In the past 30 years,signed directed graph(SDG) ,one of the qualitative simulation technologies,has been widely applied for chemical fault diagnosis.However,SDG based fault diagnosis,as any other qualitative method,ha...In the past 30 years,signed directed graph(SDG) ,one of the qualitative simulation technologies,has been widely applied for chemical fault diagnosis.However,SDG based fault diagnosis,as any other qualitative method,has poor diagnostic resolution.In this paper,a new method that combines SDG with qualitative trend analysis(QTA) is presented to improve the resolution.In the method,a bidirectional inference algorithm based on assumption and verification is used to find all the possible fault causes and their corresponding consistent paths in the SDG model.Then an improved QTA algorithm is used to extract and analyze the trends of nodes on the consis-tent paths found in the previous step.New consistency rules based on qualitative trends are used to find the real causes from the candidate causes.The resolution can be improved.This method combines the completeness feature of SDG with the good diagnostic resolution feature of QTA.The implementation of SDG-QTA based fault diagno-sis is done using the integrated SDG modeling,inference and post-processing software platform.Its application is illustrated on an atmospheric distillation tower unit of a simulation platform.The result shows its good applicability and efficiency.展开更多
The influence of magnetic field on the redox potentials of the Nernst equation. The author offered the new formula Nernst equation in a magnetic field. Our proposed formula takes into account the influence of the magn...The influence of magnetic field on the redox potentials of the Nernst equation. The author offered the new formula Nernst equation in a magnetic field. Our proposed formula takes into account the influence of the magnetic field on the redox processes.展开更多
Electrocatalytic reduction of nitrogen into ammonia(NH_(3))is a highly attractive but challenging route for NH_(3)production.We propose to realize a synergetic work of multi reaction sites to overcome the limitation o...Electrocatalytic reduction of nitrogen into ammonia(NH_(3))is a highly attractive but challenging route for NH_(3)production.We propose to realize a synergetic work of multi reaction sites to overcome the limitation of sustainable NH_(3)production.Herein,using ruthenium-sulfur-carbon(Ru-S-C)catalyst as a prototype,we show that the Ru/S dual-site cooperates to catalyse eletrocatalytic nitrogen reduction reaction(eNRR)at ambient conditions.With the combination of theoretical calculations,in situ Raman spectroscopy,and experimental observation,we demonstrate that such Ru/S dual-site cooperation greatly facilitates the activation and first protonation of N_(2)in the rate-determining step of eNRR.As a result,Ru-S-C catalyst exhibits significantly enhanced eNRR performance compared with the routine Ru-N-C catalyst via a single-site catalytic mechanism.We anticipate that our specifically designed dual-site collaborative catalytic mechanism will open up a new way to offers new opportunities for advancing sustainable NH_(3)production.展开更多
A new marine propulsion system is proposed . A small liquid sodium cooled reactor acts as prime mover; alkali-metal thermal-to-electric conversion ( AMTEC) cells are employed to convert the heat energy to electricity;...A new marine propulsion system is proposed . A small liquid sodium cooled reactor acts as prime mover; alkali-metal thermal-to-electric conversion ( AMTEC) cells are employed to convert the heat energy to electricity; superconducting magneto-hydrodynamic thruster combined with spray-water thruster works as pr opulsion. The configuration and characteristics of this system are described. Such a nuclear-powered propulsion system is not only free of noise, but also has high reliability and efficiency. It would be a preferable propulsion system for ships in the future.展开更多
To understand the effect of the doping amount of Cu^2+ on the structure and reactivity of SnO2 in NOx-SCR with NH3, a series of Sn-Cu-O binary oxide catalysts with different Sn/Cu ratios have been prepared and thoroug...To understand the effect of the doping amount of Cu^2+ on the structure and reactivity of SnO2 in NOx-SCR with NH3, a series of Sn-Cu-O binary oxide catalysts with different Sn/Cu ratios have been prepared and thoroughly characterized. Using the XRD extrapolation method, the SnO2 lattice capacity for Cu^2+ cations is determined at 0.10 g Cu O per g of SnO2, equaling a Sn/Cu molar ratio of 84/16. Therefore, in a tetragonal rutile SnO2 lattice, only a maximum of 16% of the Sn4+ cations can be replaced by Cu^2+ to form a stable solid solution structure. If the Cu content is higher, Cu O will form on the catalyst surface, which has a negative effect on the reaction performance. For samples in a pure solid solution phase, the number of surface defects increase with increasing Cu content until it reaches the lattice capacity, as confirmed by Raman spectroscopy. As a result, the amounts of both active oxygen species and acidic sites on the surface, which critically determine the reaction performance, also increase and reach the maximum level for the catalyst with a Cu content close to the lattice capacity. A distinct lattice capacity threshold effect on the structure and reactivity of Sn-Cu binary oxide catalysts has been observed. A Sn-Cu catalyst with the best reaction performance can be obtained by doping the SnO2 matrix with the lattice capacity amount of Cu^2+.展开更多
Objective： To observe the specificity of reinforcing and reducing methods of mild moxibustion and explore its clinical significance. Methods： Thirty healthy students were selected and given reinforcing of mild moxi...Objective： To observe the specificity of reinforcing and reducing methods of mild moxibustion and explore its clinical significance. Methods： Thirty healthy students were selected and given reinforcing of mild moxibustion on the left Neiguan （PC 6） and reducing on the right Neiguan （PC 6） respectively. Temperature of the acupoint skin surface and the temperature-time curve were recorded by a digital thermometer. Results： In application of mild moxibustion on Neiguan （PC 6）, there was a statistical difference in the temperature-increase section between reinforcing and reducing methods （P〈0.01）. The temperature-increasing section of the temperature-time curve in the reducing method was obviously steeper than that in the reinforcing method. In the period of 0.5-3 min during moxibustion, the temperature of Neiguan （PC 6） was remarkably higher in the reducing than in the reinforcing （P〈0.01）. In the application of the reducing, the time for the temperature of Neiguan （PC 6） to increase to 40~C was remarkably advanced （P〈0.05） and the rate of burning pain in the subjects was remarkably higher in the reducing method than in the reinforcing method （P〈0.001）. Conclusion： In comparison with the reinforcing method, the acupoint temperature increased more quickly in the application of reducing method and can produce obvious hot stimulation in a short period of time. In the application of the reinforcing method, the acupoint temperature increased mildly and could enhance the tolerance of the organism to the high temperature.展开更多
This paper is concerned with the optimal control problems of forward-backward delay systems involving impulse controls. The authors establish a stochastic maximum principle for this kind of systems. The most distingui...This paper is concerned with the optimal control problems of forward-backward delay systems involving impulse controls. The authors establish a stochastic maximum principle for this kind of systems. The most distinguishing features of the proposed problem are that the control variables consist of regular and impulsive controls, both with time delay, and that the domain of regular control is not necessarily convex. The authors obtain the necessary and sufficient conditions for optimal controls,which have potential applications in mathematical finance.展开更多
基金Supported by the Science and Technological Tackling Project of Heilongjiang Province(GB06A106)
文摘In the past 30 years,signed directed graph(SDG) ,one of the qualitative simulation technologies,has been widely applied for chemical fault diagnosis.However,SDG based fault diagnosis,as any other qualitative method,has poor diagnostic resolution.In this paper,a new method that combines SDG with qualitative trend analysis(QTA) is presented to improve the resolution.In the method,a bidirectional inference algorithm based on assumption and verification is used to find all the possible fault causes and their corresponding consistent paths in the SDG model.Then an improved QTA algorithm is used to extract and analyze the trends of nodes on the consis-tent paths found in the previous step.New consistency rules based on qualitative trends are used to find the real causes from the candidate causes.The resolution can be improved.This method combines the completeness feature of SDG with the good diagnostic resolution feature of QTA.The implementation of SDG-QTA based fault diagno-sis is done using the integrated SDG modeling,inference and post-processing software platform.Its application is illustrated on an atmospheric distillation tower unit of a simulation platform.The result shows its good applicability and efficiency.
文摘The influence of magnetic field on the redox potentials of the Nernst equation. The author offered the new formula Nernst equation in a magnetic field. Our proposed formula takes into account the influence of the magnetic field on the redox processes.
文摘Electrocatalytic reduction of nitrogen into ammonia(NH_(3))is a highly attractive but challenging route for NH_(3)production.We propose to realize a synergetic work of multi reaction sites to overcome the limitation of sustainable NH_(3)production.Herein,using ruthenium-sulfur-carbon(Ru-S-C)catalyst as a prototype,we show that the Ru/S dual-site cooperates to catalyse eletrocatalytic nitrogen reduction reaction(eNRR)at ambient conditions.With the combination of theoretical calculations,in situ Raman spectroscopy,and experimental observation,we demonstrate that such Ru/S dual-site cooperation greatly facilitates the activation and first protonation of N_(2)in the rate-determining step of eNRR.As a result,Ru-S-C catalyst exhibits significantly enhanced eNRR performance compared with the routine Ru-N-C catalyst via a single-site catalytic mechanism.We anticipate that our specifically designed dual-site collaborative catalytic mechanism will open up a new way to offers new opportunities for advancing sustainable NH_(3)production.
文摘A new marine propulsion system is proposed . A small liquid sodium cooled reactor acts as prime mover; alkali-metal thermal-to-electric conversion ( AMTEC) cells are employed to convert the heat energy to electricity; superconducting magneto-hydrodynamic thruster combined with spray-water thruster works as pr opulsion. The configuration and characteristics of this system are described. Such a nuclear-powered propulsion system is not only free of noise, but also has high reliability and efficiency. It would be a preferable propulsion system for ships in the future.
文摘To understand the effect of the doping amount of Cu^2+ on the structure and reactivity of SnO2 in NOx-SCR with NH3, a series of Sn-Cu-O binary oxide catalysts with different Sn/Cu ratios have been prepared and thoroughly characterized. Using the XRD extrapolation method, the SnO2 lattice capacity for Cu^2+ cations is determined at 0.10 g Cu O per g of SnO2, equaling a Sn/Cu molar ratio of 84/16. Therefore, in a tetragonal rutile SnO2 lattice, only a maximum of 16% of the Sn4+ cations can be replaced by Cu^2+ to form a stable solid solution structure. If the Cu content is higher, Cu O will form on the catalyst surface, which has a negative effect on the reaction performance. For samples in a pure solid solution phase, the number of surface defects increase with increasing Cu content until it reaches the lattice capacity, as confirmed by Raman spectroscopy. As a result, the amounts of both active oxygen species and acidic sites on the surface, which critically determine the reaction performance, also increase and reach the maximum level for the catalyst with a Cu content close to the lattice capacity. A distinct lattice capacity threshold effect on the structure and reactivity of Sn-Cu binary oxide catalysts has been observed. A Sn-Cu catalyst with the best reaction performance can be obtained by doping the SnO2 matrix with the lattice capacity amount of Cu^2+.
基金supported by National Basic Research Program of China(973 Program,2009CB522901)National Natural Science Foundation of China(81202648)+2 种基金Project of Shanghai Science and Technology Committee(11DZ1973300,11ZR1436700)Innovation Project of Shanghai Municipal Education Commission(11YZ68)Leading Academic Discipline Project of the State Administration of Traditional Chinese Medicine
文摘Objective： To observe the specificity of reinforcing and reducing methods of mild moxibustion and explore its clinical significance. Methods： Thirty healthy students were selected and given reinforcing of mild moxibustion on the left Neiguan （PC 6） and reducing on the right Neiguan （PC 6） respectively. Temperature of the acupoint skin surface and the temperature-time curve were recorded by a digital thermometer. Results： In application of mild moxibustion on Neiguan （PC 6）, there was a statistical difference in the temperature-increase section between reinforcing and reducing methods （P〈0.01）. The temperature-increasing section of the temperature-time curve in the reducing method was obviously steeper than that in the reinforcing method. In the period of 0.5-3 min during moxibustion, the temperature of Neiguan （PC 6） was remarkably higher in the reducing than in the reinforcing （P〈0.01）. In the application of the reducing, the time for the temperature of Neiguan （PC 6） to increase to 40~C was remarkably advanced （P〈0.05） and the rate of burning pain in the subjects was remarkably higher in the reducing method than in the reinforcing method （P〈0.001）. Conclusion： In comparison with the reinforcing method, the acupoint temperature increased more quickly in the application of reducing method and can produce obvious hot stimulation in a short period of time. In the application of the reinforcing method, the acupoint temperature increased mildly and could enhance the tolerance of the organism to the high temperature.
基金supported by the Natural Science Foundation of China under Grant No.61573217,111 Project(B12023)the National High-Level Personnel of Special Support Programthe Chang Jiang Scholar Program of Chinese Education Ministry
文摘This paper is concerned with the optimal control problems of forward-backward delay systems involving impulse controls. The authors establish a stochastic maximum principle for this kind of systems. The most distinguishing features of the proposed problem are that the control variables consist of regular and impulsive controls, both with time delay, and that the domain of regular control is not necessarily convex. The authors obtain the necessary and sufficient conditions for optimal controls,which have potential applications in mathematical finance.
