PEM （Proton Exchange Membrane） fuel cell is a promising renewable energy source to a wide range of applications for its clean products and high power density. However, controlling its humidity is a challenging probl...PEM （Proton Exchange Membrane） fuel cell is a promising renewable energy source to a wide range of applications for its clean products and high power density. However, controlling its humidity is a challenging problem due to the interdependence of several phenomena contributing in membrane＇s water content. This work deals with efficiency improvement of PEM fuel cells via humidity control. An innovative strategy of control based on the model of Ref. [1] is proposed. It consists on regulating gas humidification rates according to the power demand so that to minimize power losses. The proposed control takes into consideration constraints related to humidification in order to avoid dry out or flooding of the membrane. Simulations results show that time-phasing between hydrogen and oxygen humidification rates plays an important role in minimizing power losses. The proposed control shows significant improvement in the fuel cell＇s efficiency up to 20%.展开更多
The long-term safe operation of high-power equipment and integrated electronic devices requires efficient thermal management,which in turn increases the energy consumption further.Hence,the sustainable development of ...The long-term safe operation of high-power equipment and integrated electronic devices requires efficient thermal management,which in turn increases the energy consumption further.Hence,the sustainable development of our society needs advanced thermal management with low,even zero,energy consumption.Harvesting water from the atmosphere,followed by moisture desorption to dissipate heat,is an efficient and feasible approach for zero-energy-consumption thermal management.However,current methods are limited by the low absorbance of water,low water vapor transmission rate(WVTR)and low stability,thus resulting in low thermal management capability.In this study,we report an innovative electrospinning method to process hierarchically porous metal–organic framework(MOF)composite fabrics with high-efficiency and zero-energy-consumption thermal management.The composite fabrics are highly loaded with MOF(75 wt%)and their WVTR value can be up to 3138 g m^(-2) d^(-1).The composite fabrics also exhibit stable microstructure and performance.Under a conventional environment(30℃,60%relative humidity),the composite fabrics adsorb water vapor for regeneration within 1.5 h to a saturated value Wsat of 0.614 g g^(-1),and a corresponding equivalent enthalpy of 1705.6 J g^(-1).In the thermal management tests,the composite fabrics show a strong cooling capability and significantly improve the performance of thermoelectric devices,portable storage devices and wireless chargers.These results suggest that hierarchically porous MOF composite fabrics are highly promising for thermal management of intermittent-operation electronic devices.展开更多
文摘PEM （Proton Exchange Membrane） fuel cell is a promising renewable energy source to a wide range of applications for its clean products and high power density. However, controlling its humidity is a challenging problem due to the interdependence of several phenomena contributing in membrane＇s water content. This work deals with efficiency improvement of PEM fuel cells via humidity control. An innovative strategy of control based on the model of Ref. [1] is proposed. It consists on regulating gas humidification rates according to the power demand so that to minimize power losses. The proposed control takes into consideration constraints related to humidification in order to avoid dry out or flooding of the membrane. Simulations results show that time-phasing between hydrogen and oxygen humidification rates plays an important role in minimizing power losses. The proposed control shows significant improvement in the fuel cell＇s efficiency up to 20%.
基金supported by the National Natural Science Foundation of China(51877132,U19A20105,and 52003153)the Program of Shanghai Academic Research Leader(21XD1401600)。
文摘The long-term safe operation of high-power equipment and integrated electronic devices requires efficient thermal management,which in turn increases the energy consumption further.Hence,the sustainable development of our society needs advanced thermal management with low,even zero,energy consumption.Harvesting water from the atmosphere,followed by moisture desorption to dissipate heat,is an efficient and feasible approach for zero-energy-consumption thermal management.However,current methods are limited by the low absorbance of water,low water vapor transmission rate(WVTR)and low stability,thus resulting in low thermal management capability.In this study,we report an innovative electrospinning method to process hierarchically porous metal–organic framework(MOF)composite fabrics with high-efficiency and zero-energy-consumption thermal management.The composite fabrics are highly loaded with MOF(75 wt%)and their WVTR value can be up to 3138 g m^(-2) d^(-1).The composite fabrics also exhibit stable microstructure and performance.Under a conventional environment(30℃,60%relative humidity),the composite fabrics adsorb water vapor for regeneration within 1.5 h to a saturated value Wsat of 0.614 g g^(-1),and a corresponding equivalent enthalpy of 1705.6 J g^(-1).In the thermal management tests,the composite fabrics show a strong cooling capability and significantly improve the performance of thermoelectric devices,portable storage devices and wireless chargers.These results suggest that hierarchically porous MOF composite fabrics are highly promising for thermal management of intermittent-operation electronic devices.
