The variation of toxic pollutants emission during a feeding cycle was examined by field monitoring from a batch feeding updraft fixed bed gasifier for disposing rural domestic solid waste. Results showed that the cont...The variation of toxic pollutants emission during a feeding cycle was examined by field monitoring from a batch feeding updraft fixed bed gasifier for disposing rural domestic solid waste. Results showed that the content of oxygen in flue gas gradually increased, while SO_2 and HCl in flue gas decreased with time after feeding in a whole feeding cycle. Although large amount of CO was produced during the gasifying, low CO content in flue gas could be obtained after the heat treatment with an electric heating device. The distribution characteristics of dioxin congeners in flue gas indicted the re-synthesis of dioxins after flue gas heating, and the increase of oxygen promoted the synthesis of dioxins. The emission content of dioxins could meet the standard(0.1 ng I-TEQ·m^(-3),GB18458-2014) of China when the oxygen content was controlled below 8.3%. Hence, for a batch feeding gasifier,low oxygen condition should be offered by reducing air intake at the later stage of feeding cycle in order to decrease the re-synthesis of dioxins after the flue gas heating.展开更多
Biomass has a tendency to adsorb mercury from the flue gas emissions from fossil fuel combustion. In this paper, we have established an experimental table of the adsorption of mercury vapor by rice husk ash according ...Biomass has a tendency to adsorb mercury from the flue gas emissions from fossil fuel combustion. In this paper, we have established an experimental table of the adsorption of mercury vapor by rice husk ash according to the method described in the Chinese national standard GB/T 5009.17-1996. The experimental stud)' was made using rice husk ash samples of different types and at different temperatures. The results show that the carbon content of the rice husk ash was 3.81% after treatment for 1 h at 600℃, the mercury removal rate was above 95%, but the adsorption efficiency was below 20% after incineration for 4 h. The adsorption efficiency of rice husk ash treated by H202 or HCI was very low, while the adsorption efficiency was very high when rice husk ash was pyrolytically carbonized or basified by NaOH; the adsorption efficiency ofbasified rice husk ash sample was up to 98.5%. The carbon content of rice husk ash could affect the adsorption of mercury to some degree, but the internal structure of the rice husk ash samples was a more important factor for adsorption.展开更多
The current status and trend of CO2 emission from coal-fired power plants in China are introduced. Main flue gas decarbonization technologies and their prospective of applications in China are discussed in two separat...The current status and trend of CO2 emission from coal-fired power plants in China are introduced. Main flue gas decarbonization technologies and their prospective of applications in China are discussed in two separate parts-capture and sequestration. It is stated that the selection of CO2 capture and sequestration technologies relates closely with the geographical location of power plants, with the destination of CO2 being the key. Further, it is suggested that industrialized test centers or test platforms of national or industrial level should be set up.展开更多
To control contamination of flue gas emission NOx, the author mixcd method of preparing new magnesia base catalyst and researched on denitrificating fine gas by directness catalytic decomposition. Usually removal rate...To control contamination of flue gas emission NOx, the author mixcd method of preparing new magnesia base catalyst and researched on denitrificating fine gas by directness catalytic decomposition. Usually removal rate of NO is regarded on the main evaluation criteria. The author analyzed calcination temperature of catalyzer manufacturing process, the temperature of flue gas desorption tower, bed height and efficiency denitrification of NO concentration. And discussed the result of both denitrate lore-and-aft of FT-IR and XRD. The experiment indicates that magnesia base catalyst is available to directness catalytic decomposition denitrificate flue gas. Through denitrification rate is from 85% to 95%. The ingredient of magnesia base catalyst is made from magnesia, firming agent, addition agent. Height denitration bed was 4 cm- 5 cm, deuitration reaction temperature is 130℃-170℃, through the analyses above, presumed that magnesia base catalyst exist activating of vice, and analyzed this vice preliminarily.展开更多
Black carbon (BC) aerosol, accounting for a minor fraction of atmospheric aerosols, is attracting increased attentio1 due to its impact on air quality, human health, and climate change. Focusing on BC emission reduc...Black carbon (BC) aerosol, accounting for a minor fraction of atmospheric aerosols, is attracting increased attentio1 due to its impact on air quality, human health, and climate change. Focusing on BC emission reduction, this paper give1 a brief introduction to the sources and global distribution of BC. Along with the decrease of BC emissions from sue1 actions as the reduction of global greenhouse gases (GHGs) and regulating local air quality, it also highlights othet BC reduction approaches such as control and improvement of combustion conditions, the elimination of open biomas burning, and the sequestration of BC by biomass pyrolysis. Finally, it is stressed that at this moment there is no enougt reason to push BC reduction into any climate change related negotiations, although BC has been included in some o so-called win-win reduction targets for the quick response to both climate and non-climate appeals.展开更多
To better understand the characteristics of air quality and the relationship between the chemical composition evolution and source variation,an intensive atmospheric campaign was conducted in Tianjin,a megacity of the...To better understand the characteristics of air quality and the relationship between the chemical composition evolution and source variation,an intensive atmospheric campaign was conducted in Tianjin,a megacity of the North China Plain,from 10 February to 6 March 2015.There were 20 days exceeding the threshold value of secondary Chinese Ambient Air Quality Standards for PM2.5(75 μg m-3,daily average over 24 h)during the study period.Five air pollution episodes were selected for investigation.During the pre-holiday pollution episode,NH^+_4,NO^-_3,and SO^(2-)_4 were more abundant,indicating that air pollution was caused by motor vehicle exhaust emissions and coal consumption under unfavorable meteorological conditions.During Chinese Lunar New Year's Eve,widespread use of fireworks resulted in extremely high aerosol concentrations.Firework displays caused increases in K+ and also enrichment of SO^(2-)_4 relative to NO^-_3.The holiday pollution episode was caused by regional transport,characterized by abundant SO^(2-)_4 and NH^+_4.In addition,the aging processes of the particles from fireworks discharge played an important role in the formation of NO-3and SO^(2-)_4.The Lantern Festival episode was characterized by a transition from the enrichment of K+ to secondary inorganic ions(NO^-_3,SO^(2-)_4,and NH^+_4).The results of this study are useful for a detailed understanding of the variation in atmospheric compositions and sources caused by anthropogenic activity,and highlight the importance of controlling intensive fireworks discharge.展开更多
Diesel particulate matter(DPM) is a by-product from operating diesel engines. Since diesel powers are one of the major sources of energy for mobile underground mining equipment, the adverse health effects of DPM are o...Diesel particulate matter(DPM) is a by-product from operating diesel engines. Since diesel powers are one of the major sources of energy for mobile underground mining equipment, the adverse health effects of DPM are of a great concern. This paper used computational fluid dynamics(CFD) method to study the effect of entry inclination on DPM plume distribution in a dead end entry. An upward mining face and a downward mining face were built with a truck and a loader in loading operation close to the face area. A species transport model with incorporated buoyancy effect was used to examine the DPM dispersion pattern for the above steady-state scenarios. High DPM and temperature regions were identified for the two different faces. The model was used to assess the role of auxiliary ventilation in reducing DPM exposures of underground miners working in those entries. In this study, it is suggested to provide local ventilation at least three times of the diesel exhaust rate to be able to lower the average DPM level for the mining upward face. The requirement for local ventilation is much less for the mining downward face. This can provide guidelines for good working practices and selection of diesel emission reduction technologies underground.展开更多
The reasons of introducing cold air into pulverizer are analyzed for boilers with large capacity and high parameters. The temperature rises of the exhaust gas are calculated when varying the amount of the cold air. Th...The reasons of introducing cold air into pulverizer are analyzed for boilers with large capacity and high parameters. The temperature rises of the exhaust gas are calculated when varying the amount of the cold air. The hot primary air heater, a new technology, is developed to eliminate the cold air from the pulverized coal system. The applications, advantages and disadvantages are introduced in detail for the new device and system. It is concluded that introducing cold air into pulverizer is one of the major factors that causes the exhaust gas temperature of boilers with large capacity to be high. The amount of the cold air could be reduced signif icantly, even to zero in some cases by adopting the hot primary air heater, which drops the exhaust gas temperature of the boiler effectively. The hot primary air heater, which could play part roles of the steam-air heater or the hot air recirculation system, could also be used to adjust the exhaust gas temperature within the range of 20 ℃ by controlling the flow rate of the cooling medium. Moreover, the startup period of the steam-air heater or the hot air recirculation system will be shortened, which is a unique advantage of the hot primary air heater among the measures to drop the exhaust gas temperature.展开更多
The district heating company "Rigas siltums" operates biomass fuelled boiler in Riga city. Three systems consisting ofbiomass boilers having a comparatively similar heat capacity and particle abatement units like mu...The district heating company "Rigas siltums" operates biomass fuelled boiler in Riga city. Three systems consisting ofbiomass boilers having a comparatively similar heat capacity and particle abatement units like multicyclons, electrostatic precipitators and flue gas condensers are compared. The main goal of the study is to evaluate the boiler plant as a system where solid particles are both emitted and caught. The results show that, the particulate matter can be efficiently trapped from flue gases by the particle abatement technologies, and the electrostatic precipitator with sufficiently large collection surfaces is able to provide appropriate flue gas treatment of the particulate matter in the biomass boilers also without pre-cleaning of the flue gas in multieyelons.展开更多
This research reports on potentiality in the solar chimney as an exhaust ventilation device through a hypothetical statement that convenient weather conditions exist on sub-humid warm climate to enhance the performanc...This research reports on potentiality in the solar chimney as an exhaust ventilation device through a hypothetical statement that convenient weather conditions exist on sub-humid warm climate to enhance the performance ofa SC (solar chimney), in order to increase ventilation to dissipate metabolic heat from inhabitants of airtight buildings. The methodology used in this research integrates the use of simplified mathematical models that predict in a semi-empirical way a potential volume flow through estimation of kinetic power generation, by natural circulation and stack effect in a typical covered-plate air solar collector. The study was carried out during the warm month of April, an important warm season for Colima, where the prevailing wind is about 6.8 m/s, the average temperature of maximums and minimums oscillates between 15.4℃and 34.4 ℃ with average relative humidity of 65% according to national weather service. A scale model of the SC was installed on environmental chambers. The results showed that this device is capable of generating ventilation conditions around light breeze parameters near between 0.6 m/s and 1.5 m/s width, a better performance at day in 45% approximately than the night values, making ventilation rates up 0.24 ACH (air changes per hour) as average air change rate.展开更多
Emission of carbon dioxide is considered to be the main cause of the greenhouse effect. Mineral carbonation, an important part of the CCS technology, is an attractive option for long-term CO2 sequestration. In this st...Emission of carbon dioxide is considered to be the main cause of the greenhouse effect. Mineral carbonation, an important part of the CCS technology, is an attractive option for long-term CO2 sequestration. In this study, wollastonite was chosen as the feedstock and the feasibility of direct aqueous mineral carbonation in the simulated flue gas was investigated via a series of experimental studies carried in a stirred reactor. X-ray diffraction (XRD), X-ray fluorescence spectroscopy (XRF), ion chro- matography (IC) and thermal decomposition were used to determine the carbonation conversion. The influences of various factors, including reaction temperature, reaction pressure, solution composition, heat-treatment and particle size, were dis- cussed. Concurrently, the effects of SO2 and NO presented in simulated flue gas were also investigated and a possible mecha- nism was used to explain the results. Experimental results show that reaction temperature, reaction pressure and particle size can effectively improve the carbonation reaction. Addition of 0.6 M NaHCO3 was also proved to be beneficial to the reaction and heat-treatment is not needed for wollastonite to get a higher carbonation conversion. Compared with carbonation in puri- fied CO2 gas, CO2 sequestration directly from simulated flue gas by mineral carbonation is suggested to have a certain degree of economic feasibility in the conditions of medium and low-pressure. A highest carbonation conversion of 35.9% is gained on the condition of T=150℃, P=40 bar and PS 〈30 μ in distilled water for 1 h.展开更多
基金Supported by the Science and Technology Planning Project of Guangdong Province,China(2013B090600134)the National Natural Science Foundation of China(51608223)the Fund for Basic Scientific Research Business of Central Institutes of Environmental Protection(PM-zx 703-201602-050)
文摘The variation of toxic pollutants emission during a feeding cycle was examined by field monitoring from a batch feeding updraft fixed bed gasifier for disposing rural domestic solid waste. Results showed that the content of oxygen in flue gas gradually increased, while SO_2 and HCl in flue gas decreased with time after feeding in a whole feeding cycle. Although large amount of CO was produced during the gasifying, low CO content in flue gas could be obtained after the heat treatment with an electric heating device. The distribution characteristics of dioxin congeners in flue gas indicted the re-synthesis of dioxins after flue gas heating, and the increase of oxygen promoted the synthesis of dioxins. The emission content of dioxins could meet the standard(0.1 ng I-TEQ·m^(-3),GB18458-2014) of China when the oxygen content was controlled below 8.3%. Hence, for a batch feeding gasifier,low oxygen condition should be offered by reducing air intake at the later stage of feeding cycle in order to decrease the re-synthesis of dioxins after the flue gas heating.
文摘Biomass has a tendency to adsorb mercury from the flue gas emissions from fossil fuel combustion. In this paper, we have established an experimental table of the adsorption of mercury vapor by rice husk ash according to the method described in the Chinese national standard GB/T 5009.17-1996. The experimental stud)' was made using rice husk ash samples of different types and at different temperatures. The results show that the carbon content of the rice husk ash was 3.81% after treatment for 1 h at 600℃, the mercury removal rate was above 95%, but the adsorption efficiency was below 20% after incineration for 4 h. The adsorption efficiency of rice husk ash treated by H202 or HCI was very low, while the adsorption efficiency was very high when rice husk ash was pyrolytically carbonized or basified by NaOH; the adsorption efficiency ofbasified rice husk ash sample was up to 98.5%. The carbon content of rice husk ash could affect the adsorption of mercury to some degree, but the internal structure of the rice husk ash samples was a more important factor for adsorption.
文摘The current status and trend of CO2 emission from coal-fired power plants in China are introduced. Main flue gas decarbonization technologies and their prospective of applications in China are discussed in two separate parts-capture and sequestration. It is stated that the selection of CO2 capture and sequestration technologies relates closely with the geographical location of power plants, with the destination of CO2 being the key. Further, it is suggested that industrialized test centers or test platforms of national or industrial level should be set up.
文摘To control contamination of flue gas emission NOx, the author mixcd method of preparing new magnesia base catalyst and researched on denitrificating fine gas by directness catalytic decomposition. Usually removal rate of NO is regarded on the main evaluation criteria. The author analyzed calcination temperature of catalyzer manufacturing process, the temperature of flue gas desorption tower, bed height and efficiency denitrification of NO concentration. And discussed the result of both denitrate lore-and-aft of FT-IR and XRD. The experiment indicates that magnesia base catalyst is available to directness catalytic decomposition denitrificate flue gas. Through denitrification rate is from 85% to 95%. The ingredient of magnesia base catalyst is made from magnesia, firming agent, addition agent. Height denitration bed was 4 cm- 5 cm, deuitration reaction temperature is 130℃-170℃, through the analyses above, presumed that magnesia base catalyst exist activating of vice, and analyzed this vice preliminarily.
基金co-supported by China 973 project of MOST(2011CB403401)China Postdoctoral Science Foundation(20080440463,200902157)
文摘Black carbon (BC) aerosol, accounting for a minor fraction of atmospheric aerosols, is attracting increased attentio1 due to its impact on air quality, human health, and climate change. Focusing on BC emission reduction, this paper give1 a brief introduction to the sources and global distribution of BC. Along with the decrease of BC emissions from sue1 actions as the reduction of global greenhouse gases (GHGs) and regulating local air quality, it also highlights othet BC reduction approaches such as control and improvement of combustion conditions, the elimination of open biomas burning, and the sequestration of BC by biomass pyrolysis. Finally, it is stressed that at this moment there is no enougt reason to push BC reduction into any climate change related negotiations, although BC has been included in some o so-called win-win reduction targets for the quick response to both climate and non-climate appeals.
基金supported by the Beijing Natural Science Foundation[grant number 8142034]Strategic Priority Research Program(B)of the Chinese Academy of Sciences[grant numbers XDB0502050 and XDB05030203]
文摘To better understand the characteristics of air quality and the relationship between the chemical composition evolution and source variation,an intensive atmospheric campaign was conducted in Tianjin,a megacity of the North China Plain,from 10 February to 6 March 2015.There were 20 days exceeding the threshold value of secondary Chinese Ambient Air Quality Standards for PM2.5(75 μg m-3,daily average over 24 h)during the study period.Five air pollution episodes were selected for investigation.During the pre-holiday pollution episode,NH^+_4,NO^-_3,and SO^(2-)_4 were more abundant,indicating that air pollution was caused by motor vehicle exhaust emissions and coal consumption under unfavorable meteorological conditions.During Chinese Lunar New Year's Eve,widespread use of fireworks resulted in extremely high aerosol concentrations.Firework displays caused increases in K+ and also enrichment of SO^(2-)_4 relative to NO^-_3.The holiday pollution episode was caused by regional transport,characterized by abundant SO^(2-)_4 and NH^+_4.In addition,the aging processes of the particles from fireworks discharge played an important role in the formation of NO-3and SO^(2-)_4.The Lantern Festival episode was characterized by a transition from the enrichment of K+ to secondary inorganic ions(NO^-_3,SO^(2-)_4,and NH^+_4).The results of this study are useful for a detailed understanding of the variation in atmospheric compositions and sources caused by anthropogenic activity,and highlight the importance of controlling intensive fireworks discharge.
基金financial support provided by the Western US Mining Safety and Health Training & Translation Center by the National Institute for Occupational Safety and Health of America (NIOSH) (No.1R25OH008319)
文摘Diesel particulate matter(DPM) is a by-product from operating diesel engines. Since diesel powers are one of the major sources of energy for mobile underground mining equipment, the adverse health effects of DPM are of a great concern. This paper used computational fluid dynamics(CFD) method to study the effect of entry inclination on DPM plume distribution in a dead end entry. An upward mining face and a downward mining face were built with a truck and a loader in loading operation close to the face area. A species transport model with incorporated buoyancy effect was used to examine the DPM dispersion pattern for the above steady-state scenarios. High DPM and temperature regions were identified for the two different faces. The model was used to assess the role of auxiliary ventilation in reducing DPM exposures of underground miners working in those entries. In this study, it is suggested to provide local ventilation at least three times of the diesel exhaust rate to be able to lower the average DPM level for the mining upward face. The requirement for local ventilation is much less for the mining downward face. This can provide guidelines for good working practices and selection of diesel emission reduction technologies underground.
文摘The reasons of introducing cold air into pulverizer are analyzed for boilers with large capacity and high parameters. The temperature rises of the exhaust gas are calculated when varying the amount of the cold air. The hot primary air heater, a new technology, is developed to eliminate the cold air from the pulverized coal system. The applications, advantages and disadvantages are introduced in detail for the new device and system. It is concluded that introducing cold air into pulverizer is one of the major factors that causes the exhaust gas temperature of boilers with large capacity to be high. The amount of the cold air could be reduced signif icantly, even to zero in some cases by adopting the hot primary air heater, which drops the exhaust gas temperature of the boiler effectively. The hot primary air heater, which could play part roles of the steam-air heater or the hot air recirculation system, could also be used to adjust the exhaust gas temperature within the range of 20 ℃ by controlling the flow rate of the cooling medium. Moreover, the startup period of the steam-air heater or the hot air recirculation system will be shortened, which is a unique advantage of the hot primary air heater among the measures to drop the exhaust gas temperature.
文摘The district heating company "Rigas siltums" operates biomass fuelled boiler in Riga city. Three systems consisting ofbiomass boilers having a comparatively similar heat capacity and particle abatement units like multicyclons, electrostatic precipitators and flue gas condensers are compared. The main goal of the study is to evaluate the boiler plant as a system where solid particles are both emitted and caught. The results show that, the particulate matter can be efficiently trapped from flue gases by the particle abatement technologies, and the electrostatic precipitator with sufficiently large collection surfaces is able to provide appropriate flue gas treatment of the particulate matter in the biomass boilers also without pre-cleaning of the flue gas in multieyelons.
文摘This research reports on potentiality in the solar chimney as an exhaust ventilation device through a hypothetical statement that convenient weather conditions exist on sub-humid warm climate to enhance the performance ofa SC (solar chimney), in order to increase ventilation to dissipate metabolic heat from inhabitants of airtight buildings. The methodology used in this research integrates the use of simplified mathematical models that predict in a semi-empirical way a potential volume flow through estimation of kinetic power generation, by natural circulation and stack effect in a typical covered-plate air solar collector. The study was carried out during the warm month of April, an important warm season for Colima, where the prevailing wind is about 6.8 m/s, the average temperature of maximums and minimums oscillates between 15.4℃and 34.4 ℃ with average relative humidity of 65% according to national weather service. A scale model of the SC was installed on environmental chambers. The results showed that this device is capable of generating ventilation conditions around light breeze parameters near between 0.6 m/s and 1.5 m/s width, a better performance at day in 45% approximately than the night values, making ventilation rates up 0.24 ACH (air changes per hour) as average air change rate.
基金supported by the National Natural Science Foundation of China (Grant Nos. 40972102, 41172140)the National Basic Research Program of China ("973" Project) (Grant No. 2011CB201500)
文摘Emission of carbon dioxide is considered to be the main cause of the greenhouse effect. Mineral carbonation, an important part of the CCS technology, is an attractive option for long-term CO2 sequestration. In this study, wollastonite was chosen as the feedstock and the feasibility of direct aqueous mineral carbonation in the simulated flue gas was investigated via a series of experimental studies carried in a stirred reactor. X-ray diffraction (XRD), X-ray fluorescence spectroscopy (XRF), ion chro- matography (IC) and thermal decomposition were used to determine the carbonation conversion. The influences of various factors, including reaction temperature, reaction pressure, solution composition, heat-treatment and particle size, were dis- cussed. Concurrently, the effects of SO2 and NO presented in simulated flue gas were also investigated and a possible mecha- nism was used to explain the results. Experimental results show that reaction temperature, reaction pressure and particle size can effectively improve the carbonation reaction. Addition of 0.6 M NaHCO3 was also proved to be beneficial to the reaction and heat-treatment is not needed for wollastonite to get a higher carbonation conversion. Compared with carbonation in puri- fied CO2 gas, CO2 sequestration directly from simulated flue gas by mineral carbonation is suggested to have a certain degree of economic feasibility in the conditions of medium and low-pressure. A highest carbonation conversion of 35.9% is gained on the condition of T=150℃, P=40 bar and PS 〈30 μ in distilled water for 1 h.