Reburning was applied to Polish automatic coal-fired retort boiler (25 kW).The use of bio-syngas reduced NOx emissions from the boiler by over 25%,below the significant level of 200 mg/m3 .Reburning was carried out us...Reburning was applied to Polish automatic coal-fired retort boiler (25 kW).The use of bio-syngas reduced NOx emissions from the boiler by over 25%,below the significant level of 200 mg/m3 .Reburning was carried out using an integrated system consisting of the boiler and a fixed-bed 60 kW (GazEla) gasification reactor.The process gas was continuously introduced above the coal burner of the boiler.The process parameters of the boiler and the gasifier were also measured and compared with the other units.Characteristic NOx emissions from automatic and manually operated boilers were also presented.展开更多
The temperature is 56.5℃when acetone gas is rectified during the production of powdery phospholipid. If heat exchanger is added, heat energy that is reclaimed can be used by other heaters. On the basis of exchange ho...The temperature is 56.5℃when acetone gas is rectified during the production of powdery phospholipid. If heat exchanger is added, heat energy that is reclaimed can be used by other heaters. On the basis of exchange hot water (51℃) 4m3 every minute, a factory with the productivity of powdery phospholipid being 10 ton a day can save 533.2 ton standard coal which is equivalent to 746.48 ton common coal. If this technique of saving energy and reducing emission could be widely used in correlative industries of all over the country, economic benefits will be prominent.展开更多
The mathematic model of combined converter with two different flow modes of gas-cooled reactor was established. The effects of gas flow mode in gas-cooled reactor on combined converter was investigated with the yield ...The mathematic model of combined converter with two different flow modes of gas-cooled reactor was established. The effects of gas flow mode in gas-cooled reactor on combined converter was investigated with the yield of methanol was 1 400 kt/a. The results show that if the flow mode of the cooling pipe gas and the catalytic bed gas change from countercurrent to concurrent, the catalytic bed temperature distribution does not fit the most optimum temperature curve of reversible exothermic reaction and the heat duty of heat changer in whole process increased seriously, which means that there is much more equipment investment and more operating cost. The gas flow mode of gas-cooled reactor affects the methanol yield slightly. There- fore, the countercurrent gas flow mode of gas-cooled reactor is more lucrative in the combined converter process.展开更多
Thoron (Rn-220) is an invisible, odorless radioactive gas and nine times heavier than air. Purpose of project is to set up procedure to determine Rn-220 concentration which has been carried out in laboratory using S...Thoron (Rn-220) is an invisible, odorless radioactive gas and nine times heavier than air. Purpose of project is to set up procedure to determine Rn-220 concentration which has been carried out in laboratory using Solid State Nuclear Track Detector (SSNTD) based passive detector technique. In this study, technical procedure has been applied in Karlsruhe diffusion chamber and LR-115, Type II strippable (Kodak Pathe, France) detector. The results have investigated how LR-115 work for Rn-220 by using Monazite ore to simultaneously measure Rn-222 and Rn-220. To carry out experiment, Karlsruhe diffusion chamber is used to with and without Poly-Ethylene (PE) membrane. Karlsruhe diffusion chamber with PE membrane only detect Rn-222, without PE membrane detect total Rn-222 and Rn-220. Precision evaluation by duplicate measure at 8 cm detector-source distance with relative standard deviation is less than 2.54%. Testing technical procedure, detectors have been sent to National Institute of Radiological Science (NIRS) for Rn-220 calibration exposure. After detectors have been calibration exposure at NIRS, it carried out all the following steps of procedure which set up at laboratory in 1NST, Vietnam. Finally, calibration factor calculated is 0.21 (tracks-cm2/Bq·m3·h) and constructed curve between integrated Tn-220 concentration and tracks density with factor R2 = 0.975.展开更多
At Olkaria (Kenya) geothermal energy has been used since 1981, to generate electricity and now there are currently 3 plants with a nominal capacity of 205 MW. Preliminary measurement and evaluation of possible mercu...At Olkaria (Kenya) geothermal energy has been used since 1981, to generate electricity and now there are currently 3 plants with a nominal capacity of 205 MW. Preliminary measurement and evaluation of possible mercury (Hg) emission from two plants has been investigated. Potential atmospheric Hg emission has been determined based on an existing model for estimating the transport of mercury along geothermal fluid flow streams as pertains to energy recovery and conversion from liquid dominated geothermal reservoirs. Hg concentrations, addition, retention and release rates were calculated at a number of locations in the geothermal power plants based on the plant operating parameters and steam flow process (turbine, condenser, non-condensable gas ejector, and cooling tower). Potential Hg emission rates through plume range from 0.455 g/h to 2.17 g/h, or 10-30 mg/h per MWe. The emission per hour per MWe is 130-300 times lower compared to Hg levels reported for 88 MWe five operating geothermal power plants around Mt. Amiata area in Italy. These emissions are coupled with a release of 1.07 kg/h per MW of hydrogen sulphide (HzS). The potential Hg release rates to the environment will depend greatly on the concentration of HzS in the system. Any higher HzS contents may reduce solubility of rig in the brine hence making it to be available in the steam. The volatile Hg may travel with the non-condensable gases as Hg vapour.展开更多
Binary metal chalcogenides(BMCs)have shown better electrochemical performance compared with their mono metal counterparts owing to their abundant phase interfaces,higher active sites,faster electrochemical kinetics an...Binary metal chalcogenides(BMCs)have shown better electrochemical performance compared with their mono metal counterparts owing to their abundant phase interfaces,higher active sites,faster electrochemical kinetics and higher electronic conductivity.Nevertheless,their performance still undergoes adverse decline during electrochemical processes mainly due to poor intrinsic ionic conductivities,large volume expansions,and structural agglomeration and fracture.To tackle these problems,various strategies have been applied to engineer the BMC nanostructures to obtain optimized electrode materials.However,the lack of understanding of the electrochemical response of BMCs still hinders their large-scale application.This review not only highlights the recent progress and development in the preparation of BMC-based electrode materials but also explains the kinetics to further understand the relation between structure and performance.It will also explain the engineering of BMCs through nanostructuring and formation of their hybrid structures with various carbonaceous materials and three-dimensional(3 D)templates.The review will discuss the detailed working mechanism of BMC-based nanostructures in various electrochemical energy storage(EES)systems including supercapacitors,metal-ion batteries,metal-air batteries,and alkaline batteries.In the end,major challenges and prospective solutions for the development of BMCs in EES devices are also outlined.We believe that the current review will provide a guideline for tailoring BMCs for better electrochemical devices.展开更多
基金Projects(DEC-2011/01/B/ST8/07394,DEC-2011/01/D/ST8/07399)supported by the Polish National Centre for Science(NCN)
文摘Reburning was applied to Polish automatic coal-fired retort boiler (25 kW).The use of bio-syngas reduced NOx emissions from the boiler by over 25%,below the significant level of 200 mg/m3 .Reburning was carried out using an integrated system consisting of the boiler and a fixed-bed 60 kW (GazEla) gasification reactor.The process gas was continuously introduced above the coal burner of the boiler.The process parameters of the boiler and the gasifier were also measured and compared with the other units.Characteristic NOx emissions from automatic and manually operated boilers were also presented.
文摘The temperature is 56.5℃when acetone gas is rectified during the production of powdery phospholipid. If heat exchanger is added, heat energy that is reclaimed can be used by other heaters. On the basis of exchange hot water (51℃) 4m3 every minute, a factory with the productivity of powdery phospholipid being 10 ton a day can save 533.2 ton standard coal which is equivalent to 746.48 ton common coal. If this technique of saving energy and reducing emission could be widely used in correlative industries of all over the country, economic benefits will be prominent.
文摘The mathematic model of combined converter with two different flow modes of gas-cooled reactor was established. The effects of gas flow mode in gas-cooled reactor on combined converter was investigated with the yield of methanol was 1 400 kt/a. The results show that if the flow mode of the cooling pipe gas and the catalytic bed gas change from countercurrent to concurrent, the catalytic bed temperature distribution does not fit the most optimum temperature curve of reversible exothermic reaction and the heat duty of heat changer in whole process increased seriously, which means that there is much more equipment investment and more operating cost. The gas flow mode of gas-cooled reactor affects the methanol yield slightly. There- fore, the countercurrent gas flow mode of gas-cooled reactor is more lucrative in the combined converter process.
文摘Thoron (Rn-220) is an invisible, odorless radioactive gas and nine times heavier than air. Purpose of project is to set up procedure to determine Rn-220 concentration which has been carried out in laboratory using Solid State Nuclear Track Detector (SSNTD) based passive detector technique. In this study, technical procedure has been applied in Karlsruhe diffusion chamber and LR-115, Type II strippable (Kodak Pathe, France) detector. The results have investigated how LR-115 work for Rn-220 by using Monazite ore to simultaneously measure Rn-222 and Rn-220. To carry out experiment, Karlsruhe diffusion chamber is used to with and without Poly-Ethylene (PE) membrane. Karlsruhe diffusion chamber with PE membrane only detect Rn-222, without PE membrane detect total Rn-222 and Rn-220. Precision evaluation by duplicate measure at 8 cm detector-source distance with relative standard deviation is less than 2.54%. Testing technical procedure, detectors have been sent to National Institute of Radiological Science (NIRS) for Rn-220 calibration exposure. After detectors have been calibration exposure at NIRS, it carried out all the following steps of procedure which set up at laboratory in 1NST, Vietnam. Finally, calibration factor calculated is 0.21 (tracks-cm2/Bq·m3·h) and constructed curve between integrated Tn-220 concentration and tracks density with factor R2 = 0.975.
文摘At Olkaria (Kenya) geothermal energy has been used since 1981, to generate electricity and now there are currently 3 plants with a nominal capacity of 205 MW. Preliminary measurement and evaluation of possible mercury (Hg) emission from two plants has been investigated. Potential atmospheric Hg emission has been determined based on an existing model for estimating the transport of mercury along geothermal fluid flow streams as pertains to energy recovery and conversion from liquid dominated geothermal reservoirs. Hg concentrations, addition, retention and release rates were calculated at a number of locations in the geothermal power plants based on the plant operating parameters and steam flow process (turbine, condenser, non-condensable gas ejector, and cooling tower). Potential Hg emission rates through plume range from 0.455 g/h to 2.17 g/h, or 10-30 mg/h per MWe. The emission per hour per MWe is 130-300 times lower compared to Hg levels reported for 88 MWe five operating geothermal power plants around Mt. Amiata area in Italy. These emissions are coupled with a release of 1.07 kg/h per MW of hydrogen sulphide (HzS). The potential Hg release rates to the environment will depend greatly on the concentration of HzS in the system. Any higher HzS contents may reduce solubility of rig in the brine hence making it to be available in the steam. The volatile Hg may travel with the non-condensable gases as Hg vapour.
基金supported by the National Natural Science Fund for Distinguished Young Scholars(52025133)the Tencent Foundation through the XPLORER PRIZE,Beijing Natural Science Foundation(JQ18005)+2 种基金the National Natural Science Foundation of China(52125307 and 11974023)the Fund of the State Key Laboratory of Solidification Processing in Northwestern Polytechnic University(NWPU)(SKLSP202004)the Key Area R&D Program of Guangdong Province(2018B030327001 and 2018B010109009)。
文摘Binary metal chalcogenides(BMCs)have shown better electrochemical performance compared with their mono metal counterparts owing to their abundant phase interfaces,higher active sites,faster electrochemical kinetics and higher electronic conductivity.Nevertheless,their performance still undergoes adverse decline during electrochemical processes mainly due to poor intrinsic ionic conductivities,large volume expansions,and structural agglomeration and fracture.To tackle these problems,various strategies have been applied to engineer the BMC nanostructures to obtain optimized electrode materials.However,the lack of understanding of the electrochemical response of BMCs still hinders their large-scale application.This review not only highlights the recent progress and development in the preparation of BMC-based electrode materials but also explains the kinetics to further understand the relation between structure and performance.It will also explain the engineering of BMCs through nanostructuring and formation of their hybrid structures with various carbonaceous materials and three-dimensional(3 D)templates.The review will discuss the detailed working mechanism of BMC-based nanostructures in various electrochemical energy storage(EES)systems including supercapacitors,metal-ion batteries,metal-air batteries,and alkaline batteries.In the end,major challenges and prospective solutions for the development of BMCs in EES devices are also outlined.We believe that the current review will provide a guideline for tailoring BMCs for better electrochemical devices.