Lithium elemental and isotopic disequilibrium has frequently been observed in the continental and oceanic mantle xenoliths, but its origin remains controversial. Here,we present a combined elemental and Li isotopic st...Lithium elemental and isotopic disequilibrium has frequently been observed in the continental and oceanic mantle xenoliths, but its origin remains controversial. Here,we present a combined elemental and Li isotopic study on variably metasomatised peridotite xenoliths entrained in the Cenozoic basalts from Shangzhi in Northeast (NE) China that provides insight into this issue. Li concentration (0.3–2.7 ppm) and δ7 Li (mostly 2‰–6‰) in olivine from the Shangzhi peridotites are similar to the normal mantle values and show roughly negative correlations with the indices of melt extraction(such as modal olivine and whole rock MgO). These features are consistent with variable degrees of partial melting. In contrast, clinopyroxene from the Shangzhi xenoliths shows significant Li enrichment (0.9–6.1 ppm) and anomalously light δ7 Li (-13.8‰ to7.7‰) relative to normal mantle values. Such features can be explained by Li diffusion from silicate melts or Li-rich fluids occurring over a very short time(several minutes to several hours). Moreover, the light Li isotopic compositions preserved in some bulk samples also indicate that these percolated melts/fluids have not had enough time to isotopically equilibrate with the bulk peridotite. We thus emphasize that Li isotopic fractionation in the Shangzhi mantle xenoliths is mainly related to Li diffusion from silicate melts or Li-rich fluids that took place shortly before or coincident with their entrainment into the host magmas.展开更多
Mantle xenoliths brought up by Cenozoic volcanic rocks onto the earth’s surface may provide direct information about the upper mantle beneath the volcanic region. This paper presents the study on mantle xenoliths col...Mantle xenoliths brought up by Cenozoic volcanic rocks onto the earth’s surface may provide direct information about the upper mantle beneath the volcanic region. This paper presents the study on mantle xenoliths collected from Haoti village, Dangchang County, Gansu Province, western China. The main purpose of the study is to gain an insight into the thermal structure and rheology of the upper mantle beneath the region. The results show that the upper mantle of the region is composed mainly of spinel lherzolite at shallower depth (52~75km), and garnet lherzolite at greater depth (greater than 75km), instead of harzburgite and dunite as proposed by some previous studies. The upper mantle geotherm derived from the equilibrium temperatures and pressures of xenoliths from the region is lower than that of North China, and is somewhat closer to the Oceanic geotherm. The crust-mantle boundary is determined from the geotherm to be at about 52km, and the Moho seems to be the transition zone of lower crust material with spinel lherzolite. If we take 1280℃ as the temperature of the top of asthenosphere, then the lithosphere-asthenosphere boundary should be at about 120km depth. The differential stress of the upper mantle is determined by using recrystallized grain size piezometry, while the strain rate and equivalent viscosity are determined by using the high temperature flow law of peridotite. The differential stress, strain rate and viscosity profiles constructed on the basis of the obtained values indicate that asthenospheric diapir occurred in this region during the Cenozoic time, resulting in the corresponding thinning of the lithosphere. However, the scale and intensity of the diapir was significantly less than that occurring in the North China region. Moreover, numerous small-scale shear zones with localized deformation might occur in the lithospheric mantle, as evidenced by the extensive occurrence of xenoliths with tabular equigranular texture.展开更多
This paper reports petrographic, mineral chemical, olivine oxygen isotopic, and whole-rock geochemical data for wehrlite xenoliths from the Early Cretaceous Tietonggou high-Mg diorites in western Shandong Province, in...This paper reports petrographic, mineral chemical, olivine oxygen isotopic, and whole-rock geochemical data for wehrlite xenoliths from the Early Cretaceous Tietonggou high-Mg diorites in western Shandong Province, in the eastern part of the North China Craton (NCC), and describes the origin of these wehrlites and the processes that affected the deep lithospheric mantle in this area.Wehrlite xenoliths are rounded and vary in size between 3 cm × 4 cm 5 cm and 3 cm 2 cm 1 cm.Olivine within these xenoliths occurs as an isolated residual phase within clinopyroxene, has Fo contents between 89 and 91, and contains between 1414 and 3629 ppm Ni, similar to the values of olivine from peridotite xenoliths in the Cenozoic basalts of eastern China, but lower than the values of olivine from harzburgite xenoliths in the Early Cretaceous high-Mg diorites in western Shandong.In situ oxygen isotope analysis yielded 18 O values of olivine from (6.03±0.33)‰ to (6.82±0.35)‰, averaging (6.5±0.4)‰; this is higher than typical mantle-derived olivine ((5.2±0.3)‰).Compared with clinopyroxenes from peridotite xenoliths in the Late Cretaceous and Cenozoic basalts, clinopyroxenes in the wehrlites contain relatively low concentrations of Na 2 O, TiO 2 , and Al 2 O 3 , high concentrations of CaO, and higher Mg # (91.2-94.1) and Ti/Eu ratios (2082-2845), being similar in composition to clinopyroxenes within harzburgite xenoliths in the Early Cretaceous high-Mg diorites.Clinopyroxenes from wehrlite xenoliths are characterized by low total REE abundance, enrichment in light REEs, and depletion in high field strength elements such as Nb, Ta, Zr, and Hf.Moreover, the 87 Sr/ 86 Sr, 143 Nd/ 144 Nd, and 187 Os/ 188 Os (125 Ma) ratios of these wehrlites vary from 0.70596 to 0.70737, 0.512181 to 0.512416, and 0.12661 to 0.57650, respectively.These data suggest that these wehrlite xenoliths were formed by modification of the lithospheric mantle by melts derived from recycled continental crust.展开更多
Trace amount of water associated with the lattice defects of nominally anhydrous minerals (NAMs) can be measured using Fourier transform infrared spectroscopy (FTIR) and secondary ion mass spectrometry (SIMS). L...Trace amount of water associated with the lattice defects of nominally anhydrous minerals (NAMs) can be measured using Fourier transform infrared spectroscopy (FTIR) and secondary ion mass spectrometry (SIMS). Lots of data on water in NAMs from different lithologies, especially mantle peridotite xenoliths, have been published. The water distribution in olivine from peridotite xenoliths often displays a diffusion profile with high water concentration in the core and low at the rim, which indicates water loss via diffusion during the ascent of host magma. On the other hand, water is homogeneously distributed in pyroxene and its concentration is typically interpreted to represent a mantle value. The water concentration of magma in equilibrium with NAM can be estimated using specific partition coefficient, from which the water content of parental magma and the mantle source can be inferred. The accuracy of this method, however, depends on the selection of appropriate partition coefficient for the system. Using hydrogen isotope compositions and H2O/Ce ratios of mantle NAMs, water source regions can be traced and water heterogeneity can be mapped in the upper mantle. Water plays an important role in the stability of cratonic mantle. The water contents and vertical distribution patterns can be significantly different among different cratonic manties, which may result from different geologic activities. However, the mantle-plume interaction may not necessarily result in significant change of water content in cratonic mantle. The estimation of the water content in the upper mantle is still largely based on geochemical models due to the limitations of data on water in mantle NAMs.展开更多
基金funded by the strategic priority research program(B)of the Chinese Academy of Sciences(XDB18000000)NSFC(41573009+1 种基金 41373042,41203031)Open research fund of the State Key Laboratory of Ore Deposit Geochemistry of China(SKLODG Grant#201204)
文摘Lithium elemental and isotopic disequilibrium has frequently been observed in the continental and oceanic mantle xenoliths, but its origin remains controversial. Here,we present a combined elemental and Li isotopic study on variably metasomatised peridotite xenoliths entrained in the Cenozoic basalts from Shangzhi in Northeast (NE) China that provides insight into this issue. Li concentration (0.3–2.7 ppm) and δ7 Li (mostly 2‰–6‰) in olivine from the Shangzhi peridotites are similar to the normal mantle values and show roughly negative correlations with the indices of melt extraction(such as modal olivine and whole rock MgO). These features are consistent with variable degrees of partial melting. In contrast, clinopyroxene from the Shangzhi xenoliths shows significant Li enrichment (0.9–6.1 ppm) and anomalously light δ7 Li (-13.8‰ to7.7‰) relative to normal mantle values. Such features can be explained by Li diffusion from silicate melts or Li-rich fluids occurring over a very short time(several minutes to several hours). Moreover, the light Li isotopic compositions preserved in some bulk samples also indicate that these percolated melts/fluids have not had enough time to isotopically equilibrate with the bulk peridotite. We thus emphasize that Li isotopic fractionation in the Shangzhi mantle xenoliths is mainly related to Li diffusion from silicate melts or Li-rich fluids that took place shortly before or coincident with their entrainment into the host magmas.
文摘Mantle xenoliths brought up by Cenozoic volcanic rocks onto the earth’s surface may provide direct information about the upper mantle beneath the volcanic region. This paper presents the study on mantle xenoliths collected from Haoti village, Dangchang County, Gansu Province, western China. The main purpose of the study is to gain an insight into the thermal structure and rheology of the upper mantle beneath the region. The results show that the upper mantle of the region is composed mainly of spinel lherzolite at shallower depth (52~75km), and garnet lherzolite at greater depth (greater than 75km), instead of harzburgite and dunite as proposed by some previous studies. The upper mantle geotherm derived from the equilibrium temperatures and pressures of xenoliths from the region is lower than that of North China, and is somewhat closer to the Oceanic geotherm. The crust-mantle boundary is determined from the geotherm to be at about 52km, and the Moho seems to be the transition zone of lower crust material with spinel lherzolite. If we take 1280℃ as the temperature of the top of asthenosphere, then the lithosphere-asthenosphere boundary should be at about 120km depth. The differential stress of the upper mantle is determined by using recrystallized grain size piezometry, while the strain rate and equivalent viscosity are determined by using the high temperature flow law of peridotite. The differential stress, strain rate and viscosity profiles constructed on the basis of the obtained values indicate that asthenospheric diapir occurred in this region during the Cenozoic time, resulting in the corresponding thinning of the lithosphere. However, the scale and intensity of the diapir was significantly less than that occurring in the North China region. Moreover, numerous small-scale shear zones with localized deformation might occur in the lithospheric mantle, as evidenced by the extensive occurrence of xenoliths with tabular equigranular texture.
基金supported by Chinese Ministry of Science and Technology(Grant No.2009CB825005)Natural Science Foundation of China(Grant Nos.90814003 and 90714010)+1 种基金State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences(Wuhan)State Key Laboratory of Continental Dynamics,Northwest University
文摘This paper reports petrographic, mineral chemical, olivine oxygen isotopic, and whole-rock geochemical data for wehrlite xenoliths from the Early Cretaceous Tietonggou high-Mg diorites in western Shandong Province, in the eastern part of the North China Craton (NCC), and describes the origin of these wehrlites and the processes that affected the deep lithospheric mantle in this area.Wehrlite xenoliths are rounded and vary in size between 3 cm × 4 cm 5 cm and 3 cm 2 cm 1 cm.Olivine within these xenoliths occurs as an isolated residual phase within clinopyroxene, has Fo contents between 89 and 91, and contains between 1414 and 3629 ppm Ni, similar to the values of olivine from peridotite xenoliths in the Cenozoic basalts of eastern China, but lower than the values of olivine from harzburgite xenoliths in the Early Cretaceous high-Mg diorites in western Shandong.In situ oxygen isotope analysis yielded 18 O values of olivine from (6.03±0.33)‰ to (6.82±0.35)‰, averaging (6.5±0.4)‰; this is higher than typical mantle-derived olivine ((5.2±0.3)‰).Compared with clinopyroxenes from peridotite xenoliths in the Late Cretaceous and Cenozoic basalts, clinopyroxenes in the wehrlites contain relatively low concentrations of Na 2 O, TiO 2 , and Al 2 O 3 , high concentrations of CaO, and higher Mg # (91.2-94.1) and Ti/Eu ratios (2082-2845), being similar in composition to clinopyroxenes within harzburgite xenoliths in the Early Cretaceous high-Mg diorites.Clinopyroxenes from wehrlite xenoliths are characterized by low total REE abundance, enrichment in light REEs, and depletion in high field strength elements such as Nb, Ta, Zr, and Hf.Moreover, the 87 Sr/ 86 Sr, 143 Nd/ 144 Nd, and 187 Os/ 188 Os (125 Ma) ratios of these wehrlites vary from 0.70596 to 0.70737, 0.512181 to 0.512416, and 0.12661 to 0.57650, respectively.These data suggest that these wehrlite xenoliths were formed by modification of the lithospheric mantle by melts derived from recycled continental crust.
基金supported by the National Natural Science Foundation of China (Grant Nos. 41590623 & 41573055)the Fundamental Research Funds for the Central Universities of China
文摘Trace amount of water associated with the lattice defects of nominally anhydrous minerals (NAMs) can be measured using Fourier transform infrared spectroscopy (FTIR) and secondary ion mass spectrometry (SIMS). Lots of data on water in NAMs from different lithologies, especially mantle peridotite xenoliths, have been published. The water distribution in olivine from peridotite xenoliths often displays a diffusion profile with high water concentration in the core and low at the rim, which indicates water loss via diffusion during the ascent of host magma. On the other hand, water is homogeneously distributed in pyroxene and its concentration is typically interpreted to represent a mantle value. The water concentration of magma in equilibrium with NAM can be estimated using specific partition coefficient, from which the water content of parental magma and the mantle source can be inferred. The accuracy of this method, however, depends on the selection of appropriate partition coefficient for the system. Using hydrogen isotope compositions and H2O/Ce ratios of mantle NAMs, water source regions can be traced and water heterogeneity can be mapped in the upper mantle. Water plays an important role in the stability of cratonic mantle. The water contents and vertical distribution patterns can be significantly different among different cratonic manties, which may result from different geologic activities. However, the mantle-plume interaction may not necessarily result in significant change of water content in cratonic mantle. The estimation of the water content in the upper mantle is still largely based on geochemical models due to the limitations of data on water in mantle NAMs.