Using Fe doped titania powders as the precursor, Fe doped TiO2 nanotubes with small diameter of 10nm were obtained by hydrothermal method. The doped titania powders have two different crystalline phases, anatase and r...Using Fe doped titania powders as the precursor, Fe doped TiO2 nanotubes with small diameter of 10nm were obtained by hydrothermal method. The doped titania powders have two different crystalline phases, anatase and rutile of which the average particle diameters are 30.3nm and 41.7nm, receptively. The products were characterized by TEM, XRD and EDS. The results showed that Fe doped TiO2 nanotubes of 200nm in length could be obtained from Fe doped rutile powder, and have higher yields. The formation mechanism of long titania nanotubes was suggested in the light of the relative stability of crystalline phase.展开更多
We prepared TiO 2(anatase) and Sn doped TiO 2 nanoparticlate film by Plasma enhanced Chemical Vapor Deposition(PECVD) method. XRD and XPS experiments showed that Sn was doped into the lattice of TiO 2 with a ratio of ...We prepared TiO 2(anatase) and Sn doped TiO 2 nanoparticlate film by Plasma enhanced Chemical Vapor Deposition(PECVD) method. XRD and XPS experiments showed that Sn was doped into the lattice of TiO 2 with a ratio of n (Sn)∶ n (Ti)=1∶10 . Sn doping largely enhanced the photocatalytic activity of TiO 2 film for phenol degradation. The enhancement in photoactivity by doping was discussed, based on the characterization with AFM, FTIR and EFISPS. Sn doping produced localized level of Sn 4+ in the band gap of TiO 2, about 0.4 eV below the conduction band, which could capture photogenerated electrons and reduce O 2 adsorbed on the surface of TiO 2 film, thus accelerated the photocatalytic reaction.展开更多
文摘Using Fe doped titania powders as the precursor, Fe doped TiO2 nanotubes with small diameter of 10nm were obtained by hydrothermal method. The doped titania powders have two different crystalline phases, anatase and rutile of which the average particle diameters are 30.3nm and 41.7nm, receptively. The products were characterized by TEM, XRD and EDS. The results showed that Fe doped TiO2 nanotubes of 200nm in length could be obtained from Fe doped rutile powder, and have higher yields. The formation mechanism of long titania nanotubes was suggested in the light of the relative stability of crystalline phase.
文摘We prepared TiO 2(anatase) and Sn doped TiO 2 nanoparticlate film by Plasma enhanced Chemical Vapor Deposition(PECVD) method. XRD and XPS experiments showed that Sn was doped into the lattice of TiO 2 with a ratio of n (Sn)∶ n (Ti)=1∶10 . Sn doping largely enhanced the photocatalytic activity of TiO 2 film for phenol degradation. The enhancement in photoactivity by doping was discussed, based on the characterization with AFM, FTIR and EFISPS. Sn doping produced localized level of Sn 4+ in the band gap of TiO 2, about 0.4 eV below the conduction band, which could capture photogenerated electrons and reduce O 2 adsorbed on the surface of TiO 2 film, thus accelerated the photocatalytic reaction.
基金supported by the Fund of the State Key Laboratory of Hydrology-Water Resources and Hydraulic Engineering,Hohai University, China(2009490911)National Natural Science Foundation for Young Scientists of China(20906097)~~
