本研究通过改性红外染料和热引发剂的延迟自由基生成技术,旨在提高计算机直接制版(computer to plate,CTP)技术中免处理版的清晰度和反应性。研究提出了一种延迟自由基生成的策略,实现精确聚合,提升版材图像质量。结果表明,该技术通过...本研究通过改性红外染料和热引发剂的延迟自由基生成技术,旨在提高计算机直接制版(computer to plate,CTP)技术中免处理版的清晰度和反应性。研究提出了一种延迟自由基生成的策略,实现精确聚合,提升版材图像质量。结果表明,该技术通过自由基生成的双峰值曲线,显著提高了版材的清晰度和耐印性。此外,该技术降低了对传统化学品的依赖,减少了环境污染。总体而言,本研究为促进CTP技术的可持续发展提供了新的方法。展开更多
The objective of this work is to study the efficiency of some surface modified phyllosilicate minerals （bentonite and glauconite） in the removal of dyes from textile waste water. It is found that complete dye remova...The objective of this work is to study the efficiency of some surface modified phyllosilicate minerals （bentonite and glauconite） in the removal of dyes from textile waste water. It is found that complete dye removal was achieved by using 10-25g modified glauconite from solutions having a dye concentration of 10-50 mg/L. Adsorption data were modeled using Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherms. Adsorption capacities and optimum adsorption isotherms were predicted by linear regression method. The analysis of experimental isotherms showed that Langmuir isotherm reasonably fit the experimental data in the studied concentration range for the adsorption of dye onto glauconite mineral surface where Freundlich isotherm fit the experimental data for the adsorption of dve onto bentonite mineral surface.展开更多
Polymer exchange membrane fuel cells （PEMFC） are objects of the current engineering technology and these are versatile generators for electrical energy. There are various kinds from them, but all of them are going o...Polymer exchange membrane fuel cells （PEMFC） are objects of the current engineering technology and these are versatile generators for electrical energy. There are various kinds from them, but all of them are going on work at highest temperature. There isn＇t a PEMFC which can run at room temperature, like 20 ℃. In this study there is a aim for constructing such one for alternative fuels utilisation. PS and many electroconducting polymer formulations were proved by different researchers for PEM benefications, but here PS was synthesized without containing metalic contaminants and after converted to the PEM membrane.展开更多
Graphene oxide(GO) has been demonstrated to be an effective hydrophilic nanofiller to modify the polymeric membranes when forming a mixed matrix structure. GO quantum dots(QDs) are promising candidates to fully exert ...Graphene oxide(GO) has been demonstrated to be an effective hydrophilic nanofiller to modify the polymeric membranes when forming a mixed matrix structure. GO quantum dots(QDs) are promising candidates to fully exert the rich oxygen containing functional groups due to their unique size induced edge effects. In this work, GO QDs modified polysulfone(PSF) ultrafiltration(UF) membranes were prepared by phase inversion method with various GO QDs loadings(0.1–0.5 wt.%). A proper amount of GO QDs addition led to a more porous and hydrophilic membrane structure. With 0.3 wt.% GO QDs, the membranes showed a60% increase in permeability(130.54 vs. 82.52 LMH bar^-1).The pristine PSF membranes had a complete cutoff of bovine serum albumin molecules and it was well maintained with GO QDs incorporated. The membranes with 0.5 wt.% GO QDs exhibited the highest flux recovery ratio of 89.7% and the lowest irreversible fouling of 10.3%(54.5% and 33.3% for the pristine PSF membranes). Our results proved that GO QDs can function as effective nanofillers to enhance the hydrophilicity, permeability and antifouling performance of PSF UF membranes.展开更多
文摘本研究通过改性红外染料和热引发剂的延迟自由基生成技术,旨在提高计算机直接制版(computer to plate,CTP)技术中免处理版的清晰度和反应性。研究提出了一种延迟自由基生成的策略,实现精确聚合,提升版材图像质量。结果表明,该技术通过自由基生成的双峰值曲线,显著提高了版材的清晰度和耐印性。此外,该技术降低了对传统化学品的依赖,减少了环境污染。总体而言,本研究为促进CTP技术的可持续发展提供了新的方法。
文摘The objective of this work is to study the efficiency of some surface modified phyllosilicate minerals （bentonite and glauconite） in the removal of dyes from textile waste water. It is found that complete dye removal was achieved by using 10-25g modified glauconite from solutions having a dye concentration of 10-50 mg/L. Adsorption data were modeled using Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherms. Adsorption capacities and optimum adsorption isotherms were predicted by linear regression method. The analysis of experimental isotherms showed that Langmuir isotherm reasonably fit the experimental data in the studied concentration range for the adsorption of dye onto glauconite mineral surface where Freundlich isotherm fit the experimental data for the adsorption of dve onto bentonite mineral surface.
文摘Polymer exchange membrane fuel cells （PEMFC） are objects of the current engineering technology and these are versatile generators for electrical energy. There are various kinds from them, but all of them are going on work at highest temperature. There isn＇t a PEMFC which can run at room temperature, like 20 ℃. In this study there is a aim for constructing such one for alternative fuels utilisation. PS and many electroconducting polymer formulations were proved by different researchers for PEM benefications, but here PS was synthesized without containing metalic contaminants and after converted to the PEM membrane.
基金supported by Beijing Natural Science Foundation(2172027)
文摘Graphene oxide(GO) has been demonstrated to be an effective hydrophilic nanofiller to modify the polymeric membranes when forming a mixed matrix structure. GO quantum dots(QDs) are promising candidates to fully exert the rich oxygen containing functional groups due to their unique size induced edge effects. In this work, GO QDs modified polysulfone(PSF) ultrafiltration(UF) membranes were prepared by phase inversion method with various GO QDs loadings(0.1–0.5 wt.%). A proper amount of GO QDs addition led to a more porous and hydrophilic membrane structure. With 0.3 wt.% GO QDs, the membranes showed a60% increase in permeability(130.54 vs. 82.52 LMH bar^-1).The pristine PSF membranes had a complete cutoff of bovine serum albumin molecules and it was well maintained with GO QDs incorporated. The membranes with 0.5 wt.% GO QDs exhibited the highest flux recovery ratio of 89.7% and the lowest irreversible fouling of 10.3%(54.5% and 33.3% for the pristine PSF membranes). Our results proved that GO QDs can function as effective nanofillers to enhance the hydrophilicity, permeability and antifouling performance of PSF UF membranes.
