A facile route for preparation of gradient wettability surface on copper substrate with contact angle changing from 90.3°to4.2°was developed.The Cu（OH）2 nanoribbon arrays were electrochemically deposited o...A facile route for preparation of gradient wettability surface on copper substrate with contact angle changing from 90.3°to4.2°was developed.The Cu（OH）2 nanoribbon arrays were electrochemically deposited on copper foil via a modified anodization technology,and the growth degree and density of the Cu（OH）2 arrays may be controlled varying with position along the substrate by slowly adding aqueous solution of KOH into the two-electrode cell of an anodization system to form the gradient surface.The prepared surface was water resistant and thermal stable,which could keep its gradient wetting property after being immersed in water bath at 100℃ for 10 h.The results of scanning electron microscopy（SEM）,X-ray diffraction（XRD） and X-ray photoelectron spectroscopy（XPS） demonstrate that the distribution of Cu（OH）2 nanoribbon arrays on copper surface are responsible for the gradient wettability.展开更多
Two different poling techniques-corona poling and contact poling in the backdrop of electro-optic （EO） polymer modulators are compared. A 3-layer structure EO polymer modulator is prepared for the poling. The poling...Two different poling techniques-corona poling and contact poling in the backdrop of electro-optic （EO） polymer modulators are compared. A 3-layer structure EO polymer modulator is prepared for the poling. The poling setups and procedures of these two different methods are given. It is found that a well-controlled precure step is very critical, otherwise it will result in either lower poling efficiency or damaged film. Experimental results show that contact poling does not create severe surface damage as corona poling and poling voltage is much lower, but corona poling provides higher EO effect than contact poling. Besides, contact poling can provide poling size as large as the substrate size.展开更多
A new method of nanocontact fabrication for Adreev reflection measurement based on the nanopore method using a SiN membrane with focused ion beam technique is presented. With this method, controllable, clean,tensionle...A new method of nanocontact fabrication for Adreev reflection measurement based on the nanopore method using a SiN membrane with focused ion beam technique is presented. With this method, controllable, clean,tensionless nano-contacts for spin polarization probing can be obtained. Measurements of the fabricated samples show complicated spectral structures with a zero bias anomaly and dip structures from quasipartical interactions. A control sample of Co40Fe40B20 is measured with Nb tip method. None of the measured spectra can be explained satisfactorily by present theory. Further analysis of the contact interface and a more complete theory are needed to extract a reliable spin polarization message with the point contact Andreev reflection method.展开更多
Based on ab initio theory, the interracial spin polarization of a benzene-dithiolate molecule vertically adsorbed on a nickel surface is investigated by adopting different microscopic con- tact configurations. The res...Based on ab initio theory, the interracial spin polarization of a benzene-dithiolate molecule vertically adsorbed on a nickel surface is investigated by adopting different microscopic con- tact configurations. The results demonstrate a strong dependence of the interfacial spin polarization on the contact configuration, where the sign of spin polarization may vary from positive to negative with the change of contact configuration. By analyzing the projected density of states, an interracial orbital hybridization between the 3d orbital of the nickel atom and the sp3 hybridized orbital of the sulfur atom is observed. We also simulated the interracial adsorption in mechanically controllable break junction experiments. The magne- toresistance obtained from Julliere model is about 27% based on the calculated interracial spin polarization, which is consistent with experimental measurement.展开更多
基金Project(S2012010010417)supported by the Guangdong Natural Science Foundation,ChinaProject(20130172110008)supported by the Specialized Research Fund for the Doctoral Program of Higher Education of China
文摘A facile route for preparation of gradient wettability surface on copper substrate with contact angle changing from 90.3°to4.2°was developed.The Cu（OH）2 nanoribbon arrays were electrochemically deposited on copper foil via a modified anodization technology,and the growth degree and density of the Cu（OH）2 arrays may be controlled varying with position along the substrate by slowly adding aqueous solution of KOH into the two-electrode cell of an anodization system to form the gradient surface.The prepared surface was water resistant and thermal stable,which could keep its gradient wetting property after being immersed in water bath at 100℃ for 10 h.The results of scanning electron microscopy（SEM）,X-ray diffraction（XRD） and X-ray photoelectron spectroscopy（XPS） demonstrate that the distribution of Cu（OH）2 nanoribbon arrays on copper surface are responsible for the gradient wettability.
文摘Two different poling techniques-corona poling and contact poling in the backdrop of electro-optic （EO） polymer modulators are compared. A 3-layer structure EO polymer modulator is prepared for the poling. The poling setups and procedures of these two different methods are given. It is found that a well-controlled precure step is very critical, otherwise it will result in either lower poling efficiency or damaged film. Experimental results show that contact poling does not create severe surface damage as corona poling and poling voltage is much lower, but corona poling provides higher EO effect than contact poling. Besides, contact poling can provide poling size as large as the substrate size.
文摘A new method of nanocontact fabrication for Adreev reflection measurement based on the nanopore method using a SiN membrane with focused ion beam technique is presented. With this method, controllable, clean,tensionless nano-contacts for spin polarization probing can be obtained. Measurements of the fabricated samples show complicated spectral structures with a zero bias anomaly and dip structures from quasipartical interactions. A control sample of Co40Fe40B20 is measured with Nb tip method. None of the measured spectra can be explained satisfactorily by present theory. Further analysis of the contact interface and a more complete theory are needed to extract a reliable spin polarization message with the point contact Andreev reflection method.
文摘Based on ab initio theory, the interracial spin polarization of a benzene-dithiolate molecule vertically adsorbed on a nickel surface is investigated by adopting different microscopic con- tact configurations. The results demonstrate a strong dependence of the interfacial spin polarization on the contact configuration, where the sign of spin polarization may vary from positive to negative with the change of contact configuration. By analyzing the projected density of states, an interracial orbital hybridization between the 3d orbital of the nickel atom and the sp3 hybridized orbital of the sulfur atom is observed. We also simulated the interracial adsorption in mechanically controllable break junction experiments. The magne- toresistance obtained from Julliere model is about 27% based on the calculated interracial spin polarization, which is consistent with experimental measurement.
