A two-step alkaline-acidic leaching process was conducted to separate the cryolite from spent pot lining and to purify the carbon. The influencing factors of temperature, time, and the ratio of liquid to solid in alka...A two-step alkaline-acidic leaching process was conducted to separate the cryolite from spent pot lining and to purify the carbon. The influencing factors of temperature, time, and the ratio of liquid to solid in alkaline and acidic leaching were investigated. The results show that the recovery of soluble compounds of Na3AlF6 and Al2O3 dissolving into the solution during the NaOH leaching is 65.0%,and the purity of carbon reaches 72.7%. During the next step of HCl leaching, the recovery of soluble compounds of CaF2 and NaAl11O17 dissolving into the HCl solution is 96.2%, and the carbon purity increases to 96.4%. By mixing the acidic leaching solution and the alkaline leaching solution, the cryolite precipitates under a suitable conditions of pH value 9 at 70 °C for 2 h. The cryolite precipitating rate is 95.6%, and the purity of Na3AlF6 obtained is 96.4%.展开更多
The cathode materials of spent lithium-ion batteries(LIBs)were recovered via reductive roasting,Na_(2)CO_(3) leaching,and ammonia leaching.The effects of roasting parameters,Na_(2)CO_(3) leaching parameters,and ammoni...The cathode materials of spent lithium-ion batteries(LIBs)were recovered via reductive roasting,Na_(2)CO_(3) leaching,and ammonia leaching.The effects of roasting parameters,Na_(2)CO_(3) leaching parameters,and ammonia leaching parameters on the leaching efficiencies of metals were explored.The results show that the mineral phase of spent LIBs is reconstructed during reductive roasting,and more than 99%of Li can be preferentially leached via Na_(2)CO_(3) leaching.Ni(99.7%)and Co(99.9%)can be leached via one-step ammonia leaching,and Mn cannot be leached.Thus,good leaching selectivity is achieved.The kinetic study shows that the leaching of Ni and Co conforms to chemical reaction control.展开更多
Advances in technology make full use of recyclable material as possible, so the efficient recovery of Recyclable material can avoid a lot of energy waste. This paper takes the PET plastic bottles and waste battery as ...Advances in technology make full use of recyclable material as possible, so the efficient recovery of Recyclable material can avoid a lot of energy waste. This paper takes the PET plastic bottles and waste battery as an example, simple analyses the current situation of China＇ s processing Recyclable substance and development trend, and compared with the foreign outstanding cases, finally proposes the solution展开更多
基金Project (50804010) supported by the National Natural Science Foundation of China
文摘A two-step alkaline-acidic leaching process was conducted to separate the cryolite from spent pot lining and to purify the carbon. The influencing factors of temperature, time, and the ratio of liquid to solid in alkaline and acidic leaching were investigated. The results show that the recovery of soluble compounds of Na3AlF6 and Al2O3 dissolving into the solution during the NaOH leaching is 65.0%,and the purity of carbon reaches 72.7%. During the next step of HCl leaching, the recovery of soluble compounds of CaF2 and NaAl11O17 dissolving into the HCl solution is 96.2%, and the carbon purity increases to 96.4%. By mixing the acidic leaching solution and the alkaline leaching solution, the cryolite precipitates under a suitable conditions of pH value 9 at 70 °C for 2 h. The cryolite precipitating rate is 95.6%, and the purity of Na3AlF6 obtained is 96.4%.
基金the financial support from the Focus on Research and Development Plan in Shandong Province,China(No.2017GSF16102)。
文摘The cathode materials of spent lithium-ion batteries(LIBs)were recovered via reductive roasting,Na_(2)CO_(3) leaching,and ammonia leaching.The effects of roasting parameters,Na_(2)CO_(3) leaching parameters,and ammonia leaching parameters on the leaching efficiencies of metals were explored.The results show that the mineral phase of spent LIBs is reconstructed during reductive roasting,and more than 99%of Li can be preferentially leached via Na_(2)CO_(3) leaching.Ni(99.7%)and Co(99.9%)can be leached via one-step ammonia leaching,and Mn cannot be leached.Thus,good leaching selectivity is achieved.The kinetic study shows that the leaching of Ni and Co conforms to chemical reaction control.
文摘Advances in technology make full use of recyclable material as possible, so the efficient recovery of Recyclable material can avoid a lot of energy waste. This paper takes the PET plastic bottles and waste battery as an example, simple analyses the current situation of China＇ s processing Recyclable substance and development trend, and compared with the foreign outstanding cases, finally proposes the solution
