热循环、腐蚀和自然时效对2024铝合金搅拌摩擦焊接头力学性能的影响

研究了焊接过程中热循环、焊后腐蚀和自然时效对2024铝合金搅拌摩擦焊(FSW)接头力学性能的影响。结果表明,同一焊缝不同位置的力学性能存在一定的差异,靠近插入点位置的屈服强度和抗拉强度明显低于其他位置,之后不断升高,趋于稳定,屈服强度和抗拉强度的最大值分别约为310 MPa和415 MPa;随着自然时效时间的增加,接头屈服强度和抗拉强度在前2个月增长较快,增长率最大分别为2%和1.5%,之后趋于稳定,而伸长率的增长率先较快,增长率最大为6%,之后变缓;在不同的自然时效时间下,腐蚀均明显降低2024铝合金FSW接头的屈服强度、抗拉强度和伸长率,减小率的最大值分别为6.5%,6.1%和19.8%;随着自然时效时间的增加,腐蚀后接头的力学性能下降更严重。

铜基纳米复合减摩涂料在抗腐蚀油套管螺纹接头上的应用

将高度浓缩纳米铜悬浮液与聚四氟乙烯颗粒按适当比例混合,并以特种聚丙烯酸树脂为主要黏结剂,制备出铜基纳米复合减摩涂料。将该复合减摩涂料用于N80S、P110S、TP95TS三种材质的抗腐蚀油套管接头,并在工厂进行标准全尺寸上卸扣试验。试验结果表明:卸扣后螺纹表面未出现任何明显的螺纹黏结划伤;接箍表面经该减摩涂料处理可有效提高其螺纹接头的抗黏结性能,使其达到与镀铜相当的良好效果。

基于电化学方法5Cr钢熔化焊接头CO_2腐蚀行为

为了获得5Cr钢熔化焊焊接接头的动态腐蚀特性,采用基于电极电位的电化学方法进行5Cr钢焊接接头耐CO_2腐蚀行为的研究,建立了基于极化曲线下的腐蚀模型,研究了不同填充材料的焊接接头的耐腐蚀性.研究发现,在温度为40℃,CO_2分压为10个大气压等加速腐蚀条件下,低铬焊丝的焊缝区域的自腐蚀电位最正,腐蚀速率最小,高铬焊丝的焊缝区域的自腐蚀电位较正,腐蚀速率较小,无铬焊丝的焊缝自腐蚀电位最负,腐蚀速率最大.对比只反应腐蚀前后质量变化的失重法,电化学方法反映了腐蚀周期任一时刻的动态腐蚀速率,基于电化学腐蚀模型下的腐蚀速率与失重法测量结果相吻合.验证了电化学腐蚀模型的正确性.结果表明,低铬钢匹配适当的低铬焊丝可使得焊接接头具有较强的耐CO_2腐蚀性能.

304L/SA516Gr70不锈钢复合板焊接接头的耐蚀性研究

采用化学浸泡和电化学腐蚀测试技术,研究分别采用ER316L和ER309L焊丝作为过渡层填充材料焊接获得的304L/SA516Gr70不锈钢复合板接头的耐点蚀性能。结果表明,两种接头在质量分数5%FeCl3溶液和质量分数10%FeCl3溶液中的腐蚀速率都很小,未发生明显的点蚀现象。在质量分数15%FeCl3溶液中,ER316L接头的腐蚀速率要小于ER309L接头,且通过显微镜观察发现其腐蚀坑大小也明显小于ER309L接头。室温下,在质量分数3.5%NaCl溶液中几种接头和304L母材的自腐蚀电流大小顺序依次为:ER309L接头>ER316L接头>304L母材,两种接头的耐点蚀性能只略低于304L母材,能够满足工程结构对复合板接头的耐蚀性要求。

HT—L系统甲醇氨冷器泄漏返修方案及处理措施

摘要：针对HT—L系统的氨冷器U形管、管板接头处出现泄漏的问题，采取相应的返修方案和补漏措施，对u形管进行若干堵头堵漏和对管板接头坑蚀情况进行焊接等措施，有效地解决设备泄漏的问题。

DJB－823C电力电接点保护剂

介绍了一种电力电接点保护剂，它可以有效缓解供变电系统电接头温升超值现象，实用效果良好。

Electrochemical corrosion of Sn-0.75Cu solder joints in NaCl solution

The corrosion behaviors of Sn-0.75Cu solder and Sn-0.75Cu/Cu joint in 3.5% NaCl（mass fraction） solution were studied by potentiodynamic polarization test and leaching measurement.The polarization curves indicated that the corrosion rate of Sn-0.75Cu solder was lower than that of Sn-0.75Cu/Cu joint.The morphology observation and phase composition analysis on the corroded product at each interesting potential suggested that Sn3O（OH）2Cl2 formed on the surface of Sn-0.75Cu solder at active dissolution stage.As the potential increased from active/passive transition stage,all the surface of Sn-0.75Cu solder was covered by the Sn3O（OH）2Cl2 and some pits appeared after the polarization test.Compared to the Sn-0.75Cu solder alloy,much more Sn3O（OH）2Cl2 formed at active dissolution stage and the pits with bigger size were observed after polarization test for the Sn-0.75Cu/Cu solder joints.The leaching test confirmed that the faster electrochemical corrosion rate resulted in the larger amount of Sn released from the Sn-0.75Cu/Cu solder joints.

Corrosion fatigue crack growth mechanisms in welded joints of marine steel structures

This paper presents a model of fatigue crack growth in a welded joint and a two-dimensional model of anodic dissolution based on Donahue model and anodic dissolution mechanism,respectively.In addition,a model for predicting the corrosion fatigue crack growth rate in welded joints of steel marine structures is established and crack growth mechanisms are analyzed.The results show that during early stages of crack growth,corrosion fatigue crack growth rate in welded joints is mainly controlled by corrosion action,whereas cyclic loading becomes more influential during the later stage of crack propagation.Loading frequency and effective stress ratio can affect rupture period of protective film at the corrosion fatigue crack tip and the length of corrosion crack increment,respectively,which changes the influence of corrosion action on crack growth rate.However,the impact of stress amplitude on crack growth rate is only significant when crack propagation is caused by cyclic loading.Welding residual stress not only improves the effective stress ratio of cyclic loading,but also promotes crack closure and increases corrosion fatigue crack growth rate in welded joints.Compared to corrosion action,welding residual stress has a more significant influence on crack growth caused by cyclic loading.

Electrochemical corrosion behaviour of stir zone of friction stir welded dissimilar joints of AA6061 aluminium-AZ31B magnesium alloys

Joining of dissimilar metals will offer many advantages in transportation sectors such as fuel consumption,weightreduction and emission reduction.However,joining of aluminium(Al)alloys with magnesium(Mg)alloys by fusion welding processis very complicated.Friction stir welding(FSW)is a feasible method to join these two dissimilar alloys.Mixing these two metalstogether in stir zone(SZ)leads to poor corrosion resistance.In this investigation,an attempt has been made to understand thecorrosion resistance of SZ of FSWed dissimilar joints of AA6061Al alloy and AZ31B Mg alloy.Potentiodynamic polarization testwas conducted by varying chloride ion concentration,pH value of the NaCl solution and exposure time.The corroded surfaces wereanalyzed using optical microscopy,scanning electron microscopy and XRD techniques.Of these three factors investigated,exposuretime is found to be the most significant factor to influence the corrosion behaviour of SZ of friction stir welded dissimilar joints ofAl/Mg alloys.

Mechanism of corrosion fatigue fracture of friction stir welding joints of 7075 aluminium alloy in 3.5% NaCl solution

The corrosion fatigue fracture mechanism of friction stir welding(FSW) joints of 7075 aluminium alloy in3.5% NaCl solution is investigated. The corrosion fatigue crack source originates from the junction of nugget zone(NZ)and thermo-mechanical affected zone(TMAZ). Multiple crack sources are developed at the same time, and they merge into large cracks along the boundary line of NZ and TMAZ during the propagation stage. Furthermore, a mutual reinforcement coupling always exists between corrosion and cyclic loading during the initiation and propagation of corrosion fatigue crack. It is necessary to consider the effect of welding residual stress for understanding the mechanism of corrosion fatigue fracture of FSW joints.

Effects of laser heat treatment on salt spray corrosion of 1Cr5Mo heat resistant steel welding joints

The surface of 1Cr5 Mo heat-resistant steel welding joint was processed with CO2 laser, and the corrosion behaviors before and after laser heat treatment(LHT) were investigated in the salt spray corrosion environments. The microstructures, phases, residual stresses and retained austenite content of 1Cr5 Mo steel welding joint before and after LHT were analyzed with optical microscope and X-ray diffraction, respectively. The cracking morphologies and chemical compositions of corrosion products after salt spray corrosion were analyzed with field emission scanning electron microscopy(FESEM) and energy disperse spectroscopy(EDS), respectively, the polarization curves were measured on a PS-268 A type electrochemical workstation, and the mechanism of corrosion resistance by LHT was investigated as well. The results show that the passive film of original sample is destroyed owing to the corrosive media penetrating into the subsurface, resulting in the redox reaction. The content of residual austenite in the surface and the self-corrosion potential are increased by LHT, which is contributed to improving the capability of salt spray corrosion resistance.

HT—L系统低温甲醇洗氨冷器泄漏返修方案及处理措施

针对HT—L系统的低温甲醇洗岗位氨冷器U形管、管板接头处出现泄漏的问题，采取相应的返修方案和补漏措施，对u形管进行若干堵头堵漏和对管板接头坑蚀情况进行焊接等措施，有效地解决设备泄漏的问题。