The systematical and scalable frameworks were provided for estimating the blocking probabilities under asynchronous traffic in optical burst switching(OBS) nodes with limited wavelength conversion capability(LWCC) . T...The systematical and scalable frameworks were provided for estimating the blocking probabilities under asynchronous traffic in optical burst switching(OBS) nodes with limited wavelength conversion capability(LWCC) . The relevant system architectures of limited range and limited number of wavelength converters(WCs) deployed by a share-per-fiber(SPF) mode were developed,and the novel theoretical analysis of node blocking probability was derived by combining the calculation of discouraged arrival rate in a birth-death process and two-dimensional Markov chain model of SPF. The simulation results on single node performance verify the accuracy and effectiveness of the analysis models. Under most scenarios,it is difficult to distinguish the plots generated by the analysis and simulation. As the conversion degree increases,the accuracy of the analysis model worsens slightly. However,the utmost error on burst loss probability is far less than one order of magnitude and hence,still allows for an accurate estimate. Some results are of actual significance to the construction of next-generation commercial OBS backbones.展开更多
Many wave energy conversion devices have not been well received. The main reasons are that they are too complicated and not economical. However, in the last two decades direct conversion systems have drawn the attenti...Many wave energy conversion devices have not been well received. The main reasons are that they are too complicated and not economical. However, in the last two decades direct conversion systems have drawn the attention of researchers to their widely distributed energy source due to their simple structure and low cost. The most well-known direct conversion systems presently in use include the Archimedes Wave Swing (AWS) and Power Buoy (PB). In this paper, these two systems were simulated in the same conditions and their behaviors were studied in different wave conditions. In order to verify the simulations, results of the generator of the finite element computations were followed. An attempt was made to determine the merits and drawbacks of each method under different wave conditions by comparing the performance of the two systems. The wave conditions suitable for each system were specified.展开更多
CSP (concentrated solar power) has been viewed as the technology that if properly developed could lead to a large scale conversion of solar energy into electricity. CSP is a type of solar energy converter that is cl...CSP (concentrated solar power) has been viewed as the technology that if properly developed could lead to a large scale conversion of solar energy into electricity. CSP is a type of solar energy converter that is classified as thermal converter because the output power produced is a function of the operating temperature. The main components of a CSP plant are the solar field which is made up of the heliostat arrays, the receiver tower, the heat transfer fluid, the molten salt thermal energy storage tanks and the power conversion unit, which is made up of the turbine and the generator. The main advantage of CSP is that of a cheap thermal storage (i.e., molten salt storage) which makes it possible to dispatch power at a cost comparable to the grid electricity. Simulations run with the SAM (systems advisory model) developed by NREL (National Renewable Energy Laboratory) showed that CSP is capable of delivering electricity at the cost of 17UScents per kWh for the 30-year life of the plant. The main disadvantage of CSP however, is that of low efficiency (8%-16%). There are ongoing research works to improve the efficiency of the CSP. One way to improve the efficiency is to increase the operating temperature of the system. In this paper, the authors discussed different modules of the CSP plant and suggested ways to improve on the conversion efficiencies of individual modules. Finally, an overall systems performance simulation is carried using SAM and the simulation results show that electricity can be produced using CSP at the cost of RI.05 per kWh.展开更多
Paper deals about testing of device with gravity assisted heat pipes and about researching of wick heat pipes used to effective heat transfers from power switches of energy converter. At first, to simulate ambient con...Paper deals about testing of device with gravity assisted heat pipes and about researching of wick heat pipes used to effective heat transfers from power switches of energy converter. At first, to simulate ambient condition was designed thermostatic chamber where was monitoring temperature course on main parts of cooling device (energy converter, air cooler and heat pipes) at various position of cooling device. It was found, if the cooling device is in tilt position the cooling performance is better. But if the tilt angel of gravity assisted heat pipe is higher the heat transfer is lower. From reason improve heat transfer cooling device at tilt angle are manufactured heat pipes with the sintered, mesh screen and grooved capillary structures and tested their thermal performance at vertical and tilt angel 45~ position by calorimetric method. Article describes manufacturing process and thermal performance measuring method of wick heat pipes. This experiment testify that the wick heat pipe is able operate at tilt angle position than gravity assisted heat pipe and application of wick heat pipes into cooling device will improve his cooling performance.展开更多
The conversion of solar energyinto electricity reveals a huge importance in the production of"clean" energy, mainly when applied to decentralized production systems (micro-generation). However, there is the need t...The conversion of solar energyinto electricity reveals a huge importance in the production of"clean" energy, mainly when applied to decentralized production systems (micro-generation). However, there is the need to develop and optimize these processes in order to turn it more sustainable in economic and technological scoops. The main purpose of this work is to study the solar energy conversion into electricity through photovoltaic cells, characterizing the process efficiencies. This study intends to evaluate the energetic and exergetic efficiencies defining them as indicators in the formulation ofa sustainability index. All the procedures are in a theoretical scope with an illustrative example in the end of this work.展开更多
Synergistic optimization of donor-acceptor blend morphologyis a hurdle in the path of realizing efficient non-fullerene small-molecule organic solar cells(NFSMOSCs)due to the anisotropic conjugated backbones of both d...Synergistic optimization of donor-acceptor blend morphologyis a hurdle in the path of realizing efficient non-fullerene small-molecule organic solar cells(NFSMOSCs)due to the anisotropic conjugated backbones of both donor and acceptor.Therefore,developing a facile molecular design strategy to effectively regulate the crystalline properties of photoactive materials,and thus,enable the optimization of blend morphology is of vital importance.In this study,a new donor molecule B1,comprising phenyl-substituted benzodithiophene(BDT)central unit,exhibits strong interaction with the non-fullerene acceptor BO-4 Cl in comparison with its corresponding thiophene-substituted BDT-based material,BTR.As a result,the B1 is affected and induced from an edgeon to a face-on orientation by the acceptor,while the BTR and the acceptor behave individually for the similar molecular orientation in pristine and blend films according to grazing incidence wide angle X-ray scattering results.It means the donor-acceptor blend morphology is synergistically optimized in the B1 system,and the B1:BO-4 Cl-based devices achieve an outstanding power conversion efficiency(PCE)of 15.3%,further certified to be 15.1%by the National Institute of Metrology,China.Our results demonstrate a simple and effective strategy to improve the crystalline properties of the donor molecule as well as synergistically optimize the morphology of the all-small-molecule system,leading to the high-performance NFSM-OSCs.展开更多
The objective of this paper is to compare the performances of the themes, which could be used for wave energy conversion in the near future, under various irregular wave conditions. The turbines included in the paper ...The objective of this paper is to compare the performances of the themes, which could be used for wave energy conversion in the near future, under various irregular wave conditions. The turbines included in the paper are as follows: (a) Wells turbine with guide vanes; (b) impulse turbine with self-pitch-controlled guide vanes; (c) impulse turbine with fixed guide vanes. In this study, experimental investigations were carried out to clarify the performances of the turbines under steady flow conditions, and then a numerical simulation was used for predicting the performances under irregular wave conditions with various significant wave heights. As a result it was found that the running and starting characteristics of the impulse turbines could be superior to those of the Wells turbine.展开更多
With the rapid development in recent years, small-molecule organic solar cell is challenging the dominance of its counterpart, polymer solar cell. The top power conversion efficiencies of both single and tandem solar ...With the rapid development in recent years, small-molecule organic solar cell is challenging the dominance of its counterpart, polymer solar cell. The top power conversion efficiencies of both single and tandem solar cells based on small molecules have surpassed 9%. In this mini review, achievements of small molecules with impressive photovoltaic performance especially reported in the last two years were highlighted. The relationship between molecular structure and device performance was analyzed, which draws some rules for rational molecular design. Five series of p- and n-type small molecules were selected based on the consideration of their competitiveness of power conversion efficiencies.展开更多
A polystyrene-based ion-exchange resin was employed as the precursor for preparation of resin-derived carbon spheres (RCSs) through KOH activation with various impregnation ratios. Pore structure, yield and hardness...A polystyrene-based ion-exchange resin was employed as the precursor for preparation of resin-derived carbon spheres (RCSs) through KOH activation with various impregnation ratios. Pore structure, yield and hardness, surface functional groups of the samples and their adsorption performance towards dibenzothiophene (DBT) were investigated. The RCSs with large surface areas (up to 2696 m2/g) and total pore volumes (up to 1.46 cm3/g) exhibited larger adsorption capacities than a commercial ac- tivated carbon, F400. Polanyi-Dubinin-Mane (PDM) model was applied to fit the adsorption data, which proved that micropore filling was involved during the adsorption process. Moreover, a good linear relationship was observed between the ex- tra-micropore volume and adsorption capacity. Intra-particle diffusion (IPD) model was used to describe the kinetic data of DBT onto the adsorbents. The adsorption processes were divided into three stages according to the different diffusion parame- ter. The selective adsorption towards DBT in the presence of competing compounds was also investigated and the high selec- tivity of the RSCs towards DBT may be attributed to the large quantity of acidic oxygen-containing groups.展开更多
An effective thermodynamic transformation analysis method was proposed in this study. According to the phenomenon of ex- ergy consumption always coupling with heat transfer process, the effective thermodynamic tempera...An effective thermodynamic transformation analysis method was proposed in this study. According to the phenomenon of ex- ergy consumption always coupling with heat transfer process, the effective thermodynamic temperatures were defined, then the actual power cycle or refrigeration/heat pump cycle was transformed into the equivalent reversible Carnot or reverse Carnot cycles for thermodynamic analysis. The derived effective thermodynamic temperature of the hot reservoir of the equivalent reverse Camot cycle is the basis of the proposed method. The combined diagram of TR-h and TR-q was adopted for the analy- sis of the system performance and the exergy consumption, which takes advantage of the visual expression of the heat/work exchange and the enthalpy change, and is convenient for the calculation of the coefficient of performance and exergy con- sumptions. Take a heat pump water heater with refrigerant of R22 for example, the proposed method was systematically intro- duced, and the fitting formulas of the effective thermodynamic temperatures were given as demonstration. The results show that the proposed method has advantage and well application foreground in the performance simulation and estimation under the variable working conditions.展开更多
Three acceptor-donor-acceptor (A-D-A) small molecules DCAODTBDT, DRDTBDT and DTBDTBDT using dithieno[2,3-d:2',3'-d']benzo[1,2-b:4,5-b']dithiophene as the central building block, octyl cyanoacetate, 3-octylrhod...Three acceptor-donor-acceptor (A-D-A) small molecules DCAODTBDT, DRDTBDT and DTBDTBDT using dithieno[2,3-d:2',3'-d']benzo[1,2-b:4,5-b']dithiophene as the central building block, octyl cyanoacetate, 3-octylrhodanine and thiobarbituric acid as the end groups were designed and synthesized as donor materials in solution-processed photovoltaic cells (OPVs). The impacts of these different electron withdrawing end groups on the photophysical properties, energy levels, charge carrier mobility, morphologies of blend films, and their photovoltaic properties have been systematically investigated. OPVs device based on DRDTBDT gave the best power conversion efficiency (PCE) of 8.34%, which was significantly higher than that based on DCAODTBDT (4.83%) or DTBDTBDT (3.39%). These results indicate that rather dedicated and balanced consideration of absorption, energy levels, morphology, mobility, etc. for the design of small-molecule-based OPVs (SM-OPVs) and systematic investigations are highly needed to achieve high performance for SM-OPVs.展开更多
Vortex diode,as an important component in power fluidics,has been used in nuclear reprocessing engineering where it is desirable to avoid pumps with moving parts.The performance of the fluidic system depends on the ma...Vortex diode,as an important component in power fluidics,has been used in nuclear reprocessing engineering where it is desirable to avoid pumps with moving parts.The performance of the fluidic system depends on the matched design parameters of vortex diodes and the supporting facilities.However,no clear guidelines for design and optimization of vortex diodes system are available.Therefore,we carried out detailed experimental study on hydraulic characteristics of the vortex diodes system with changeable parameters to evolve such guidelines.The study covered a wide range of a vortex diode and vortex diodes system.The variation of averaged discharge and volumetric efficiency in respect to air supply pressure,liquid level of water tank and liquid level stroke of gas-liquid energy converter was studies.The experimental results were analyzed to develop design guidelines.The guidelines are shown to be useful for obtaining the design parameters that would yield the desired hydrau- lic performance for the required operating conditions.展开更多
Thermoelectric materials(TMs)can uniquely convert waste heat into electricity,which provides a potential solution for the global energy crisis that is increasingly severe.Bulk Cu2Se,with ionic conductivity of Cu ions,...Thermoelectric materials(TMs)can uniquely convert waste heat into electricity,which provides a potential solution for the global energy crisis that is increasingly severe.Bulk Cu2Se,with ionic conductivity of Cu ions,exhibits a significant enhancement of its thermoelectric figure of merit z T by a factor of^3 near its structural transition around 400 K.Here,we show a systematic study of the electronic structure of Cu2Se and its temperature evolution using high-resolution angle-resolved photoemission spectroscopy.Upon heating across the structural transition,the electronic states near the corner of the Brillouin zone gradually disappear,while the bands near the centre of Brillouin zone shift abruptly towards high binding energies and develop an energy gap.Interestingly,the observed band reconstruction well reproduces the temperature evolution of the Seebeck coefficient of Cu2 Se,providing an electronic origin for the drastic enhancement of the thermoelectric performance near 400 K.The current results not only bridge among structural phase transition,electronic structures and thermoelectric properties in a condensed matter system,but also provide valuable insights into the search and design of new generation of thermoelectric materials.展开更多
基金Project(60632010) supported by the National Natural Science Foundation of China
文摘The systematical and scalable frameworks were provided for estimating the blocking probabilities under asynchronous traffic in optical burst switching(OBS) nodes with limited wavelength conversion capability(LWCC) . The relevant system architectures of limited range and limited number of wavelength converters(WCs) deployed by a share-per-fiber(SPF) mode were developed,and the novel theoretical analysis of node blocking probability was derived by combining the calculation of discouraged arrival rate in a birth-death process and two-dimensional Markov chain model of SPF. The simulation results on single node performance verify the accuracy and effectiveness of the analysis models. Under most scenarios,it is difficult to distinguish the plots generated by the analysis and simulation. As the conversion degree increases,the accuracy of the analysis model worsens slightly. However,the utmost error on burst loss probability is far less than one order of magnitude and hence,still allows for an accurate estimate. Some results are of actual significance to the construction of next-generation commercial OBS backbones.
文摘Many wave energy conversion devices have not been well received. The main reasons are that they are too complicated and not economical. However, in the last two decades direct conversion systems have drawn the attention of researchers to their widely distributed energy source due to their simple structure and low cost. The most well-known direct conversion systems presently in use include the Archimedes Wave Swing (AWS) and Power Buoy (PB). In this paper, these two systems were simulated in the same conditions and their behaviors were studied in different wave conditions. In order to verify the simulations, results of the generator of the finite element computations were followed. An attempt was made to determine the merits and drawbacks of each method under different wave conditions by comparing the performance of the two systems. The wave conditions suitable for each system were specified.
文摘CSP (concentrated solar power) has been viewed as the technology that if properly developed could lead to a large scale conversion of solar energy into electricity. CSP is a type of solar energy converter that is classified as thermal converter because the output power produced is a function of the operating temperature. The main components of a CSP plant are the solar field which is made up of the heliostat arrays, the receiver tower, the heat transfer fluid, the molten salt thermal energy storage tanks and the power conversion unit, which is made up of the turbine and the generator. The main advantage of CSP is that of a cheap thermal storage (i.e., molten salt storage) which makes it possible to dispatch power at a cost comparable to the grid electricity. Simulations run with the SAM (systems advisory model) developed by NREL (National Renewable Energy Laboratory) showed that CSP is capable of delivering electricity at the cost of 17UScents per kWh for the 30-year life of the plant. The main disadvantage of CSP however, is that of low efficiency (8%-16%). There are ongoing research works to improve the efficiency of the CSP. One way to improve the efficiency is to increase the operating temperature of the system. In this paper, the authors discussed different modules of the CSP plant and suggested ways to improve on the conversion efficiencies of individual modules. Finally, an overall systems performance simulation is carried using SAM and the simulation results show that electricity can be produced using CSP at the cost of RI.05 per kWh.
文摘Paper deals about testing of device with gravity assisted heat pipes and about researching of wick heat pipes used to effective heat transfers from power switches of energy converter. At first, to simulate ambient condition was designed thermostatic chamber where was monitoring temperature course on main parts of cooling device (energy converter, air cooler and heat pipes) at various position of cooling device. It was found, if the cooling device is in tilt position the cooling performance is better. But if the tilt angel of gravity assisted heat pipe is higher the heat transfer is lower. From reason improve heat transfer cooling device at tilt angle are manufactured heat pipes with the sintered, mesh screen and grooved capillary structures and tested their thermal performance at vertical and tilt angel 45~ position by calorimetric method. Article describes manufacturing process and thermal performance measuring method of wick heat pipes. This experiment testify that the wick heat pipe is able operate at tilt angle position than gravity assisted heat pipe and application of wick heat pipes into cooling device will improve his cooling performance.
文摘The conversion of solar energyinto electricity reveals a huge importance in the production of"clean" energy, mainly when applied to decentralized production systems (micro-generation). However, there is the need to develop and optimize these processes in order to turn it more sustainable in economic and technological scoops. The main purpose of this work is to study the solar energy conversion into electricity through photovoltaic cells, characterizing the process efficiencies. This study intends to evaluate the energetic and exergetic efficiencies defining them as indicators in the formulation ofa sustainability index. All the procedures are in a theoretical scope with an illustrative example in the end of this work.
基金financially supported by the Basic and Applied Basic Research Major Program of Guangdong Province(2019B030302007)the National Natural Science Foundation of China(51873217,21734008,51703228,51961135103,51773047 and 51903239)。
文摘Synergistic optimization of donor-acceptor blend morphologyis a hurdle in the path of realizing efficient non-fullerene small-molecule organic solar cells(NFSMOSCs)due to the anisotropic conjugated backbones of both donor and acceptor.Therefore,developing a facile molecular design strategy to effectively regulate the crystalline properties of photoactive materials,and thus,enable the optimization of blend morphology is of vital importance.In this study,a new donor molecule B1,comprising phenyl-substituted benzodithiophene(BDT)central unit,exhibits strong interaction with the non-fullerene acceptor BO-4 Cl in comparison with its corresponding thiophene-substituted BDT-based material,BTR.As a result,the B1 is affected and induced from an edgeon to a face-on orientation by the acceptor,while the BTR and the acceptor behave individually for the similar molecular orientation in pristine and blend films according to grazing incidence wide angle X-ray scattering results.It means the donor-acceptor blend morphology is synergistically optimized in the B1 system,and the B1:BO-4 Cl-based devices achieve an outstanding power conversion efficiency(PCE)of 15.3%,further certified to be 15.1%by the National Institute of Metrology,China.Our results demonstrate a simple and effective strategy to improve the crystalline properties of the donor molecule as well as synergistically optimize the morphology of the all-small-molecule system,leading to the high-performance NFSM-OSCs.
文摘The objective of this paper is to compare the performances of the themes, which could be used for wave energy conversion in the near future, under various irregular wave conditions. The turbines included in the paper are as follows: (a) Wells turbine with guide vanes; (b) impulse turbine with self-pitch-controlled guide vanes; (c) impulse turbine with fixed guide vanes. In this study, experimental investigations were carried out to clarify the performances of the turbines under steady flow conditions, and then a numerical simulation was used for predicting the performances under irregular wave conditions with various significant wave heights. As a result it was found that the running and starting characteristics of the impulse turbines could be superior to those of the Wells turbine.
基金supported by the National Basic Research Program of China(2014CB643502)the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB12010200)the National Natural Science Foundation of China(91333113)
文摘With the rapid development in recent years, small-molecule organic solar cell is challenging the dominance of its counterpart, polymer solar cell. The top power conversion efficiencies of both single and tandem solar cells based on small molecules have surpassed 9%. In this mini review, achievements of small molecules with impressive photovoltaic performance especially reported in the last two years were highlighted. The relationship between molecular structure and device performance was analyzed, which draws some rules for rational molecular design. Five series of p- and n-type small molecules were selected based on the consideration of their competitiveness of power conversion efficiencies.
文摘A polystyrene-based ion-exchange resin was employed as the precursor for preparation of resin-derived carbon spheres (RCSs) through KOH activation with various impregnation ratios. Pore structure, yield and hardness, surface functional groups of the samples and their adsorption performance towards dibenzothiophene (DBT) were investigated. The RCSs with large surface areas (up to 2696 m2/g) and total pore volumes (up to 1.46 cm3/g) exhibited larger adsorption capacities than a commercial ac- tivated carbon, F400. Polanyi-Dubinin-Mane (PDM) model was applied to fit the adsorption data, which proved that micropore filling was involved during the adsorption process. Moreover, a good linear relationship was observed between the ex- tra-micropore volume and adsorption capacity. Intra-particle diffusion (IPD) model was used to describe the kinetic data of DBT onto the adsorbents. The adsorption processes were divided into three stages according to the different diffusion parame- ter. The selective adsorption towards DBT in the presence of competing compounds was also investigated and the high selec- tivity of the RSCs towards DBT may be attributed to the large quantity of acidic oxygen-containing groups.
基金supported by the National Natural Science Foundation of China (Grant No. 51076147)
文摘An effective thermodynamic transformation analysis method was proposed in this study. According to the phenomenon of ex- ergy consumption always coupling with heat transfer process, the effective thermodynamic temperatures were defined, then the actual power cycle or refrigeration/heat pump cycle was transformed into the equivalent reversible Carnot or reverse Carnot cycles for thermodynamic analysis. The derived effective thermodynamic temperature of the hot reservoir of the equivalent reverse Camot cycle is the basis of the proposed method. The combined diagram of TR-h and TR-q was adopted for the analy- sis of the system performance and the exergy consumption, which takes advantage of the visual expression of the heat/work exchange and the enthalpy change, and is convenient for the calculation of the coefficient of performance and exergy con- sumptions. Take a heat pump water heater with refrigerant of R22 for example, the proposed method was systematically intro- duced, and the fitting formulas of the effective thermodynamic temperatures were given as demonstration. The results show that the proposed method has advantage and well application foreground in the performance simulation and estimation under the variable working conditions.
基金supported by the Ministry of Science and Technology(2014CB643502,2016YFA0200200)the Natural Science Foundation of China(21404060,51422304,91433101)
文摘Three acceptor-donor-acceptor (A-D-A) small molecules DCAODTBDT, DRDTBDT and DTBDTBDT using dithieno[2,3-d:2',3'-d']benzo[1,2-b:4,5-b']dithiophene as the central building block, octyl cyanoacetate, 3-octylrhodanine and thiobarbituric acid as the end groups were designed and synthesized as donor materials in solution-processed photovoltaic cells (OPVs). The impacts of these different electron withdrawing end groups on the photophysical properties, energy levels, charge carrier mobility, morphologies of blend films, and their photovoltaic properties have been systematically investigated. OPVs device based on DRDTBDT gave the best power conversion efficiency (PCE) of 8.34%, which was significantly higher than that based on DCAODTBDT (4.83%) or DTBDTBDT (3.39%). These results indicate that rather dedicated and balanced consideration of absorption, energy levels, morphology, mobility, etc. for the design of small-molecule-based OPVs (SM-OPVs) and systematic investigations are highly needed to achieve high performance for SM-OPVs.
基金supported by the National Natural Science Foundation of China(Grant No.51006087)
文摘Vortex diode,as an important component in power fluidics,has been used in nuclear reprocessing engineering where it is desirable to avoid pumps with moving parts.The performance of the fluidic system depends on the matched design parameters of vortex diodes and the supporting facilities.However,no clear guidelines for design and optimization of vortex diodes system are available.Therefore,we carried out detailed experimental study on hydraulic characteristics of the vortex diodes system with changeable parameters to evolve such guidelines.The study covered a wide range of a vortex diode and vortex diodes system.The variation of averaged discharge and volumetric efficiency in respect to air supply pressure,liquid level of water tank and liquid level stroke of gas-liquid energy converter was studies.The experimental results were analyzed to develop design guidelines.The guidelines are shown to be useful for obtaining the design parameters that would yield the desired hydrau- lic performance for the required operating conditions.
基金the National Natural Science Foundation of China(11774190,11674229,11634009 and 11874264)the National Key R&D Program of China(2017YFA0304600,2017YFA0305400 and 2017YFA0402900)+2 种基金EPSRC Platform Grant(EP/M020517/1)the support from the Natural Science Foundation of Shanghai(17ZR1443300)the support from Tsinghua University Initiative Scientific Research Program。
文摘Thermoelectric materials(TMs)can uniquely convert waste heat into electricity,which provides a potential solution for the global energy crisis that is increasingly severe.Bulk Cu2Se,with ionic conductivity of Cu ions,exhibits a significant enhancement of its thermoelectric figure of merit z T by a factor of^3 near its structural transition around 400 K.Here,we show a systematic study of the electronic structure of Cu2Se and its temperature evolution using high-resolution angle-resolved photoemission spectroscopy.Upon heating across the structural transition,the electronic states near the corner of the Brillouin zone gradually disappear,while the bands near the centre of Brillouin zone shift abruptly towards high binding energies and develop an energy gap.Interestingly,the observed band reconstruction well reproduces the temperature evolution of the Seebeck coefficient of Cu2 Se,providing an electronic origin for the drastic enhancement of the thermoelectric performance near 400 K.The current results not only bridge among structural phase transition,electronic structures and thermoelectric properties in a condensed matter system,but also provide valuable insights into the search and design of new generation of thermoelectric materials.