A series of Cu-substituted Ni_(0.5-x)Cu_xZn_(0.5)Fe_2O_4(x=0.12,0.16,0.20,0.24 and 0.28) spinel ferrites were prepared by conventional ceramic method to investigate the effects of Cu compositional variation on the str...A series of Cu-substituted Ni_(0.5-x)Cu_xZn_(0.5)Fe_2O_4(x=0.12,0.16,0.20,0.24 and 0.28) spinel ferrites were prepared by conventional ceramic method to investigate the effects of Cu compositional variation on the structure and dielectric properties.XRD patterns demonstrate that all the samples are crystallized in single-phase cubic spinel structure and the lattice constant increases with increasing Cu content.White grains observed by SEM are Cu-rich phase.The dielectric constant versus frequency curve displays a normal dielectric behavior of spinel ferrites.While the frequency dependence of dielectric loss tangent is found to be abnormal,exhibiting a peak at certain frequency for all Cu-substituted Ni-Zn ferrites.A maximum of the resistivity is observed at x=0.2 due to the decrease of hopping electrons between Fe^(2+) and Fe^(3+) in per unit volume,which is in contrast with the Cu content dependence of dielectric constant and dielectric loss.展开更多
The studied sample is a metallic glass in Fe-Si-B system. It is developed with the nominal composition of Fe735-Cu1-Ta3-Si13.5-B9 by single-roller melt spinning technique in air. The dielectric constant and loss facto...The studied sample is a metallic glass in Fe-Si-B system. It is developed with the nominal composition of Fe735-Cu1-Ta3-Si13.5-B9 by single-roller melt spinning technique in air. The dielectric constant and loss factor have been measured both for as cast and annealed samples using Agilent Impedance analyzer. They are found to decrease with frequency up to 10 MHz and remain constant afterwards. The decrease of dielectric constant and loss factor with frequency is due to ceasing of orientational polarizability. Their constancy is owing to presence of only electronic contribution to its polarizability above 10 MHz. Three distinct regions （1-4 MHz, 4-10 MHz and 10 MHz-1 GHz） also noticed from its frequency dependence, which might make it useful in switching and sensor devices. The temperature dependence of dielectric constant and loss factor maintain inverse relationship： （1） dielectric constant increases, and （2） loss factor decreases with annealing temperature for structural relaxation due to thermal agitation.展开更多
The structural and electrical properties of lead free Srx-xLax（Tio.sFeo.5）O3 （SLTFO） prepared by standard solid state reaction technique were studied. The X-ray diffraction analysis confirmed the formation of a si...The structural and electrical properties of lead free Srx-xLax（Tio.sFeo.5）O3 （SLTFO） prepared by standard solid state reaction technique were studied. The X-ray diffraction analysis confirmed the formation of a single-phase cubic perovskite structure. The compositional dependence of lattice constant, density and microstructural studies show that they vary significantly with La3＋ content. When measured at 10 kHz, all the compositions of SLTFO at room temperature exhibit a high permittivity （about 104） and low dielectric loss （about 10-3）. SLTFO also display minimum dielectric loss within the lower and higher limits of frequency, indicating that the samples are of good quality. It is concluded from the calculated ac conductivity that the conduction is due to mixed polarons hopping. The complex impedance plot exhibits a tendency of forming a single semicircular arc for all compositions, which implies a dominance of grain boundary resistance on the impedance. Impedance parameters were determined by fitting the experimental data with Cole-Cole empirical formula. The results of the present experiment indicate that the lead free SLTFO materials with higher permittivity and lower dielectric loss have possible practical applications.展开更多
Mg-doped CaCu_(3-x)Mg_(x)Ti_(4)O_(12)(x=0,0.05,0.1,0.15,0.2,at.%)thin films were prepared by a modified sol−gel method.A comparative study on the microstructure and electrical properties of Mg-doped CaCu_(3)Ti_(4)O_(1...Mg-doped CaCu_(3-x)Mg_(x)Ti_(4)O_(12)(x=0,0.05,0.1,0.15,0.2,at.%)thin films were prepared by a modified sol−gel method.A comparative study on the microstructure and electrical properties of Mg-doped CaCu_(3)Ti_(4)O_(12)(CCTO)thin films was carried out.The grain sizes of the Mg-doped CCTO thin films were smaller in comparison to the undoped CCTO films.Furthermore,compared to undoped CCTO films,Mg-doped CCTO thin films obtained higher dielectric constant as well as excellent frequency stability.Meanwhile,Mg doping could reduce the dielectric loss of CCTO thin films in the frequency range of 104−106 Hz.The results showed that the Mg-doped CCTO thin films had the better electrical characteristics compared with the undoped CCTO films.The nonlinear coefficient of Mg-doped CCTO thin films at x=0.15 and x=0.1 was improved to 7.4 and 6.0,respectively.展开更多
In the light of fractal geometry theory, the characteristics of coal's electric parameters (including dielectric constant, alternating conductivity, dielectric loss angle tangent and electric polarization constant...In the light of fractal geometry theory, the characteristics of coal's electric parameters (including dielectric constant, alternating conductivity, dielectric loss angle tangent and electric polarization constant) were studied by using literature data. The results are shown that the electrical properties of coal have fractal characteristic. The fractal dimensions of dielectric, alternating conductivity, dielectric loss angle tangent were obtained, and are relative to the content of pyrite sulfur, heat and ash content of coal.展开更多
基金Project(M26012)supported by the Foundation of National Laboratory of Solid State Microstructures,China
文摘A series of Cu-substituted Ni_(0.5-x)Cu_xZn_(0.5)Fe_2O_4(x=0.12,0.16,0.20,0.24 and 0.28) spinel ferrites were prepared by conventional ceramic method to investigate the effects of Cu compositional variation on the structure and dielectric properties.XRD patterns demonstrate that all the samples are crystallized in single-phase cubic spinel structure and the lattice constant increases with increasing Cu content.White grains observed by SEM are Cu-rich phase.The dielectric constant versus frequency curve displays a normal dielectric behavior of spinel ferrites.While the frequency dependence of dielectric loss tangent is found to be abnormal,exhibiting a peak at certain frequency for all Cu-substituted Ni-Zn ferrites.A maximum of the resistivity is observed at x=0.2 due to the decrease of hopping electrons between Fe^(2+) and Fe^(3+) in per unit volume,which is in contrast with the Cu content dependence of dielectric constant and dielectric loss.
文摘The studied sample is a metallic glass in Fe-Si-B system. It is developed with the nominal composition of Fe735-Cu1-Ta3-Si13.5-B9 by single-roller melt spinning technique in air. The dielectric constant and loss factor have been measured both for as cast and annealed samples using Agilent Impedance analyzer. They are found to decrease with frequency up to 10 MHz and remain constant afterwards. The decrease of dielectric constant and loss factor with frequency is due to ceasing of orientational polarizability. Their constancy is owing to presence of only electronic contribution to its polarizability above 10 MHz. Three distinct regions （1-4 MHz, 4-10 MHz and 10 MHz-1 GHz） also noticed from its frequency dependence, which might make it useful in switching and sensor devices. The temperature dependence of dielectric constant and loss factor maintain inverse relationship： （1） dielectric constant increases, and （2） loss factor decreases with annealing temperature for structural relaxation due to thermal agitation.
基金Project supported by CASR of Bangladesh University of Engineering and Technology(BUET)
文摘The structural and electrical properties of lead free Srx-xLax（Tio.sFeo.5）O3 （SLTFO） prepared by standard solid state reaction technique were studied. The X-ray diffraction analysis confirmed the formation of a single-phase cubic perovskite structure. The compositional dependence of lattice constant, density and microstructural studies show that they vary significantly with La3＋ content. When measured at 10 kHz, all the compositions of SLTFO at room temperature exhibit a high permittivity （about 104） and low dielectric loss （about 10-3）. SLTFO also display minimum dielectric loss within the lower and higher limits of frequency, indicating that the samples are of good quality. It is concluded from the calculated ac conductivity that the conduction is due to mixed polarons hopping. The complex impedance plot exhibits a tendency of forming a single semicircular arc for all compositions, which implies a dominance of grain boundary resistance on the impedance. Impedance parameters were determined by fitting the experimental data with Cole-Cole empirical formula. The results of the present experiment indicate that the lead free SLTFO materials with higher permittivity and lower dielectric loss have possible practical applications.
基金the financial supports from the National Natural Science Foundation of China(Nos.52072004,51802003,51572113)。
文摘Mg-doped CaCu_(3-x)Mg_(x)Ti_(4)O_(12)(x=0,0.05,0.1,0.15,0.2,at.%)thin films were prepared by a modified sol−gel method.A comparative study on the microstructure and electrical properties of Mg-doped CaCu_(3)Ti_(4)O_(12)(CCTO)thin films was carried out.The grain sizes of the Mg-doped CCTO thin films were smaller in comparison to the undoped CCTO films.Furthermore,compared to undoped CCTO films,Mg-doped CCTO thin films obtained higher dielectric constant as well as excellent frequency stability.Meanwhile,Mg doping could reduce the dielectric loss of CCTO thin films in the frequency range of 104−106 Hz.The results showed that the Mg-doped CCTO thin films had the better electrical characteristics compared with the undoped CCTO films.The nonlinear coefficient of Mg-doped CCTO thin films at x=0.15 and x=0.1 was improved to 7.4 and 6.0,respectively.
基金Supported by Key Project of Chinese National Programs for Fundamental Research Development(973 Project 2005CB221502)
文摘In the light of fractal geometry theory, the characteristics of coal's electric parameters (including dielectric constant, alternating conductivity, dielectric loss angle tangent and electric polarization constant) were studied by using literature data. The results are shown that the electrical properties of coal have fractal characteristic. The fractal dimensions of dielectric, alternating conductivity, dielectric loss angle tangent were obtained, and are relative to the content of pyrite sulfur, heat and ash content of coal.
