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固相微萃取-色/质法鉴定易燃液体放火物 被引量:19
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作者 邓震宇 赵术学 +2 位作者 鲁志宝 范子琳 田桂花 《消防科学与技术》 CAS 北大核心 2009年第9期695-697,共3页
建立了固相微萃取—气相色谱/质谱鉴定常见易燃液体放火物的方法。筛选固相微萃取的条件包括萃取纤维、吸附温度、加热温度、吸附时间和解析时间。文中列出了93#汽油、航空煤油、0#柴油和通用油漆稀释剂诸样品的SPM E-GC/M S总离子谱图... 建立了固相微萃取—气相色谱/质谱鉴定常见易燃液体放火物的方法。筛选固相微萃取的条件包括萃取纤维、吸附温度、加热温度、吸附时间和解析时间。文中列出了93#汽油、航空煤油、0#柴油和通用油漆稀释剂诸样品的SPM E-GC/M S总离子谱图。该方法简便、灵敏、快捷、准确、抗干扰能力强。 展开更多
关键词 放火物 火场残留物 固相微萃取 气相色谱/质谱法
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顶空固相微萃取-气相色谱/质谱法(HS-SPME-GC/MS)鉴定火场残留物样品中生物柴油的研究
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作者 邓震宇 刘振刚 +1 位作者 王玉领 田桂花 《广东化工》 CAS 2023年第2期158-160,共3页
本文利用顶空固相微萃取-气相色谱质谱法(HS-SPME-GC/MS)对火场残留物样品中的生物柴油进行分析鉴定研究。通过SPME条件的优化、筛选实验和GC/MS分析条件的设立,建立了生物柴油的顶空固相微萃取-气相色谱质谱(HS-SPME-GC/MS)定性分析鉴... 本文利用顶空固相微萃取-气相色谱质谱法(HS-SPME-GC/MS)对火场残留物样品中的生物柴油进行分析鉴定研究。通过SPME条件的优化、筛选实验和GC/MS分析条件的设立,建立了生物柴油的顶空固相微萃取-气相色谱质谱(HS-SPME-GC/MS)定性分析鉴定方法,其中SPME优化条件为微萃取头:100μm PDMS(红);加热温度:70℃;加热时间:50 min。实验结果表明该方法是一种简便高效、灵敏准确,分离分析效果好,抗干扰能力强的分析鉴定火场残留物样品中生物柴油的方法。 展开更多
关键词 顶空-固相微萃取 气相色谱-质谱法 生物柴油 火场残留物分析 放火物
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Thinking About the New Atmospheric Pollutant Emission Standard for Thermal Power Plants 被引量:1
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作者 Sun Weimin Zhang Jie 《Electricity》 2012年第4期46-51,共6页
China's new Atmospheric Pollutant Emission Standard for Thermal Power Plants has been made the most stringent atmospheric pollutant emission limit in the world,with the intensified control of nitrogen oxides in th... China's new Atmospheric Pollutant Emission Standard for Thermal Power Plants has been made the most stringent atmospheric pollutant emission limit in the world,with the intensified control of nitrogen oxides in the air pollutants emitted by thermal power plants,the tightened limit on the emission of sulfur dioxide,and the widened range of control including mercury and other compounds discharge.The adoption of the new standard will considerably impact the survival and development of power plants,even the whole economy of the nation.While implementing all the policies and measures on emission reduction issued by the State to fulfill political,social,and economic responsibilities,China Huadian Corporation,one of the leading state-owned power generation groups,is actively exploring the green and low-carbon path for the sound and rapid development of the group. 展开更多
关键词 environment protection emission standard emission reduction
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Emission Factors of Particulate Matter Emitted from Co-Firing of Thai Lignite and Agricultural Residues in Fixed Bed Combustor
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作者 N. Mantananont S. Garivait S. Patumsawad 《Journal of Environmental Science and Engineering》 2011年第7期890-899,共10页
Emission factors (EFs) of particulate matter (PM) derived from mono and co-firing of Thai lignite and agricultural residues have been investigated. Two sampling methods for PM, total filtration (TF) and electric... Emission factors (EFs) of particulate matter (PM) derived from mono and co-firing of Thai lignite and agricultural residues have been investigated. Two sampling methods for PM, total filtration (TF) and electrical low-pressure impactor (ELPI), were used together. The study is focused on the influence of fuel mass fraction, and of secondary air to total air; SA:TA on EFs of PM. The results have shown that EFs of PM in mass-basis given by TF method are 8.9, 5.3 and 8.1 mg/kgfuel, while 3.3, 2.7 and 3.3 mg/kgfuel when using ELPI, for firing at constant SA:TA (30%) of lignite, rice husk and bagasse, respectively. For co-firing with 30%SA of coal/rice husk, higher EFs of PM is observed. They are 7.17 and 10.9 mg/kgfuel (TF) for 40 and 70% rice husk share, respectively, or 4.18 and 5.19 mg/kgfuel (ELPI). However, lower PM emission; 1-3.3 mg/kgruel (TF) or 0.72-2.83 mg/kgfuel (ELPI) are obtained during co-firing of coal/rice husk with lower degree of air staging (i.e. 0-10% SA:TA). For the influence of oxygenation state, increasing of SA: TA leads to a low formation of ultrafine particles (Dp 〈 0.1 μm). Apart from PM, major gases (CO, NO, SO2) will be documented in this paper. 展开更多
关键词 Emission factors particulate matter CO-FIRING Thai lignite agricultural residues fixed bed.
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Challenges from the New Emission Standards for SO_2 and NO_X
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作者 Shen Baozhong Chen Zhen Xu Xiaoming 《Electricity》 2012年第5期55-58,共4页
The Emission Standards of Air Pollutants from Thermal Power Plants (GB 13223-2011) prescribe a stricter limitation to air pollutants than ever before. As set in the new emission standard, the limitations of SO2 and NO... The Emission Standards of Air Pollutants from Thermal Power Plants (GB 13223-2011) prescribe a stricter limitation to air pollutants than ever before. As set in the new emission standard, the limitations of SO2 and NOX for sensitive areas under normal conditions are 50 mg/m3 and 100 mg/m3, respectively. The objective analysis and suggestions are proposed. The recent status and operational experience of desulfurization and denitrification equipment are discussed. From the discussions, thermal power plants face a huge challenge to satisfy the new emission standards. For further reducing of the emission concentrations of SO2 and NOX, three methods were introduced, including: seriously implementing the emission standards, improving treatment equipment, and increasing the efficiencies of desulfurization and denitrification. 展开更多
关键词 power plant emission standard sulfur dioxide nitrogen oxides
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Effect of a semi electro-mechanical engine valve on performance and emissions in a single cylinder spark ignited engine 被引量:1
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作者 Bülent ZDALYAN Oguzhan DOGAN 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2010年第2期106-114,共9页
In this study, an electro-mechanical valve (EMV) system for the intake valve ofa fottr stroke, single cylinder, overhead valve and spark ignition (SI) engine was designed and constructed. An engine with the EMV sy... In this study, an electro-mechanical valve (EMV) system for the intake valve ofa fottr stroke, single cylinder, overhead valve and spark ignition (SI) engine was designed and constructed. An engine with the EMV system and a standard engine were tested to observe the effects of the EMV on engine performance and emissions at different speeds under full load. The EMV engine showed improved engine power, engine torque and break specific fuel consumption (BSFC). A 66% decrease in CO emissions was also obtained with the EMV system, but hydrocarbons (HC) and NOx emissions increased by 12% and 13% respectively. 展开更多
关键词 Semi electro-mechanic Camless engine Electro-mechanic engine valve Engine performance EMISSIONS
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