A simple and facile gas chromatography-mass spectrometer （GC-MS） fingerprint of Su-He-Xiang-Wan （SHXW） was developed, the similarity analysis was conducted, and attribution of the major characteristic peaks was id...A simple and facile gas chromatography-mass spectrometer （GC-MS） fingerprint of Su-He-Xiang-Wan （SHXW） was developed, the similarity analysis was conducted, and attribution of the major characteristic peaks was identified for SHXW quality control. GC-MS analysis was performed on a QP2010 instrument （Shimadzu, Japan） equipped with a capillary column of RTX-5MS. The column temperature was initiated at 50℃, held for 5 min, increased at the rate of 3 ℃/min to 120 ℃, held for 2 min, and then increased at the rate of 4 ℃/min to 220℃, held for 10 min. Helium carrier gas was used at a constant flow rate of 1.3 mL/min. Mass conditions were ionization voltage, 70 eV; injector temperature, 250℃; ion source temperature, 250 ℃; splitting ratio, 30：1; full scan mode in the 40-500 Da mass ranges with rate of 0.2 s per scan. Attribution of the major characteristic peaks was identified for SHXW by comparing the chemical standards, references of Chinese herbal medicines and the negative controls of prescription samples （NC） of SHXW. With the help of the temperature-programmed retention indices （PTRIs） used together with mass spectra and chemical standards, 25 major characteristic peaks have been identified. Nine volatile medicinal materials were identified in the prescription of SHXW by attributing to the 27 major characteristic peaks. The results demonstrate that the proposed method is a powerful approach to quality control of complex herbal medicines.展开更多
This paper focuses graph theory method for the problem of decomposition w.r.t. outputs for Boolean control networks(BCNs). First, by resorting to the semi-tensor product of matrices and the matrix expression of BCNs, ...This paper focuses graph theory method for the problem of decomposition w.r.t. outputs for Boolean control networks(BCNs). First, by resorting to the semi-tensor product of matrices and the matrix expression of BCNs, the definition of decomposition w.r.t. outputs is introduced. Second, by referring to the graphical structure of BCNs, a necessary and sufficient condition for the decomposition w.r.t. outputs is obtained based on graph theory method. Third, an effective algorithm to realize the maximum decomposition w.r.t. outputs is proposed. Finally, some examples are addressed to validate the theoretical results.展开更多
基金Foundation item： Projects（21275164, 21075138） supported by the National Natural Science Foundation of China
文摘A simple and facile gas chromatography-mass spectrometer （GC-MS） fingerprint of Su-He-Xiang-Wan （SHXW） was developed, the similarity analysis was conducted, and attribution of the major characteristic peaks was identified for SHXW quality control. GC-MS analysis was performed on a QP2010 instrument （Shimadzu, Japan） equipped with a capillary column of RTX-5MS. The column temperature was initiated at 50℃, held for 5 min, increased at the rate of 3 ℃/min to 120 ℃, held for 2 min, and then increased at the rate of 4 ℃/min to 220℃, held for 10 min. Helium carrier gas was used at a constant flow rate of 1.3 mL/min. Mass conditions were ionization voltage, 70 eV; injector temperature, 250℃; ion source temperature, 250 ℃; splitting ratio, 30：1; full scan mode in the 40-500 Da mass ranges with rate of 0.2 s per scan. Attribution of the major characteristic peaks was identified for SHXW by comparing the chemical standards, references of Chinese herbal medicines and the negative controls of prescription samples （NC） of SHXW. With the help of the temperature-programmed retention indices （PTRIs） used together with mass spectra and chemical standards, 25 major characteristic peaks have been identified. Nine volatile medicinal materials were identified in the prescription of SHXW by attributing to the 27 major characteristic peaks. The results demonstrate that the proposed method is a powerful approach to quality control of complex herbal medicines.
基金supported in part by the National Natural Science Foundation of China under Grant Nos.61673012,11271194a Project on the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)
文摘This paper focuses graph theory method for the problem of decomposition w.r.t. outputs for Boolean control networks(BCNs). First, by resorting to the semi-tensor product of matrices and the matrix expression of BCNs, the definition of decomposition w.r.t. outputs is introduced. Second, by referring to the graphical structure of BCNs, a necessary and sufficient condition for the decomposition w.r.t. outputs is obtained based on graph theory method. Third, an effective algorithm to realize the maximum decomposition w.r.t. outputs is proposed. Finally, some examples are addressed to validate the theoretical results.
