Ion conductive membranes(ICMs)are frequently used as separators for energy conversion and storage technologies of fuel cells,flow battery,and hydrogen pump,because of their good ion-selective conduction and low electr...Ion conductive membranes(ICMs)are frequently used as separators for energy conversion and storage technologies of fuel cells,flow battery,and hydrogen pump,because of their good ion-selective conduction and low electronic conductivity.Firstly,this feature article reviews the recent studies on the development of new nonfluorinated ICMs with low cost and their macro/micro-structure control.In general,these new nonfluorinated ICMs have lower conductivity than commercial perfluorinated ones,due to their poor ion transport channels.Increasing ion exchange capacity(IEC)would create more continuous hydrophilic channels,thus enhancing the conductivity.However,high IEC also expands the overall hydrophilic domains,weakens the interaction between polymer chains,enhances the mobility of polymer chains,and eventually induces larger swelling.The micro-scale expansion and macro-scale swelling of the ICMs with high IEC could be controlled by limiting the mobility of polymer chains.Based on this strategy,some ef ficient techniques have been developed,including covalent crosslinking,semi-interpenatrating polymer network,and blending.Secondly,this review introduces the optimization of macro/microstructure of both perfluorinated and nonfluorinated ICMs to improve the performance.Macro-scale multilayer composite is an ef ficient way to enhance the mechanical strength and the dimensional stability of the ICMs,and could also decrease the content of per fluorosulfonic acid resin in the membrane,thereby reducing the cost of the perfluorinated ICMs.Long side chain,multiple functionalization,small molecule inducing micro-phase separation,electrospun nano fiber,and organic–inorganic hybrid could construct more ef ficient ion transport channels,improving the ion conductivity of ICMs.展开更多
The National Development and Reform Commission beefed up its efforts to promote the work of electricity price reform in 2004. It took measures in aspects of easing price contradictions, tentatively implementing discri...The National Development and Reform Commission beefed up its efforts to promote the work of electricity price reform in 2004. It took measures in aspects of easing price contradictions, tentatively implementing discriminated price and time-of-use price and issuing a policy on the linkage of coal and electricity prices and price administration. In 2005 the basic thinking of the Commission's electricity price reform is to actively advance the pilot work of price reform,carry out the reform of transmission and distribution price, enlarge the scope of pilot work of large consumer's direct purchase, simplify sales price structure and bring about the linkage of coal and electricity prices.展开更多
A perimeter traffic signal control strategy is proposed based on the macroscopic fundamental diagram theory(MFD)to solve the signal control problem in oversaturated states.First,the MFD of a specific regional network ...A perimeter traffic signal control strategy is proposed based on the macroscopic fundamental diagram theory(MFD)to solve the signal control problem in oversaturated states.First,the MFD of a specific regional network can be derived using VSS IM simulation software.Secondly,the maximum number of cumulative vehicles that the network can accommodate is determined based on the MFD.Then,through monitoring the influx flow,the number of vehicles existing in and exiting from the network,a perimeter traffic control model is proposed to optimize the signal timing of the boundary intersections.Finally,a virtual network simulation model is established and three different kinds o f traffic demand are loaded into the network.Simulation results show that a fer the strategy implementation,the number o f vehicles accumulating in the network can be kept near the optimal value,while the number o f both entering and exiting vehicles increases significantly and the road network can be maintained at a large capacity.Simultaneously,the queue length at the approach of the border intersections is reasonably controlled and vehicles entering and exiting the network can maintain a more efficient and stable speed.The network performance indices such as the average traffic delay and average number of stops can be improved to a certain degree,thus verifying the effectiveness and feasibility of the perimeter control strategy.展开更多
基金Supported by the National Science Fund for Distinguished Young Scholars of China(Grant No.21125628)the Major National Scienti fic Instrument Development Project(Grant No.21527812)+3 种基金the National Natural Science Foundation of China(Grant Nos.21406031 and 21476044)the State Key Laboratory of Fine Chemicals(KF1507)the Fundamental Research Funds for the Central Universities(Grant Nos.DUTPJ14RC(3)003)State Key Laboratory of fine chemicals(Panjin)project(Grant No.JH2014009)
文摘Ion conductive membranes(ICMs)are frequently used as separators for energy conversion and storage technologies of fuel cells,flow battery,and hydrogen pump,because of their good ion-selective conduction and low electronic conductivity.Firstly,this feature article reviews the recent studies on the development of new nonfluorinated ICMs with low cost and their macro/micro-structure control.In general,these new nonfluorinated ICMs have lower conductivity than commercial perfluorinated ones,due to their poor ion transport channels.Increasing ion exchange capacity(IEC)would create more continuous hydrophilic channels,thus enhancing the conductivity.However,high IEC also expands the overall hydrophilic domains,weakens the interaction between polymer chains,enhances the mobility of polymer chains,and eventually induces larger swelling.The micro-scale expansion and macro-scale swelling of the ICMs with high IEC could be controlled by limiting the mobility of polymer chains.Based on this strategy,some ef ficient techniques have been developed,including covalent crosslinking,semi-interpenatrating polymer network,and blending.Secondly,this review introduces the optimization of macro/microstructure of both perfluorinated and nonfluorinated ICMs to improve the performance.Macro-scale multilayer composite is an ef ficient way to enhance the mechanical strength and the dimensional stability of the ICMs,and could also decrease the content of per fluorosulfonic acid resin in the membrane,thereby reducing the cost of the perfluorinated ICMs.Long side chain,multiple functionalization,small molecule inducing micro-phase separation,electrospun nano fiber,and organic–inorganic hybrid could construct more ef ficient ion transport channels,improving the ion conductivity of ICMs.
文摘The National Development and Reform Commission beefed up its efforts to promote the work of electricity price reform in 2004. It took measures in aspects of easing price contradictions, tentatively implementing discriminated price and time-of-use price and issuing a policy on the linkage of coal and electricity prices and price administration. In 2005 the basic thinking of the Commission's electricity price reform is to actively advance the pilot work of price reform,carry out the reform of transmission and distribution price, enlarge the scope of pilot work of large consumer's direct purchase, simplify sales price structure and bring about the linkage of coal and electricity prices.
基金The National Natural Science Foundation of China(No.51308227)the Fundamental Research Funds for the Central Universities(No.201522087)+1 种基金the Science and Technology Planning Project of Guangdong Province(No.2016A030305001)the Project of Department of Communications of Guangdong Province(No.2015-02-070)
文摘A perimeter traffic signal control strategy is proposed based on the macroscopic fundamental diagram theory(MFD)to solve the signal control problem in oversaturated states.First,the MFD of a specific regional network can be derived using VSS IM simulation software.Secondly,the maximum number of cumulative vehicles that the network can accommodate is determined based on the MFD.Then,through monitoring the influx flow,the number of vehicles existing in and exiting from the network,a perimeter traffic control model is proposed to optimize the signal timing of the boundary intersections.Finally,a virtual network simulation model is established and three different kinds o f traffic demand are loaded into the network.Simulation results show that a fer the strategy implementation,the number o f vehicles accumulating in the network can be kept near the optimal value,while the number o f both entering and exiting vehicles increases significantly and the road network can be maintained at a large capacity.Simultaneously,the queue length at the approach of the border intersections is reasonably controlled and vehicles entering and exiting the network can maintain a more efficient and stable speed.The network performance indices such as the average traffic delay and average number of stops can be improved to a certain degree,thus verifying the effectiveness and feasibility of the perimeter control strategy.
