphere generated from scorching of fossil fuels, carbon capture and sequestration(CCS) technology is considered as a potential route to mitigate the emissions of CO_2 from reaching the atmosphere. Power generation from sources such as gas, coal and biomass can fulfill the energy demand more readily than many other sources of electricity production. Thus these sources may be retained as important alternative option in the global energy cycle. In order to curtail CO_2, porous aramid network was fabricated by the condensation of 1,3,5-benzenetricarbonyl trichloride and 1,3-phenylenediamine in 1,4-dioxane solvent. Aramid was characterized for various analyses including FTIR, XRD, TGA, BET surface area and pore size analysis, FESEM and CO_2 adsorption measurements. Excellent thermal stability was provided by strong amide linkages in the polymer backbone. Optimum CO_2 uptake of aramid was achieved to be 23.14 mg·g^(-1) at 273 K at 0.1 MPa. The basic amide groups of network structure showed greater affinity for CO_2.Excellent thermal stability of aramid makes it a promising sorbent for CO_2 capture in adverse conditions.展开更多
文摘Solid sorbents adsorption is considered as one of the potential options for CO2 capture process. CO2 adsorption on MCM-68 (Si/AI ratio 22) sorbent material was investigated. MCM-68 was synthesized using N,N,N',N'-tetraethylbicyclo [2.2.2] oct-7-ene-2,3:5,6-dipyrrolidinium diiodide (TEBOP^2+(I^+)2) as a structure-directing agent (SDA). CO2 adsorption capacity on MCM-68 sorbent was measured at a broad temperature window i.e. 60 ℃, 300 ℃ and at 400 ℃. The presence of ordered mesoporous structure, high surface area (456 me/g) and high thermal stability (TGA analysis up to 900℃) in MCM-68 are thought to be to be advantageous for the CO2 adsorption in broad temperature window.
文摘To prevent CO_2 accumulation in the atmosphere generated from scorching of fossil fuels, carbon capture and sequestration(CCS) technology is considered as a potential route to mitigate the emissions of CO_2 from reaching the atmosphere. Power generation from sources such as gas, coal and biomass can fulfill the energy demand more readily than many other sources of electricity production. Thus these sources may be retained as important alternative option in the global energy cycle. In order to curtail CO_2, porous aramid network was fabricated by the condensation of 1,3,5-benzenetricarbonyl trichloride and 1,3-phenylenediamine in 1,4-dioxane solvent. Aramid was characterized for various analyses including FTIR, XRD, TGA, BET surface area and pore size analysis, FESEM and CO_2 adsorption measurements. Excellent thermal stability was provided by strong amide linkages in the polymer backbone. Optimum CO_2 uptake of aramid was achieved to be 23.14 mg·g^(-1) at 273 K at 0.1 MPa. The basic amide groups of network structure showed greater affinity for CO_2.Excellent thermal stability of aramid makes it a promising sorbent for CO_2 capture in adverse conditions.