Vertical profiles of sound speed in the sea can be measured by using laser excited Brillouin scattering. In this paper the dependence of the accuracy of sound speed measurement on the accuracy of the Brillouin shift m...Vertical profiles of sound speed in the sea can be measured by using laser excited Brillouin scattering. In this paper the dependence of the accuracy of sound speed measurement on the accuracy of the Brillouin shift measurement is analyzed. We calculated the maximum detecting depths of sound speed to an accuracy of 1 m/s by lidar with different laser pulse energy, platform altitude, telescope aperture and lidar effective attenuation coefficient. The estimation of sounding ability in the East China Sea is made in some stations. These data can be used in the design of Brillouin Lidar for the China Sea.展开更多
A laser technique based scanning system was employed to make a comprehensive scanning through borehole forunmapped cavity under open pit bench,then the three-dimensional data will be obtained,and these data were used ...A laser technique based scanning system was employed to make a comprehensive scanning through borehole forunmapped cavity under open pit bench,then the three-dimensional data will be obtained,and these data were used for theoreticalanalysis and numerical simulation to analyze the stability of cap rock.Acoustic emission techniques were also adopted to carry outlong term real time rupture monitoring in cap rock.Therefore,a complete safety evaluation system for the cap rock was establishedto ensure safe operation of subsequent blasting processes.The ideal way of eliminating collapse hazard of such cavity is cap rockcaving through deep-hole blasting,thus,two deep-hole blasting schemes named as vertical deep-hole blasting scheme and one-timeraise driving integrated with deep-hole bench blasting scheme were proposed.The vertical deep-hole blasting scheme has moreexplosive consumption,but the relatively simple blasting net work structure can greatly reduce workloads.However,the one-timeraise driving integrated with deep-hole bench blasting scheme can obviously reduce explosive consumption,but the higher technicalrequirements on drilling,explosive charging and blasting network will increase workloads.展开更多
In the early medieval economic and social circumstances religious centers developed in Bihar, which further led to the construction of temples by the rulers as well as by the locally powerful communities. It must be n...In the early medieval economic and social circumstances religious centers developed in Bihar, which further led to the construction of temples by the rulers as well as by the locally powerful communities. It must be noted that these temples were not as gigantic or of great artistic value either as compared to the Buddhist monasteries of contemporary Bihar. The reason behind this was probably the fact that the Buddhist monasteries were built by the state or supported directly by them as well as patronized by the rich business community. On the contrary, few of the Brahamanical structures were getting these advantages and they were having support of the local followers. From the various excavation and exploration reports by archaeologists, temple structures of this period have been reported very often. But the ancient historiography of Bihar obsessed with the Buddhist, Jaina and other heterodox monuments, has tended to just ignore it. The question why such a large number of temples came up during this period, which is spread over the whole of modem Bihar, particularly near the important Buddhist sites, was never posed. Moreover, the question why the Pala rulers who were known for their Buddhist inclination later extended critical support to Brahmans has also remained unaddressed.展开更多
Large oilfields are often coincidentally located in major river deltas and wetlands,and potentially damage the structure,function and ecosystem service values of wetlands during oil exploration.In the present study,th...Large oilfields are often coincidentally located in major river deltas and wetlands,and potentially damage the structure,function and ecosystem service values of wetlands during oil exploration.In the present study,the effects of crude oil contamination during oil exploration on soil physical and chemical properties were investigated in marshes of the Momoge National Nature Reserve in Jilin Province,China.The concentrations of total petroleum hydrocarbons in the marsh soil near the oil wells are significantly higher than those in the adjacent control marsh.Soil water contents in oil-contaminated marshes are negatively correlated with soil temperature and are significantly lower than those in the control area,especially in fall.Crude oil contamination significantly increases the soil pH up to8.0,and reduces available phosphorus concentrations in the soil.The concentrations of total organic carbon are significantly different among sampling sites.Therefore,crude oil contamination could potentially alkalinize marsh soils,adversely affect soil fertility and physical properties,and cause deterioration of the marshes in the Momoge National Nature Reserve.Phyto-remediation by planting Calamagrostis angustifolia has the potential to simultaneously restore and remediate the petroleum hydrocarbon-contaminated wetlands.Crude oil contamination affects the soil physical and chemical properties,so developing an effective restoration program in the Momoge wetland is neccesary.展开更多
The goal of the present paper is to expand already published works in the frame of"Banded speed cosmology" (BSC). In particular this paper gives validated values for physical quantities not so far investigated in ...The goal of the present paper is to expand already published works in the frame of"Banded speed cosmology" (BSC). In particular this paper gives validated values for physical quantities not so far investigated in previous publications, i.e., the number of individual physical entity in the universe, as well as the maximum value for acceleration. Validates values mean identical quantities from a numerical point of view obtained with different theoretical procedures, additionally compared with data based on NASA observations with Planck probe.展开更多
Nomenclatures for lunar features always accompany the progresses of human lunar exploration,which has an important dual meaning in culture and science. The naming of lunar features not only can commemorate the outstan...Nomenclatures for lunar features always accompany the progresses of human lunar exploration,which has an important dual meaning in culture and science. The naming of lunar features not only can commemorate the outstanding contributions of academics,masters in various fields, and popularize the traditional cultures of ethnic groups all over the world, but also have a critical function of providing accurate indicative information on features with special morphology, origin, nature and scientific value. However, nomenclature for features at the Chang'e-3 landing site, which has a more arbitrary form without many constrains posed by a uniformed system, is unlike the features for other morphological units.This paper originated from the actual needs for the description of scientific exploration activities, interpretation of scientific research and dissemination of scientific results. Some prominent morphological units with great scientific importance and identification purpose were chosen from the images taken by the terrain camera, panorama cameras and landing camera onboard the Chang'e lander and Yutu rover. A nomenclature system was established under the three enclosures, four quadrants and twenty-eight lunar lodges' system of the Chinese ancient sky division method. Finally, a standard feature names set waspublished after some necessary approval procedures by the International Astronomical Union.展开更多
High-density resistivity method is a new, efficient electrical prospecting method, which can complete a two-dimensional (vertical and horizontal) prospecting process, possesses certain imaging functions for the geo-...High-density resistivity method is a new, efficient electrical prospecting method, which can complete a two-dimensional (vertical and horizontal) prospecting process, possesses certain imaging functions for the geo-electric structure, and integrates electric profiling method with electric sounding method together. In this paper, the basic principle, data processing, and result explanation and inference of high- density resistivity method are introduced by taking the application of high-density resistivity method to the prospecting project in the slope of Gongchangling Open Pit, Liaoyang. The result of the prospecting result map analysis showed that the prospecting result was basically in line with the actual situation and proved the great significance of high-density resistivity method to the evaluation on the slope stability of Gongchangling open pit.展开更多
Marine controlled source electromagnetic signal could be used in mineral resource exploration,reservoir appraisal and communicative technique in ocean. It's necessary to study the electromagnetic generated by MCSE...Marine controlled source electromagnetic signal could be used in mineral resource exploration,reservoir appraisal and communicative technique in ocean. It's necessary to study the electromagnetic generated by MCSEM. The propagation of the electromagnetic fields from a controlled source in the marine environment was studied with virtual interface method combined with discrete complex image method. Transmitter of finite length current source is approximated by dipole (HED) . A three-layered model is accepted,with sea water as intermediate conductive layer under air and a relatively high resistive seabed as basement,possibly containing a hydrogen layer of higher resistivity. The electromagnetic fields in whole space thus computed show that: (1) the spatial distribution of field component depends on its type; (2) inline Ex component is more sensitive to reservoir layer than that in broadside; (3) The airwave affects marine electromagnetic (MEM) exploration when sea water is relatively shallow; in the case of deep water MEM exploration,the airwave influence could be neglected; and (4) an appropriate frequency should be selected in order to balance the signal strength and electromagnetic induction effect.展开更多
The spatial variability of geotechnical earthquake engineering critical parameters obtained by laboratory and in situ tests in the same area is affected by different measurements. The paper provides a brief synthesis ...The spatial variability of geotechnical earthquake engineering critical parameters obtained by laboratory and in situ tests in the same area is affected by different measurements. The paper provides a brief synthesis of ground motion and site effects analysis procedures within a Performance-Based Design framework. In particular it focuses about the influence on the evaluation of site effects in some active regions by different shear waves velocity measurements (Down Hole D-H and Seismic Dilatometer Marchetti Test SDMT). Moreover the variation of shear modulus and damping ratio with strain level and depth from different laboratory dynamic or cyclic tests for soil characterisation (Resonant Column Test RCT) was evaluated. The available data enabled one to compare the shear waves velocity profile obtained by laboratory and in situ tests (Cone Penetration Tests CPT) with empirical correlations proposed in literature.展开更多
According to the results of estimation of the maximum potential earthquake in the project of "The Active Fault Detection and Seismic Risk Evaluation (Phase H) of Zhengzhou City", the near east-west trending Laoyac...According to the results of estimation of the maximum potential earthquake in the project of "The Active Fault Detection and Seismic Risk Evaluation (Phase H) of Zhengzhou City", the near east-west trending Laoyachen fault and Shangjie fault are developed in the urban area. The Laoyachen fault was not active in the Quaternary, but the Shangjie fault may have the potential of generating M5.0 - 5.5 earthquakes. In order to get the probability of occurrence of maximum potential earthquakes, we delineate the statistical areas and the potential source areas and calculate the seismicity parameters and the space distribution functions. Our study shows that the probability of occurrence of an earthquake with M〉 5.0 on the faults in Zhengzhou city is 6% in the next 50 years and 11% in the next 100 years.展开更多
It is important for the determination of biologically and/or environmentally relevant species by utilization of fluorescent probes. Conventional fluorescent probes are subjected to the influence of aggregation-caused ...It is important for the determination of biologically and/or environmentally relevant species by utilization of fluorescent probes. Conventional fluorescent probes are subjected to the influence of aggregation-caused quenching that is limiting their application due to low selectivity as well as photobleaching. Additionally, quencher pairs are usually introduced in the design of these probes, which lead to the complex synthetic procedure. A novel class of fluorogens with aggregation-induced emission (AIE) characteristic provide a solution to address the dilemma. By taking advantage of the unique characteristic of AIE fluorogens, specific turn-on probes have been developed via combination with recognition components, exhibiting low background, good selectivity and outstanding photostability. This review focuses on the development of fluorescent probes with AIE characteristics via the bond cleavage as well as formation strategy.展开更多
The Unified S-Band (USB) ranging/Doppler system and the Very Long Baseline Interferometry (VLBI) system as the ground tracking system jointly supported the lunar orbit capture of both Chang'E-2 (CE-2) and Chang...The Unified S-Band (USB) ranging/Doppler system and the Very Long Baseline Interferometry (VLBI) system as the ground tracking system jointly supported the lunar orbit capture of both Chang'E-2 (CE-2) and Chang'E-1 (CE-1) missions. The tracking system is also responsible for providing precise orbits for scientific data processing. New VLBI equipment and data processing strategies have been proposed based on CE-1 experiences and implemented for CE-2. In this work the role VLBI tracking data played was reassessed through precision orbit determination (POD) experiments for CE-2. Significant improve- ment in terms of both VLBI delay and delay rate data accuracy was achieved with the noise level of X-band band-width syn- thesis delay data reaching 0.2-0.3 ns. Short-arc orbit determination experiments showed that the combination of only 15 min's range and VLBI data was able to improve the accuracy of 3 h's orbit using range data only by a 1-1.5 order of magnitude, confirming a similar conclusion for CE-1. Moreover, because of the accuracy improvement, VLBI data was able to contribute to CE-2's long-arc POD especially in the along-track and orbital normal directions. Orbital accuracy was assessed through the orbital overlapping analysis (2 h arc overlapping for 18 h POD arc). Compared with about 100 m position error of CE-l's 200 kin x 200 km lunar orbit, for CE-2's 100 km x 100 km lunar orbit, the position errors were better than 31 and 6 m in the radial direction, and for CE-2's 15 km^100 km orbit, the position errors were better than 45 and 12 m in the radial direction. In addi- tion, in trying to analyze the Delta Differential One-Way Ranging (ADOR) experiments data we concluded that the accuracy of ADOR delay was dramatically improved with the noise level better than 0.1 ns and systematic errors better calibrated, and the Short-arc POD tests with ADOR data showed excellent results. Although unable to support the development of an independent lunar gravity model, the tracking data of CE-2 provided evaluations of different lunar gravity models through POD. It is found that for the 100 km x 100 km lunar orbit, with a degree and order expansion up to 165, JPL's gravity model LP165P did not show noticeable improvement over Japan's SGM series models (100x100), but for the 15 kmxl00 km lunar orbit, a higher de- gree-order model can significantly improve the orbit accuracy.展开更多
Energy saving is the crucial task of green architecture,energy-saving design and evaluation should be interactive.Low Energy Certificate(LEC),an interactive computer program for energy efficiency and certification of ...Energy saving is the crucial task of green architecture,energy-saving design and evaluation should be interactive.Low Energy Certificate(LEC),an interactive computer program for energy efficiency and certification of building envelope,is briefly introduced in this paper in aspects of certification standards,procedure,methods etc.Through the evaluation report of Innovation-pavilion PoI features,reference values of LEC are presented.展开更多
Binding of fluorescent molecules to the porous matrix through noncovalent interactions will synergistically expand their application spectrum. In this regard, we report an integrative self-assembly of molecule 1 with ...Binding of fluorescent molecules to the porous matrix through noncovalent interactions will synergistically expand their application spectrum. In this regard, we report an integrative self-assembly of molecule 1 with benzothiadizole and 9,9-dihexyl fluorene units, and covalent organic frameworks(COFs) via an emulsion-modulated polymerization process, within which molecules of 1 are able to interact with the scaffolds of COFs through CH-π interactions. Thus the π-πinteractions between the fluorescent molecules are largely suppressed, giving rise to their remarkable monomer-like optical properties. Of particular interest is that, given by the specific interaction between COFs and a nerve agent simulant diethyl chlorophosphite(DCP), these assembled composites show the ability of ultrasensitive detection of DCP with a detection limit of ~40 ppb. Moreover, the present integrative assembly strategy can be extended to encapsulate multiple fluorescent molecules, enabling the assemblies with white light emission. Our results highlight opportunities for the development of highly emissive porous materials by molecular selfassembly of fluorophores and molecular units of COFs.展开更多
A plant is stabilized by its root system. In congested urban cities such as Hong Kong, ground trenching is frequently seen due to the installation of utility lines along the roadside. Soil nailing, which involves soil...A plant is stabilized by its root system. In congested urban cities such as Hong Kong, ground trenching is frequently seen due to the installation of utility lines along the roadside. Soil nailing, which involves soil coring in slopes, is a common solution to improve the slope stability. However, both activities inevitably pose a risk to the integrity of any root sys- tems present, and thus reduce the root anchorage. To prevent or minimize such damage, a careful design of the excava- tion/drilling location is of prime importance. Ground penetrating radar (GPR) provides a non-destructive method for locating roots by examining the contrast between the dielectric properties of the roots and the surrounding soil. To examine the perfor- mance of GPR and promote its use in Hong Kong, a test bed was prepared using local materials to create a controlled envi- ronment in which to conduct a series of systematic tests evaluating the performance of a 900 MHz GPR. The reflected radar- grams were subject to the influence of the following factors: size and depth of roots, horizontal distance between roots, and contrast between the root and soil water content. Correlations between root size and a number of waveform parameters were also explored. Limiting values for root size, root embedded depth, horizontal separation distance between roots, and water content contrast between root and soil were obtained. A significant correlation was found between the root diameter and time travel parameter T2 (p〈0.001, t=0.795). Because GPR root detection is highly site-specific, this study provides a local refer- ence for GPR performance in the Hong Kong environment. The findings demonstrate that the 900 MHz GPR is applicable in Hong Kong for the detection of main roots.展开更多
文摘Vertical profiles of sound speed in the sea can be measured by using laser excited Brillouin scattering. In this paper the dependence of the accuracy of sound speed measurement on the accuracy of the Brillouin shift measurement is analyzed. We calculated the maximum detecting depths of sound speed to an accuracy of 1 m/s by lidar with different laser pulse energy, platform altitude, telescope aperture and lidar effective attenuation coefficient. The estimation of sounding ability in the East China Sea is made in some stations. These data can be used in the design of Brillouin Lidar for the China Sea.
基金Projects(51204206,41272304,41372278) supported by the National Natural Science Foundation of China
文摘A laser technique based scanning system was employed to make a comprehensive scanning through borehole forunmapped cavity under open pit bench,then the three-dimensional data will be obtained,and these data were used for theoreticalanalysis and numerical simulation to analyze the stability of cap rock.Acoustic emission techniques were also adopted to carry outlong term real time rupture monitoring in cap rock.Therefore,a complete safety evaluation system for the cap rock was establishedto ensure safe operation of subsequent blasting processes.The ideal way of eliminating collapse hazard of such cavity is cap rockcaving through deep-hole blasting,thus,two deep-hole blasting schemes named as vertical deep-hole blasting scheme and one-timeraise driving integrated with deep-hole bench blasting scheme were proposed.The vertical deep-hole blasting scheme has moreexplosive consumption,but the relatively simple blasting net work structure can greatly reduce workloads.However,the one-timeraise driving integrated with deep-hole bench blasting scheme can obviously reduce explosive consumption,but the higher technicalrequirements on drilling,explosive charging and blasting network will increase workloads.
文摘In the early medieval economic and social circumstances religious centers developed in Bihar, which further led to the construction of temples by the rulers as well as by the locally powerful communities. It must be noted that these temples were not as gigantic or of great artistic value either as compared to the Buddhist monasteries of contemporary Bihar. The reason behind this was probably the fact that the Buddhist monasteries were built by the state or supported directly by them as well as patronized by the rich business community. On the contrary, few of the Brahamanical structures were getting these advantages and they were having support of the local followers. From the various excavation and exploration reports by archaeologists, temple structures of this period have been reported very often. But the ancient historiography of Bihar obsessed with the Buddhist, Jaina and other heterodox monuments, has tended to just ignore it. The question why such a large number of temples came up during this period, which is spread over the whole of modem Bihar, particularly near the important Buddhist sites, was never posed. Moreover, the question why the Pala rulers who were known for their Buddhist inclination later extended critical support to Brahmans has also remained unaddressed.
基金Under the auspices of National Natural Science Foundation of China(No.31170476)Chinese Academy of Sciences/State Administration of Foreign Experts Affairs International Partnership Program for Creative Research Teams(No.KZZD-EW-TZ-07)+1 种基金Major Program of Science and Technology of Jilin Province(No.20075014)Fundamental Research Funds for the Central Universities of China(No.11GJHZ002)
文摘Large oilfields are often coincidentally located in major river deltas and wetlands,and potentially damage the structure,function and ecosystem service values of wetlands during oil exploration.In the present study,the effects of crude oil contamination during oil exploration on soil physical and chemical properties were investigated in marshes of the Momoge National Nature Reserve in Jilin Province,China.The concentrations of total petroleum hydrocarbons in the marsh soil near the oil wells are significantly higher than those in the adjacent control marsh.Soil water contents in oil-contaminated marshes are negatively correlated with soil temperature and are significantly lower than those in the control area,especially in fall.Crude oil contamination significantly increases the soil pH up to8.0,and reduces available phosphorus concentrations in the soil.The concentrations of total organic carbon are significantly different among sampling sites.Therefore,crude oil contamination could potentially alkalinize marsh soils,adversely affect soil fertility and physical properties,and cause deterioration of the marshes in the Momoge National Nature Reserve.Phyto-remediation by planting Calamagrostis angustifolia has the potential to simultaneously restore and remediate the petroleum hydrocarbon-contaminated wetlands.Crude oil contamination affects the soil physical and chemical properties,so developing an effective restoration program in the Momoge wetland is neccesary.
文摘The goal of the present paper is to expand already published works in the frame of"Banded speed cosmology" (BSC). In particular this paper gives validated values for physical quantities not so far investigated in previous publications, i.e., the number of individual physical entity in the universe, as well as the maximum value for acceleration. Validates values mean identical quantities from a numerical point of view obtained with different theoretical procedures, additionally compared with data based on NASA observations with Planck probe.
基金provided by National Major Projects-GRAS Construction of China Lunar Exploration Project
文摘Nomenclatures for lunar features always accompany the progresses of human lunar exploration,which has an important dual meaning in culture and science. The naming of lunar features not only can commemorate the outstanding contributions of academics,masters in various fields, and popularize the traditional cultures of ethnic groups all over the world, but also have a critical function of providing accurate indicative information on features with special morphology, origin, nature and scientific value. However, nomenclature for features at the Chang'e-3 landing site, which has a more arbitrary form without many constrains posed by a uniformed system, is unlike the features for other morphological units.This paper originated from the actual needs for the description of scientific exploration activities, interpretation of scientific research and dissemination of scientific results. Some prominent morphological units with great scientific importance and identification purpose were chosen from the images taken by the terrain camera, panorama cameras and landing camera onboard the Chang'e lander and Yutu rover. A nomenclature system was established under the three enclosures, four quadrants and twenty-eight lunar lodges' system of the Chinese ancient sky division method. Finally, a standard feature names set waspublished after some necessary approval procedures by the International Astronomical Union.
文摘High-density resistivity method is a new, efficient electrical prospecting method, which can complete a two-dimensional (vertical and horizontal) prospecting process, possesses certain imaging functions for the geo-electric structure, and integrates electric profiling method with electric sounding method together. In this paper, the basic principle, data processing, and result explanation and inference of high- density resistivity method are introduced by taking the application of high-density resistivity method to the prospecting project in the slope of Gongchangling Open Pit, Liaoyang. The result of the prospecting result map analysis showed that the prospecting result was basically in line with the actual situation and proved the great significance of high-density resistivity method to the evaluation on the slope stability of Gongchangling open pit.
基金Supperted by project of the National Science Foundation of China(No.40874050)
文摘Marine controlled source electromagnetic signal could be used in mineral resource exploration,reservoir appraisal and communicative technique in ocean. It's necessary to study the electromagnetic generated by MCSEM. The propagation of the electromagnetic fields from a controlled source in the marine environment was studied with virtual interface method combined with discrete complex image method. Transmitter of finite length current source is approximated by dipole (HED) . A three-layered model is accepted,with sea water as intermediate conductive layer under air and a relatively high resistive seabed as basement,possibly containing a hydrogen layer of higher resistivity. The electromagnetic fields in whole space thus computed show that: (1) the spatial distribution of field component depends on its type; (2) inline Ex component is more sensitive to reservoir layer than that in broadside; (3) The airwave affects marine electromagnetic (MEM) exploration when sea water is relatively shallow; in the case of deep water MEM exploration,the airwave influence could be neglected; and (4) an appropriate frequency should be selected in order to balance the signal strength and electromagnetic induction effect.
文摘The spatial variability of geotechnical earthquake engineering critical parameters obtained by laboratory and in situ tests in the same area is affected by different measurements. The paper provides a brief synthesis of ground motion and site effects analysis procedures within a Performance-Based Design framework. In particular it focuses about the influence on the evaluation of site effects in some active regions by different shear waves velocity measurements (Down Hole D-H and Seismic Dilatometer Marchetti Test SDMT). Moreover the variation of shear modulus and damping ratio with strain level and depth from different laboratory dynamic or cyclic tests for soil characterisation (Resonant Column Test RCT) was evaluated. The available data enabled one to compare the shear waves velocity profile obtained by laboratory and in situ tests (Cone Penetration Tests CPT) with empirical correlations proposed in literature.
基金sponsored by the Seismic Risk Assessment of Active Fault in Key Monitoring Prevention Area of China
文摘According to the results of estimation of the maximum potential earthquake in the project of "The Active Fault Detection and Seismic Risk Evaluation (Phase H) of Zhengzhou City", the near east-west trending Laoyachen fault and Shangjie fault are developed in the urban area. The Laoyachen fault was not active in the Quaternary, but the Shangjie fault may have the potential of generating M5.0 - 5.5 earthquakes. In order to get the probability of occurrence of maximum potential earthquakes, we delineate the statistical areas and the potential source areas and calculate the seismicity parameters and the space distribution functions. Our study shows that the probability of occurrence of an earthquake with M〉 5.0 on the faults in Zhengzhou city is 6% in the next 50 years and 11% in the next 100 years.
基金supported by the National Natural Science Foundation of China(21525523,21722507,21574048 and21874121)the National Basic Research Program of China(973 Program,2015CB932600)+1 种基金the National Key R&D Program of China(2017YFA0208000 and 2016YFF0100800)the Natural Science Foundation of Zhejiang Province of China(LY18B050002)
文摘It is important for the determination of biologically and/or environmentally relevant species by utilization of fluorescent probes. Conventional fluorescent probes are subjected to the influence of aggregation-caused quenching that is limiting their application due to low selectivity as well as photobleaching. Additionally, quencher pairs are usually introduced in the design of these probes, which lead to the complex synthetic procedure. A novel class of fluorogens with aggregation-induced emission (AIE) characteristic provide a solution to address the dilemma. By taking advantage of the unique characteristic of AIE fluorogens, specific turn-on probes have been developed via combination with recognition components, exhibiting low background, good selectivity and outstanding photostability. This review focuses on the development of fluorescent probes with AIE characteristics via the bond cleavage as well as formation strategy.
基金supported by the National Natural Science Foundation of China (Grant Nos. 10703011 and11073047)the Science and Technology Commission of Shanghai (GrantNo. 06DZ22101)the National High Technology Research and Development Program of China (Grant No. 2010AA122202)
文摘The Unified S-Band (USB) ranging/Doppler system and the Very Long Baseline Interferometry (VLBI) system as the ground tracking system jointly supported the lunar orbit capture of both Chang'E-2 (CE-2) and Chang'E-1 (CE-1) missions. The tracking system is also responsible for providing precise orbits for scientific data processing. New VLBI equipment and data processing strategies have been proposed based on CE-1 experiences and implemented for CE-2. In this work the role VLBI tracking data played was reassessed through precision orbit determination (POD) experiments for CE-2. Significant improve- ment in terms of both VLBI delay and delay rate data accuracy was achieved with the noise level of X-band band-width syn- thesis delay data reaching 0.2-0.3 ns. Short-arc orbit determination experiments showed that the combination of only 15 min's range and VLBI data was able to improve the accuracy of 3 h's orbit using range data only by a 1-1.5 order of magnitude, confirming a similar conclusion for CE-1. Moreover, because of the accuracy improvement, VLBI data was able to contribute to CE-2's long-arc POD especially in the along-track and orbital normal directions. Orbital accuracy was assessed through the orbital overlapping analysis (2 h arc overlapping for 18 h POD arc). Compared with about 100 m position error of CE-l's 200 kin x 200 km lunar orbit, for CE-2's 100 km x 100 km lunar orbit, the position errors were better than 31 and 6 m in the radial direction, and for CE-2's 15 km^100 km orbit, the position errors were better than 45 and 12 m in the radial direction. In addi- tion, in trying to analyze the Delta Differential One-Way Ranging (ADOR) experiments data we concluded that the accuracy of ADOR delay was dramatically improved with the noise level better than 0.1 ns and systematic errors better calibrated, and the Short-arc POD tests with ADOR data showed excellent results. Although unable to support the development of an independent lunar gravity model, the tracking data of CE-2 provided evaluations of different lunar gravity models through POD. It is found that for the 100 km x 100 km lunar orbit, with a degree and order expansion up to 165, JPL's gravity model LP165P did not show noticeable improvement over Japan's SGM series models (100x100), but for the 15 kmxl00 km lunar orbit, a higher de- gree-order model can significantly improve the orbit accuracy.
文摘Energy saving is the crucial task of green architecture,energy-saving design and evaluation should be interactive.Low Energy Certificate(LEC),an interactive computer program for energy efficiency and certification of building envelope,is briefly introduced in this paper in aspects of certification standards,procedure,methods etc.Through the evaluation report of Innovation-pavilion PoI features,reference values of LEC are presented.
基金supported by the National Natural Science Foundation of China (21703120,21972076,51903140 and 21925604)China Postdoctoral Science Foundation (2019M662324)Taishan Scholars Program of Shandong Province (tsqn201812011)。
文摘Binding of fluorescent molecules to the porous matrix through noncovalent interactions will synergistically expand their application spectrum. In this regard, we report an integrative self-assembly of molecule 1 with benzothiadizole and 9,9-dihexyl fluorene units, and covalent organic frameworks(COFs) via an emulsion-modulated polymerization process, within which molecules of 1 are able to interact with the scaffolds of COFs through CH-π interactions. Thus the π-πinteractions between the fluorescent molecules are largely suppressed, giving rise to their remarkable monomer-like optical properties. Of particular interest is that, given by the specific interaction between COFs and a nerve agent simulant diethyl chlorophosphite(DCP), these assembled composites show the ability of ultrasensitive detection of DCP with a detection limit of ~40 ppb. Moreover, the present integrative assembly strategy can be extended to encapsulate multiple fluorescent molecules, enabling the assemblies with white light emission. Our results highlight opportunities for the development of highly emissive porous materials by molecular selfassembly of fluorophores and molecular units of COFs.
基金the Research Grants Council of the Hong Kong Special Administrative Region (HKSAR) (Grant Nos. HKUST9/CRF/ 09, HKUST6/CRF/12R)
文摘A plant is stabilized by its root system. In congested urban cities such as Hong Kong, ground trenching is frequently seen due to the installation of utility lines along the roadside. Soil nailing, which involves soil coring in slopes, is a common solution to improve the slope stability. However, both activities inevitably pose a risk to the integrity of any root sys- tems present, and thus reduce the root anchorage. To prevent or minimize such damage, a careful design of the excava- tion/drilling location is of prime importance. Ground penetrating radar (GPR) provides a non-destructive method for locating roots by examining the contrast between the dielectric properties of the roots and the surrounding soil. To examine the perfor- mance of GPR and promote its use in Hong Kong, a test bed was prepared using local materials to create a controlled envi- ronment in which to conduct a series of systematic tests evaluating the performance of a 900 MHz GPR. The reflected radar- grams were subject to the influence of the following factors: size and depth of roots, horizontal distance between roots, and contrast between the root and soil water content. Correlations between root size and a number of waveform parameters were also explored. Limiting values for root size, root embedded depth, horizontal separation distance between roots, and water content contrast between root and soil were obtained. A significant correlation was found between the root diameter and time travel parameter T2 (p〈0.001, t=0.795). Because GPR root detection is highly site-specific, this study provides a local refer- ence for GPR performance in the Hong Kong environment. The findings demonstrate that the 900 MHz GPR is applicable in Hong Kong for the detection of main roots.