Graft copolymers of MMA （methyl methacrylate） with NRL （natural rubber latex） referred to as NR-g-PMMA have been prepared using CHP （cumene hydroperoxide）/TEPA （tetraetbylenepentamine） redox initiator. 1H NMR ...Graft copolymers of MMA （methyl methacrylate） with NRL （natural rubber latex） referred to as NR-g-PMMA have been prepared using CHP （cumene hydroperoxide）/TEPA （tetraetbylenepentamine） redox initiator. 1H NMR （proton nuclear magnetic resonance） and FTIR （Fourier transform infrared） analysis have confirmed the occurrence of graft copolymerisations of MMA onto NR that containing 30% and 50% of MMA monomer. The influence of coagulating agents such as formic acid, sulfuric acid and boiling water on the coagulation of NR-g-PMMA latices were investigated. These types of coagulating agent formed compact coagulum and the effect of NR-g-PMMA compounds on cure characteristics, physical properties and appearances were reported.展开更多
文摘Graft copolymers of MMA （methyl methacrylate） with NRL （natural rubber latex） referred to as NR-g-PMMA have been prepared using CHP （cumene hydroperoxide）/TEPA （tetraetbylenepentamine） redox initiator. 1H NMR （proton nuclear magnetic resonance） and FTIR （Fourier transform infrared） analysis have confirmed the occurrence of graft copolymerisations of MMA onto NR that containing 30% and 50% of MMA monomer. The influence of coagulating agents such as formic acid, sulfuric acid and boiling water on the coagulation of NR-g-PMMA latices were investigated. These types of coagulating agent formed compact coagulum and the effect of NR-g-PMMA compounds on cure characteristics, physical properties and appearances were reported.
