Autothermal reforming (ATR) is one of the leading methods for hydrogen production from hydrocar- bons. Liquefied petroleum gas, with propane as the main component, is a promising fuel for on-board hydrogen producing s...Autothermal reforming (ATR) is one of the leading methods for hydrogen production from hydrocar- bons. Liquefied petroleum gas, with propane as the main component, is a promising fuel for on-board hydrogen producing systems in fuel cell vehicles and for domestic fuel cell power generation devices. In this article, propane ATR process is studied and operation conditions are optimized with PRO/Ⅱ? from SIMSCI for proton exchange membrane fuel cell application. In the ATR system including water gas shift and preferential oxidation, heat in the hot streams and cold streams is controlled to be in balance. Different operation conditions are studied and drawn in contour plots. The region for ATR reforming with the highest efficiency can thus be identified. One operation point was chosen with the following process parameters: feed temperature for the ATR reactor is 425℃, steam to carbon ratio S/C is 2.08, air stoichiometry is 0.256. Thermal efficiency for the integrated system is calculated to be as high as 84.0 % with 38.27 % H2 and 3.2μl·L-1 CO in the product gas.展开更多
The applicability of a commercial Pt-Sn/Al2O3 isobutane dehydrogenation catalyst in dehydrogenation of propane was studied. Catalyst performance tests were carded out in a fixed-bed quartz reactor under different oper...The applicability of a commercial Pt-Sn/Al2O3 isobutane dehydrogenation catalyst in dehydrogenation of propane was studied. Catalyst performance tests were carded out in a fixed-bed quartz reactor under different operating conditions. Generally, as the factors improving propane conversion decrease the propylene selectivity, the optimal operating condition to maximize propylene yield is expected. The optimal condition was obtamed by the experimental design method. The investigated parameters were temperature, hydrogen/hydrocarbon （HE/HC） ratio and space velocity, being changed in three levels. Constrains such as the susceptibility of the catalyst components to sintering or phase transformation were also taken into account. Activity, selectivity and stability of the catalyst were considered as the measured response factors, while the space-time-yield （STY） was considered as the variable to be optimized due to its commercial interest. A STY of 16 mol.kg^-1.h^-1 was achieved under the optimal conditions of T= 620 ℃, H2/HC = 0.6 and, weight hourly space velocity （WHSV） = 2.2 h^-1. Single carbon-carbon bond rupture was found to be the main route for the formation of lower hydrocarbon byproducts.展开更多
Tube furnaces are essential and primary energy intensive facilities in petrochemical plants. Operational optimization of furnaces could not only help to improve product quality but also benefit to reduce energy consum...Tube furnaces are essential and primary energy intensive facilities in petrochemical plants. Operational optimization of furnaces could not only help to improve product quality but also benefit to reduce energy consumption and exhaust emission. Inspired by this idea, this paper presents a composite model predictive control(CMPC)strategy, which, taking advantage of distributed model predictive control architectures, combines tracking nonlinear model predictive control and economic nonlinear model predictive control metrics to keep process running smoothly and optimize operational conditions. The controllers connected with two kinds of communication networks are easy to organize and maintain, and stable to process interferences. A fast solution algorithm combining interior point solvers and Newton's method is accommodated to the CMPC realization, with reasonable CPU computing time and suitable online applications. Simulation for industrial case demonstrates that the proposed approach can ensure stable operations of furnaces, improve heat efficiency, and reduce the emission effectively.展开更多
Broadly speaking, this study aims to develop ＂batik＂ dyes wastewater treatment technologies by hybrid process that combines Fenton oxidation and separation using ultrafiltration membranes. Specifically, the purpose ...Broadly speaking, this study aims to develop ＂batik＂ dyes wastewater treatment technologies by hybrid process that combines Fenton oxidation and separation using ultrafiltration membranes. Specifically, the purpose of this study was to determine the effect of membrane characteristics, feed solution pH, operating pressure of ＂Dead-end＂ membrane reactor, and the frequency of membranes which uses on the percentage of COD reduction in ＂batik＂ wastewater. In this study, the filtrate from wastewater pre-treatment with Fenton oxidation, both without and with addition of activated carbon, is passed to the ultrafiltration （UF） separation system. Fenton oxidation process was carried out at optimum conditions, i.e. at pH 3, temperature 50 ℃, and the addition FeSO4·7H2O and H2O2 at 747-830 mg/L and 1,168-1,460 mg/L, respectively. The optimum reduction percentage of COD can be achieved when the membranes used for separation has a pore size of 0.01 to 0.015 lam, feed solution pH 2, operating pressure 1 atm and frequency of membranes uses I x. To determine the fouling potential on ultrafiltration membranes that are used, flux measurements were performed 3 times for each membrane. These stages can see that the flux decline reached 22.5% when the effluent filtered directly to the membrane; 17.3% when performed pre-treatment prior to separation processes using membranes and 10% when combined pre-treatment process, use of activated carbon and the separation using ultrafiltration membranes.展开更多
The electric power transfer capability on the Manitoba-Ontario interconnection depends on various system operating conditions such as area generation patterns and ambient temperatures. This work models the power netwo...The electric power transfer capability on the Manitoba-Ontario interconnection depends on various system operating conditions such as area generation patterns and ambient temperatures. This work models the power network as a black-box function, which is evaluated with the system reliability analysis techniques to determine the maximum transfer capability under a given operating condition. A metamodel or an approximation model of the maximized power transfer capability is built based on the sampled system responses and optimized with respect to the corresponding operating conditions. An optimal metamodel is implemented as a prototype software tool, PTCanalyzer, and applied to Manitoba-Ontario interconnection power transfer calculations. This optimized metamodel technique provides an in-depth understanding of the dependency of the power transfer capability on system operating conditions and proves to be an effective tool in optimizing the operation planning of the interconnection for a given power system configuration. The PTCanalyzer has the potential to be used for optimization of other power network interconnections.展开更多
基金Supported by the National 973 Program of China on Hydrogen Energy (TG2000026410) and International Cooperation Projecton Hydrogen Energy (2001AA515080).
文摘Autothermal reforming (ATR) is one of the leading methods for hydrogen production from hydrocar- bons. Liquefied petroleum gas, with propane as the main component, is a promising fuel for on-board hydrogen producing systems in fuel cell vehicles and for domestic fuel cell power generation devices. In this article, propane ATR process is studied and operation conditions are optimized with PRO/Ⅱ? from SIMSCI for proton exchange membrane fuel cell application. In the ATR system including water gas shift and preferential oxidation, heat in the hot streams and cold streams is controlled to be in balance. Different operation conditions are studied and drawn in contour plots. The region for ATR reforming with the highest efficiency can thus be identified. One operation point was chosen with the following process parameters: feed temperature for the ATR reactor is 425℃, steam to carbon ratio S/C is 2.08, air stoichiometry is 0.256. Thermal efficiency for the integrated system is calculated to be as high as 84.0 % with 38.27 % H2 and 3.2μl·L-1 CO in the product gas.
基金Supported by the Petrochemical Research&Technology Co. of National Petrochemical Co.
文摘The applicability of a commercial Pt-Sn/Al2O3 isobutane dehydrogenation catalyst in dehydrogenation of propane was studied. Catalyst performance tests were carded out in a fixed-bed quartz reactor under different operating conditions. Generally, as the factors improving propane conversion decrease the propylene selectivity, the optimal operating condition to maximize propylene yield is expected. The optimal condition was obtamed by the experimental design method. The investigated parameters were temperature, hydrogen/hydrocarbon （HE/HC） ratio and space velocity, being changed in three levels. Constrains such as the susceptibility of the catalyst components to sintering or phase transformation were also taken into account. Activity, selectivity and stability of the catalyst were considered as the measured response factors, while the space-time-yield （STY） was considered as the variable to be optimized due to its commercial interest. A STY of 16 mol.kg^-1.h^-1 was achieved under the optimal conditions of T= 620 ℃, H2/HC = 0.6 and, weight hourly space velocity （WHSV） = 2.2 h^-1. Single carbon-carbon bond rupture was found to be the main route for the formation of lower hydrocarbon byproducts.
文摘Tube furnaces are essential and primary energy intensive facilities in petrochemical plants. Operational optimization of furnaces could not only help to improve product quality but also benefit to reduce energy consumption and exhaust emission. Inspired by this idea, this paper presents a composite model predictive control(CMPC)strategy, which, taking advantage of distributed model predictive control architectures, combines tracking nonlinear model predictive control and economic nonlinear model predictive control metrics to keep process running smoothly and optimize operational conditions. The controllers connected with two kinds of communication networks are easy to organize and maintain, and stable to process interferences. A fast solution algorithm combining interior point solvers and Newton's method is accommodated to the CMPC realization, with reasonable CPU computing time and suitable online applications. Simulation for industrial case demonstrates that the proposed approach can ensure stable operations of furnaces, improve heat efficiency, and reduce the emission effectively.
文摘Broadly speaking, this study aims to develop ＂batik＂ dyes wastewater treatment technologies by hybrid process that combines Fenton oxidation and separation using ultrafiltration membranes. Specifically, the purpose of this study was to determine the effect of membrane characteristics, feed solution pH, operating pressure of ＂Dead-end＂ membrane reactor, and the frequency of membranes which uses on the percentage of COD reduction in ＂batik＂ wastewater. In this study, the filtrate from wastewater pre-treatment with Fenton oxidation, both without and with addition of activated carbon, is passed to the ultrafiltration （UF） separation system. Fenton oxidation process was carried out at optimum conditions, i.e. at pH 3, temperature 50 ℃, and the addition FeSO4·7H2O and H2O2 at 747-830 mg/L and 1,168-1,460 mg/L, respectively. The optimum reduction percentage of COD can be achieved when the membranes used for separation has a pore size of 0.01 to 0.015 lam, feed solution pH 2, operating pressure 1 atm and frequency of membranes uses I x. To determine the fouling potential on ultrafiltration membranes that are used, flux measurements were performed 3 times for each membrane. These stages can see that the flux decline reached 22.5% when the effluent filtered directly to the membrane; 17.3% when performed pre-treatment prior to separation processes using membranes and 10% when combined pre-treatment process, use of activated carbon and the separation using ultrafiltration membranes.
文摘The electric power transfer capability on the Manitoba-Ontario interconnection depends on various system operating conditions such as area generation patterns and ambient temperatures. This work models the power network as a black-box function, which is evaluated with the system reliability analysis techniques to determine the maximum transfer capability under a given operating condition. A metamodel or an approximation model of the maximized power transfer capability is built based on the sampled system responses and optimized with respect to the corresponding operating conditions. An optimal metamodel is implemented as a prototype software tool, PTCanalyzer, and applied to Manitoba-Ontario interconnection power transfer calculations. This optimized metamodel technique provides an in-depth understanding of the dependency of the power transfer capability on system operating conditions and proves to be an effective tool in optimizing the operation planning of the interconnection for a given power system configuration. The PTCanalyzer has the potential to be used for optimization of other power network interconnections.
