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球形纳米颗粒在镍基合金纳米流体微量润滑磨削界面摩擦学机制的分子动力学研究
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作者 张宇 王德祥 +1 位作者 郭峰 栗心明 《中国机械工程》 EI CAS CSCD 北大核心 2024年第3期445-456,共12页
以1-丁基-3-甲基咪唑四氟硼酸盐([BMIM]BF 4离子液)作为纳米流体基液,以氧化铝和铜纳米颗粒分别作为高硬度类和低硬度类球形纳米颗粒的代表,用分子动力学模拟方法研究了球形纳米颗粒在镍基合金纳米流体微量润滑磨削界面减摩抗磨的摩擦... 以1-丁基-3-甲基咪唑四氟硼酸盐([BMIM]BF 4离子液)作为纳米流体基液,以氧化铝和铜纳米颗粒分别作为高硬度类和低硬度类球形纳米颗粒的代表,用分子动力学模拟方法研究了球形纳米颗粒在镍基合金纳米流体微量润滑磨削界面减摩抗磨的摩擦学机理,并进一步揭示了纳米流体在砂轮磨粒/工件磨削界面润滑成膜的摩擦学机制。研究结果表明,在镍基合金纳米流体微量润滑磨削加工中,砂轮磨粒/工件磨削界面形成了边界润滑膜。由于铜纳米颗粒硬度远低于砂轮磨粒及镍基合金工件,会在磨粒/工件界面出现压缩、剪切、铺展和分离等一系列摩擦学行为,并形成一层固体润滑膜,这层固体膜通过减小磨粒工件之间的直接接触面积来减小切向磨削力,相较于微量润滑工况可使切向磨削力减小4.6%。由于氧化铝纳米颗粒硬度高于镍基合金工件,故在磨削过程中仍能保持原本的球形纳米结构,会在磨粒/工件界面出现滑移、滚动和抛光三种摩擦学行为,抛光划痕可增大离子液体的浸润面积,并减小磨粒工件之间的直接接触面积,“类滚珠”的滚动行为可将磨粒工件之间的滑动摩擦转变为滚动摩擦,从而使切向磨削力较微量润滑工况减小6.6%。 展开更多
关键词 磨削 微量润滑 纳米流体 球形纳米颗粒 摩擦学机制
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磺酸醇胺离子液体作为水润滑添加剂的摩擦学机制研究 被引量:6
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作者 董瑞 危得全 +5 位作者 于强亮 张嘉莹 王新刚 蔡美荣 周峰 刘维民 《摩擦学学报》 EI CAS CSCD 北大核心 2022年第3期482-492,共11页
合成了不含卤素的磺酸醇胺离子液体(S-IL),并将其作为水基润滑添加剂进行研究.与商用的水基润滑添加剂聚合蓖麻油酸酯(L4)进行对比,共同考察了他们在不同金属摩擦对偶上的摩擦学性能.通过对磨斑表面的XPS测试探究了S-IL分别在钢/钢、钢... 合成了不含卤素的磺酸醇胺离子液体(S-IL),并将其作为水基润滑添加剂进行研究.与商用的水基润滑添加剂聚合蓖麻油酸酯(L4)进行对比,共同考察了他们在不同金属摩擦对偶上的摩擦学性能.通过对磨斑表面的XPS测试探究了S-IL分别在钢/钢、钢/铜、钢/铝、钢/钛和钢/镁摩擦副上的润滑机理.结果表明:所合成的磺酸醇胺离子液体在水体系中具有良好的溶解性,同时表现出一定的抗腐蚀性能.相比于商用水基添加剂,S-IL具有优异的减摩作用和极压性能,这主要归因于离子液体分子结构中极性基团(-SOO-)在金属摩擦副表面的物理/化学吸附,以及其分子结构中含有的活性元素S和N与金属摩擦副基底发生摩擦化学反应所形成的摩擦化学反应膜. 展开更多
关键词 离子液体 添加剂 水基润滑 金属摩擦 摩擦学机制
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烷基咪唑-螯合硼酸离子液体摩擦学性能 被引量:1
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作者 黄雪飞 王娇 +1 位作者 李志鹏 任天辉 《润滑与密封》 CAS CSCD 北大核心 2023年第2期23-31,共9页
以1,3-二癸基咪唑为阳离子,双水杨酸螯合硼酸为阴离子开发一类新型的环境友好螯合硼酸酯-烷基咪唑离子液体n-DICB/i-DICB,采用四球试验机考察2种添加剂在三羟甲基丙烷三油酸酯(PETO)基础中的摩擦学性能,采用SEM、EDX和XANES分析磨损表... 以1,3-二癸基咪唑为阳离子,双水杨酸螯合硼酸为阴离子开发一类新型的环境友好螯合硼酸酯-烷基咪唑离子液体n-DICB/i-DICB,采用四球试验机考察2种添加剂在三羟甲基丙烷三油酸酯(PETO)基础中的摩擦学性能,采用SEM、EDX和XANES分析磨损表面的形态和摩擦中形成的摩擦膜的化学成分。结果表明:n-DICB/i-DICB具有优异的综合摩擦学性能,可显著提高可生物降解基础油的减摩、抗磨和极压性能;i-DICB的减摩性能和极压性能优于n-DICB,质量分数2.5%的i-DICB可使PETO的摩擦因数和磨斑直径分别降低33.0%和22.1%,最大无卡咬负荷提高66.6%。摩擦过程中,n-DICB/i-DICB形成了由B_(2)O_(3)、Na_(2)B_(4)O_(7)、NaBO_(3)和BN等混合物组成的致密摩擦膜,这是离子液体具有优异的摩擦性能根本原因。 展开更多
关键词 离子液体 环境友好 摩擦性能 表面分析 摩擦学机制
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磷系润滑添加剂对7050铝合金摩擦学性能的影响 被引量:5
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作者 黄伟九 余永梅 +1 位作者 张小彬 唐丽文 《中国有色金属学报》 EI CAS CSCD 北大核心 2013年第3期652-657,共6页
采用环-块摩擦磨损试验机考察磷酸三甲酚酯(TCP)、亚磷酸二丁酯(DBPi)、二辛基二硫代磷酸锌(ZDDP)和二正丁基磷酰胺(DBPA)4种磷系润滑添加剂对7050铝合金摩擦学性能的影响,并探讨磷系润滑添加剂与7050铝合金的摩擦学作用机制。结果表明:... 采用环-块摩擦磨损试验机考察磷酸三甲酚酯(TCP)、亚磷酸二丁酯(DBPi)、二辛基二硫代磷酸锌(ZDDP)和二正丁基磷酰胺(DBPA)4种磷系润滑添加剂对7050铝合金摩擦学性能的影响,并探讨磷系润滑添加剂与7050铝合金的摩擦学作用机制。结果表明:4种磷系润滑添加剂均能降低钢-铝摩擦副间的摩擦因数,但添加剂对铝合金抗磨作用的影响因添加剂结构不同而产生较大差异;磷酸三甲酚酯和二正丁基磷酰胺能增强7050铝合金的抗磨作用,其中二正丁基磷酰胺的效果更优;而亚磷酸二丁酯和二辛基二硫代磷酸锌会增加铝合金的磨损,以亚磷酸二丁酯为甚。钢-铝摩擦副间的摩擦因数随添加剂浓度增加而减少,但随载荷增加而提高;以二正丁基磷酰胺润滑的铝合金的磨损量随添加剂浓度增加而减少,但随载荷增加而提高;而以亚磷酸二丁酯润滑时,随载荷和添加剂浓度提高,磨损量均呈增加趋势。在所有的摩擦过程中均出现了磨粒磨损、粘着磨损和化学腐蚀磨损3种磨损机制,其中化学腐蚀磨损和磨粒磨损是磷系润滑添加剂的主要摩擦学作用机制。 展开更多
关键词 含磷添加剂 超高强铝合金 摩擦磨损 摩擦学机制
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Al_2O_3陶瓷材料的摩擦学研究进展 被引量:3
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作者 黄伟九 吴桂森 《润滑与密封》 CAS CSCD 北大核心 2012年第1期93-98,共6页
氧化铝陶瓷刀具材料具有硬度高、耐磨性好、高温性能优良、抗黏结和抗扩散能力强、化学稳定性好等特点,广泛应用于高速切削和切削难加工材料领域。从陶瓷材料晶粒尺寸与摩擦学性能相关性、复相氧化铝陶瓷材料的摩擦学性能和氧化铝陶瓷... 氧化铝陶瓷刀具材料具有硬度高、耐磨性好、高温性能优良、抗黏结和抗扩散能力强、化学稳定性好等特点,广泛应用于高速切削和切削难加工材料领域。从陶瓷材料晶粒尺寸与摩擦学性能相关性、复相氧化铝陶瓷材料的摩擦学性能和氧化铝陶瓷的磨损机制3个方面,综述氧化铝陶瓷材料摩擦学研究进展,以期为新型高品质氧化铝陶瓷刀具材料的开发提供帮助。细化晶粒和组分复合化是提高陶瓷材料的强度和断裂韧性,进而提升其摩擦学性能的有效途径,但目前氧化铝陶瓷摩擦学研究主要是基于晶粒尺寸为600 nm以上的单相陶瓷和基体晶粒尺寸为1μm左右的复相陶瓷材料,对纳米/超细晶(500 nm以下)氧化铝陶瓷材料的研究是未来的研究方向。 展开更多
关键词 氧化铝 陶瓷材料 晶粒尺寸 摩擦性能 摩擦学机制
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感应烧结Fe-Cu-Al-石墨复合材料的力学性能和摩擦学性能 被引量:3
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作者 付传起 王宙 《材料保护》 CAS CSCD 北大核心 2011年第10期32-34,7,共3页
为了进一步提高材料的力学性能和摩擦学性能,以感应加热烧结的方法,制备了Fe-Cu-Al-石墨复合材料。利用XRD,EDS,SEM等分析了复合材料的组成、结构、表面形貌;研究了其力学性能、摩擦学性能及磨损机理。结果表明:Fe-Cu-Al-石墨复合材料... 为了进一步提高材料的力学性能和摩擦学性能,以感应加热烧结的方法,制备了Fe-Cu-Al-石墨复合材料。利用XRD,EDS,SEM等分析了复合材料的组成、结构、表面形貌;研究了其力学性能、摩擦学性能及磨损机理。结果表明:Fe-Cu-Al-石墨复合材料具有多孔结构;随着石墨含量的增加,复合材料的力学性能降低,摩擦学性能提高,石墨含量为4%时复合材料的摩擦学性能良好;在摩擦过程中,Fe-Cu-Al-石墨复合材料表面形成自润滑釉质层,摩擦机制由粘着磨损转变为磨粒磨损。 展开更多
关键词 摩擦性能 摩擦学机制 性能 Fe-Cu-Al-石墨复合材料 感应烧结
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共价有机骨架纳米材料的制备及摩擦学性能研究 被引量:2
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作者 文平 雷永珍 《摩擦学学报》 EI CAS CSCD 北大核心 2022年第1期123-130,共8页
利用三聚氯氰和2,5-二氨基-苯并-二噻唑为原料,通过简单的溶剂热法反应制备了一类新型的共价有机骨架纳米材料(简称TTC),该纳米材料具有二维的层状结构,在水和聚乙二醇400(PEG 400)混合润滑体系中呈现出良好的分散性.摩擦学试验表明,添... 利用三聚氯氰和2,5-二氨基-苯并-二噻唑为原料,通过简单的溶剂热法反应制备了一类新型的共价有机骨架纳米材料(简称TTC),该纳米材料具有二维的层状结构,在水和聚乙二醇400(PEG 400)混合润滑体系中呈现出良好的分散性.摩擦学试验表明,添加质量分数为0.5%时,TTC可显著降低钢-钢摩擦对偶上的摩擦系数和磨损体积.摩擦学机制研究表明三嗪环和苯并噻唑环结构高的π电子云密度使TTC与金属铁原子/离子间产生强的相互作用,同时硫原子高的亲合力进一步协同形成稳定的摩擦膜,此外,TTC层间弱的范德华力降低了横向剪切强度,层内共价键保证了润滑膜的力学强度. 展开更多
关键词 共价有机骨架 润滑添加剂 减摩抗磨性能 摩擦学机制
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ZL111和ZL104在干摩擦和油润滑下的摩擦磨损行为研究 被引量:1
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作者 王婷婷 刘佳阳 +2 位作者 王慧明 李应举 吕晓仁 《液压气动与密封》 2021年第1期35-39,共5页
采用往复式摩擦磨损试验机测试ZL111、ZL104干摩擦及油润滑摩擦性能,研究往复频率和添加剂二辛基二硫代磷酸锌(ZDDP)含量对ZL111、ZL104摩擦学性能的影响,探讨铝合金的摩擦学机理。结果表明:干摩擦下,在低频时ZL111的磨损量小于ZL104。Z... 采用往复式摩擦磨损试验机测试ZL111、ZL104干摩擦及油润滑摩擦性能,研究往复频率和添加剂二辛基二硫代磷酸锌(ZDDP)含量对ZL111、ZL104摩擦学性能的影响,探讨铝合金的摩擦学机理。结果表明:干摩擦下,在低频时ZL111的磨损量小于ZL104。ZL111在大于4 Hz时磨损量随频率增加而加大,而ZL104在大于8 Hz时才增加。基础油润滑下,铝合金在68#机械油润滑下的磨损量高于10W-30全合成油,ZL111的磨损量低于ZL104。在基础油中添加添加剂后,使得铝合金的磨损量降低。ZL111在含ZDDP的油润滑下的磨损量较小,其原因是Cu元素能够加强ZL111分子间的结合力,使化学反应膜更紧密的结合在基体表面。 展开更多
关键词 铝合金 摩擦磨损 摩擦学机制 添加剂
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Tribological behavior of CNTs-Cu and graphite-Cu composites with electric current 被引量:11
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作者 XU Wei HU Rui +2 位作者 LI Jin-shan ZHANG Yong-zhen FU Heng-zhi 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2012年第1期78-84,共7页
CNTs-Cu and graphite-Cu composites were separately prepared by powder metallurgy technique under the same consolidation processing. Tribological behavior of the composites with electric current was investigated by usi... CNTs-Cu and graphite-Cu composites were separately prepared by powder metallurgy technique under the same consolidation processing. Tribological behavior of the composites with electric current was investigated by using a pin-on-disk friction and wear tester. The results show that the friction coefficient and wear rate of the composites decrease with increasing the reinforcement content, and increase with increasing the electric current density; the effects of electric current are more obvious on tribological properties of graphite-Cu composites than on CNTs-Cu composites; for graphite-Cu composites the dominant wear mechanisms are electric arc erosion and adhesive wear, while for CNTs-Cu composites are adhesive wear. 展开更多
关键词 Cu matrix composite tribological behaviors electric current wear mechanisms
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Effects of environment on dry sliding wear behavior of silver-copper based composites containing tungsten disulfide 被引量:11
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作者 Ji-si WU Jing-fu LI +1 位作者 Lei ZHANG Zhi-yuan QIAN 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2017年第10期2202-2213,共12页
Silver based composites containing different amounts of WS2were prepared by hot-pressing method and their tribologicalbehaviors were investigated against coin silver under humid air,dry nitrogen and vacuum on a ball-o... Silver based composites containing different amounts of WS2were prepared by hot-pressing method and their tribologicalbehaviors were investigated against coin silver under humid air,dry nitrogen and vacuum on a ball-on-disk tester with normal load of5N.The components of composites,microstructure of debris and worn surface were characterized using XRD SEM,EDS and XPS.It is demonstrated that environmental conditions significantly affect the tribological behavior of silver based composites.The frictioncoefficient is the highest in humid air,and the lowest in dry nitrogen.It is found that the friction and wear behavior of the compositesare strongly depended on the characteristics of the lubrication film forming in different operating environments,such as thicknessand composition.In addition,it is indicated that the dominant wear mechanisms of silver based composites are abrasive wear anddelamination under different conditions. 展开更多
关键词 self-lubricating composites tribological behaviors ATMOSPHERE wear mechanism
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Effects of TiB_2+TiC content on microstructure and wear resistance of Ni55-based composite coatings produced by plasma cladding 被引量:6
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作者 Xin-jie ZHANG Hong-zhi CUI +3 位作者 Jia-feng WANG Guo-song ZHANG Yu-qiao ZHAO Kang SUN 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2019年第1期132-142,共11页
TiB2-TiC reinforced Ni55 matrix composite coatings were in-situ fabricated via plasma cladding on steels using Ti, B4C, and Ni55 as precursor materials at different proportions. Effects of TiB2+TiC content of ceramics... TiB2-TiC reinforced Ni55 matrix composite coatings were in-situ fabricated via plasma cladding on steels using Ti, B4C, and Ni55 as precursor materials at different proportions. Effects of TiB2+TiC content of ceramics phase on the microstructure and wear resistance were studied. The results showed that ceramic phases TiB2 and TiC were in-situ synthesized by plasma cladding, and the ceramic phase content significantly affected tribological performance and the wear mechanism of coatings under different loads. The composite ceramics protected coatings from further delamination wear by crack-resistance under a load of 30 N. Severe abrasive wear and adhesive wear were prevented when the load increased to 60 N because of the high hardness and strength of ceramic phases. Moreover, a compacted layer appeared on the wear surface of coatings with high content of ceramic phases, which effectively decreased the friction coefficient and wear rate. The TiB2-TiC composite ceramics significantly improved the wear performance of metal matrix composite coatings by different mechanisms under loads of 30 and 60 N. 展开更多
关键词 metal matrix composite coating plasma cladding MICROSTRUCTURE tribological behavior wear mechanism
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Friction and wear of 7075 aluminum alloy induced by torsional fretting 被引量:6
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作者 蔡振兵 朱旻昊 林修洲 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2010年第3期371-376,共6页
The torsional fretting wear tests of 7075 aluminum alloy flat against 52100 steel ball in dry condition were carried out on a new high-precision torsional fretting-wear tester.The kinetics behaviors and damage mechani... The torsional fretting wear tests of 7075 aluminum alloy flat against 52100 steel ball in dry condition were carried out on a new high-precision torsional fretting-wear tester.The kinetics behaviors and damage mechanism of 7075 aluminum alloy under different angular displacement amplitudes were investigated in detail.The results show that the torsional fretting running behaviors of 7075 aluminum alloy can be defined by three fretting regimes(i.e.partial slip regime(PSR),mixed fretting regime(MFR) and slip regime(SR)) with the increase of angular displacement amplitudes.In PSR,the damage occurs at the lateral portion of the contact zone with a slight annular shape.However,in MFR and SR,more severe damages are observed and the debris layer covers the wear scars.Friction torque and dissipation energy which are strongly dependent upon the imposed angular displacement amplitudes and presented in three stages were discussed in detail.The mechanisms of torsional fretting wear of aluminum alloy are mainly oxidative wear,abrasive wear and delamination in the three fretting regimes.In addition,the oxidative debris plays an important role during the torsional fretting wear processes. 展开更多
关键词 7075 aluminum alloy fretting wear torsional fretting fretting regime
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Research on Lubrication Behaviors and Mechanism of Nano-Copper Used in Emulsions for Strip Cold Rolling 被引量:3
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作者 Wang Yizhu Dai Enqi +2 位作者 Zhuang Xiaohua Sun Jianlin Wang Bing 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2012年第1期61-67,共7页
In this paper,nano-Cu particles with an average size of smaller than 20 nm were dispersed under ultrasonic agitation in emulsions for cold rolling of steel strips.The tribological properties of the cold rolling emulsi... In this paper,nano-Cu particles with an average size of smaller than 20 nm were dispersed under ultrasonic agitation in emulsions for cold rolling of steel strips.The tribological properties of the cold rolling emulsion doped with nano-Cu particles were evaluated by using a four-ball machine,and the worn surfaces of the steel balls were checked by an optical microscope.A JC2000C1 wetting angle tester was also applied to study the variation in the emulsion's wetting performance when nano-Cu particles were incorporated.Furthermore,the lubricity of the emulsion doped with nano-Cu for steel strip cold rolling was evaluated on a four-high rolling mill for comparison with the emulsion without using nano-Cu particles.Test results indicated that nano-Cu particles as the additive used in cold rolling emulsion were able to improve the wetting property,friction-reducing,anti-wear,and extreme pressure performance of the base stock significantly.At the same time,nano-Cu particles also showed good lubricity to the cold-rolled steel strips.Namely,the cold-rolled steel strips under the lubrication of the cold rolling emulsion containing nano-Cu particles had considerably decreased the after-rolling thickness and achieved excellent surface quality as well.Finally,the lubrication mechanism of nano-Cu particles in the emulsion for cold rolling of steel strips was discussed. 展开更多
关键词 cold rolling STRIP EMULSION nano-Cu
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等离子喷涂Fe基非晶复合涂层的磨损和腐蚀机制的研究 被引量:2
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作者 褚振华 周玉云 +3 位作者 郑兴伟 邓文兴 许竞翔 高丽 《稀有金属材料与工程》 SCIE EI CAS CSCD 北大核心 2020年第9期2978-2982,共5页
采用一种新型的气体多通道送粉等离子喷涂技术制备得到了含有不同质量分数的ZrO2/Fe基非晶复合涂层。采用该技术可成功制得ZrO2颗粒均匀分布于非晶基体的复合涂层,且可实现第二相颗粒的比例调控。磨损实验表明,复合涂层的磨损性能较单一... 采用一种新型的气体多通道送粉等离子喷涂技术制备得到了含有不同质量分数的ZrO2/Fe基非晶复合涂层。采用该技术可成功制得ZrO2颗粒均匀分布于非晶基体的复合涂层,且可实现第二相颗粒的比例调控。磨损实验表明,复合涂层的磨损性能较单一的Fe基涂层有了很大提高。同时,ZrO2颗粒的添加可提高耐蚀性能,降低孔隙率。经实验表明,质量分数50%ZrO2复合涂层的耐蚀性能最佳。 展开更多
关键词 涂层 非晶 等离子喷涂 摩擦学机制 耐蚀性
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