旱耕人为土N_2O排放动力学特征及其影响因素

以黄土高原南部典型旱耕地—休闲地土壤为对象 ,研究了中等水分条件下 (6 5 %的田间持水量 )土壤 N2 O排放的动力学特征 ,以及土壤深度和氮磷营养因子对 N2 O排放量的影响。结果表明 ,施肥和未施肥处理 ,土壤 N2 O排放累积量随时间 t的变化均符合修正的 Elovich方程 y=bln(t) +a。反应初始浓度 (a)和表观反应速率(dy/ dt)大多数随土壤深度增加而递增 ,但 15℃时以 10 cm深处反应初始浓度最大 ;2 5℃时 ,表观反应速率以 15cm深处最高 ,即在中等水分条件下 ,随温度升高 ,试验土壤 10～ 15 cm深处为 N2 O产生的活跃场所。磷素对土壤N2 O的减排效应不仅表现在排放总量上 ,也存在于动力学参数初始浓度和表观反应速率之中。

Simulation study on combustion system of tankless gas water heater

This paper simulates the combustion system of a regular tankless gas water heater under different static pressure conditions.The simulation results are in accordance with the test results.It proves that the used physical and mathematical models are reasonable.The results show that the flame height and the excess air ratios depend on the system pressure drop but not on the absolute pressure at the combustion chamber.The pressure drop and the amount of combustion air have an inverse relationship with CO generation,and they also impact on the temperature and velocity fields.To reduce CO emission,a stronger fan is needed to provide extra pressure head to ensure that enough combustion air is introduced into the system.This study provides a useful research tool to develop products through computational fluid dynamic analysis and laboratory testing.

Methane Dynamics in Northern Peatlands: A Review

Northern peatlands store a large amount of carbon and play a significant role in the global carbon cycle. Owing to the presence of waterlogged and anaerobic conditions, peatlands are typically a source of methane (CH4), a very potent greenhouse gas. This paper reviews the key mechanisms of peatland CH4 production, consumption and transport and the major environmental and biotic controls on peatland CH4 emissions. The advantages and disadvantages of micrometeorological and chamber methods in measuring CH4 fluxes from northern peatlands are also discussed. The magnitude of CH4 flux varies considerably among peatland types (bogs and fens) and microtopographic locations (hummocks and hollows). Some anthropogenic activities including forestry, peat harvesting and industrial emission of sulphur dioxide can cause a reduction in CH4 release from northern peatlands. Further research should be conducted to investigate the in fluence of plant growth forms on CH4 flux from northern peatlands, determine the water table threshold at which plant production in peatlands enhances CH4 release, and quantify peatland CH4 exchange at plant community level with a higher temporal resolution using automatic chambers.

Synthesis of epichlorohydrin from 1,3-dichloropropanol using solid base

In this work, the synthesis of epichlorohydrin(ECH) from 1,3-dichloropropanol(DCP) by using solid sodium hydroxide(NaOH) is carefully investigated. Inert organic solvent, 1-octanol, is introduced to ensure reaction intensity under control. The reaction performances with respect to apparent kinetics and selectivity are determined to explore optimized reaction conditions and confirm potentials for enhancing productivity in one batch. The dissolution and liquid phase reaction mechanism and instant reaction assumption are proposed and verified through process analysis. A process design towards free additional water is schematically figured out to manipulate solid NaOH, by-product,and unreacted starting materials to realize a nearly closed circuit. This process allows high selectivity over 97% and complete DCP conversion at 323.2 K within a reaction time less than 20 min. Other advantages include near-zero wastewater emission, economically possible NaOH regeneration from NaCl, and robust operating condition window.

An analytical model for pyrolysis of a single biomass particle

Decreasing in emissions of greenhouse gases to confront the global warming needs to replace fossil fuels as the main doer of the world climate changes by renewable and clean fuels produced from biomass like wood waste which is neutral on the amount of CO2. An analytical and engineering model for pyrolysis process of a single biomass particle has been presented. Using a two-stage semi global kinetic model which includes both primary and secondary reactions, the effects of parameters like shape and size of particle as well as porosity on the particle temperature profile and product yields have been investigated. Comparison of the obtained results with experimental data shows that our results are in a reasonable agreement with previous researchers' works. Finally, a sensitivity analysis is done to determine the importance of each parameter on pyrolysis of a single biomass particle which is affected by many constant parameters.

Syngas Fuel Combustion in Re-circulating Vortex Combustor

This paper presents results on the combustion of syngas fuel in re-circulating vortex combustor. The combustion stability is achieved through the use of cavities in which recirculation zones of hot products generated by the direct injection of fuel and air are created and acting as a continuous source of ignition for the incoming main fuel-air stream. CFD （computational fluid dynamics） analysis was performed in this study to test the combustion performance and emissions from the vortex trapped combustor using synthetic gas or syngas fuel produced from the gasification process. The flame temperature, the flow field and species concentrations inside the vortex trapped combustor were obtained. Several syngas fuels with different fuel compositions （H2, CO, CH4, CO2, N2 and H20） and lower heating values were tested in this study. The changes on the flame temperature and species concentrations inside the combustor, the emissions of NOx, CO, CO2 at the exit of the combustor, the combustor efficiency and the total pressure drop for syngas fuels are presented in this paper. The effect of H2/CO ratio and the mass fraction of each constituent of syngas fuels and hydrogen-methane fuel mixtures on the combustion and emissions performances were investigated.

Assessing China 2030 carbon emissions from fossil fuels:based on system dynamics model

The Chinese government has set ambitious targets to reduce the per unit of GDP by 40% ~45% during 2005 to 2020 and achieve the intensity peaking of carbon emissions of CO2 emissions a- round 2030. The T21 national development model for China was developed for the purpose of analy- zing the effects of long-term national policies that relate to carbon emissions, loss of farm land, water shortage, energy security, food security, and their contributions to this reduction target. The focus of this paper is on the policies that have substantial impacts on carbon emissions from fossil fuels. Four scenarios are developed with the model to simulate future carbon emissions ： 1 ） the BAU （ busi- ness as usual） scenario, showing the likely results of continuing current policies; 2 ） the TECH （technology） scenario showing the effects of more investment in renewable energy sources and promoting more energy efficient technologies; 3 ） the BEHAVIOR scenario, showing how government tax and price policies, together with public education programs, would instigate behaviour changes towards more sustainable living; and 4 ） the TECH＆BEHA scenario, which shows the results of combining scenarios 2 and 3. The simulation results show that CO2 emissions reduction targets of China are achievable, but also require great effort to put in.

Distribution and Variation of Carbon Monoxide in the Tropical Troposphere and Lower Stratosphere

The authors examine the distribution and varia- tion of carbon monoxide （CO） in the tropics from the sur- face to the lower stratosphere. By analyzing space-borne microwave limb sounder （MLS） measurements, measure- ments of pollution in the troposphere （MOPITT） and mod- em-era retrospective analysis for research and applications （MERRA） meteorological products, and atmospheric chemistry and climate model intercomparison project （ACCMIP） surface emission inventories, the influences of atmospheric dynamics and surface emissions are investi- gated. The results show that there are four centers of highly concentrated CO mixing ratio over tropical areas in differ- ent seasons： two in the Northern Hemisphere and another two in the Southern Hemisphere. All of these centers cor- respond to local deep convective systems and mon- soons/anticyclones. The authors suggest that both deep convections and anticyclones affect CO in the tropical tro- posphere and lower stratosphere--the former helping to transport CO from the lower to the middle troposphere （or even higher）, and the dynamical uplift and isolation effects of the latter helping to build up highly concentrated CO in the upper troposphere and lower stratosphere （UTLS）. Similarly, there are two annual surface emission peaks in- duced by biomass burning emissions： one from the North- ern Hemisphere and the other from the Southern Hemi- sphere. Both contribute to the highly concentrated CO mixing ratio and control the seasonal variabilities of CO in the UTLS, combining the effects of deep convections and monsoons. Results also show a relatively steady emission rate from anthropogenic sources, with a small increase mainly coming from Southeast Asia and lndia. These emis- sions can be transported to the UTLS over Tibet by the joint effort of surface horizontal winds, deep convections, and the Asian summer monsoon system.

Small Scale Refrigerators and Freezers： Thermal Improvements in the Envelope

Like in other sectors of activity, the sustainability in refrigeration systems is a mandatory goal to achieve, namely at house holdings, bars and restaurants, where small-scale refrigerators and freezers are widely used. The aim of this work is to demonstrate experimentally, trough measurements carried out in these equipments, the improvement that can be achieved if several modifications are implemented in traditional household refrigeration systems. In addition, it was also simulated and analysed experimentally a slightly different equipment, a refrigeration system used for draught beverages. Both systems work on a single vapour compression refrigeration with R-134a as working fluid. In the end, by implemented the modifications tested in the virtual model, it was possible to improve their thermal behaviour, a decrease in electrical energy consumption, as well as, the associated CO2 emissions reduction can be attained. In this project, the CFD （Computational Fluid Dynamics） soffware--ANSYS Fluent was used to simulate the ambient temperature and velocity fields inside the refrigerator and in that way to validate the measured results.

Evaluation of the Thermodynamic Performance of the Traditional Passive Systems

The energy consumption of buildings in urban areas is one of the greatest source of energy wasting and, consequently, ofincreasing of CO2 emission. Research is currently focused on the reduction of this consumption through the use of passive air-conditioning systems, that can be integrated with conventional systems and give rise to the so-called hybrid systems. Historically, these passive systems were developed in the Mediterranean and Middle East area. The research approach on this topic involves the application of design strategies and the development of computational tools and control systems. The development of the hybrid systems is the result of the synergy between current scientific knowledge, advanced manufacturing and information technology. In this study, a modular housing system has been investigated under different conditions. Simulations have been repeated, in order to identify the configuration that provides the highest indoor comfort. The analysis of the different conditions has been carried out using a CFD （computational fluid dynamic） software. The paper shows the results developed by the Dipartimento di Architettura of the Universit^t di Palermo in the analysis of the natural ventilation effect on the indoor comfort.

Short-Term Response of Soil Respiration to Addition of Chars:Impact of Fermentation Post-Processing and Mineral Nitrogen

The biodegradability of chars derived from pyrolysis and hydrothermal carbonisation(HTC) was studied in short-term dynamic incubation experiments under controlled conditions. Carbon dioxide C(CO2) emissions from soil-char mixtures in combination with solid digestate or mineral nitrogen(N) fertiliser were measured in dynamic chambers for 10 d. Compared to the original material(maize straw), pyrolysis and HTC chars showed significantly lower CO2 emissions and slower decay dynamics; and compared to the soil control, HTC char increased soil respiration to a significant extent, while pyrolysis char did not. The addition of mineral N resulted in a delayed respiration dynamics for HTC char, while the addition of digestate resulted in an increase in the respired CO2 for pyrolysis char and a decrease for HTC char. For the first time, a peculiar two-stage decay kinetics was observed for HTC char,indicating a highly inhomogeneous substrate consisting at least of two C pools.